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METHYLMAGNESIUM IODIDE

METHYLMAGNESIUM IODIDE Structure
CAS No.
917-64-6
Chemical Name:
METHYLMAGNESIUM IODIDE
Synonyms
CHLOROMETHYLMAGNESIUM;Methylmagnesium iodide solution;nesium iodide;iodomethylmagnesium;iodomethyl-magnesiu;Methyliodomagnesium;METHYLMAGNESIUM IODIDE;Methylmagnesium iodine;MagnesiuM, iodoMethyl-;3.0 M in diethyl ether
CBNumber:
CB4248837
Molecular Formula:
CH3IMg
Molecular Weight:
166.24
MOL File:
917-64-6.mol
MSDS File:
SDS
Modify Date:
2024/8/26 21:18:56

METHYLMAGNESIUM IODIDE Properties

Density 1.26 g/mL at 20 °C
Flash point -40 °C
BRN 1209226
InChIKey AUPXBVDHVRZMIB-UHFFFAOYSA-M
EPA Substance Registry System Magnesium, iodomethyl- (917-64-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS05,GHS07
Signal word  Danger
Hazard statements  H260-H314-H336-H225
Precautionary statements  P223-P231+P232-P261-P280-P370+P378-P422-P210
Hazard Codes  F+,C,F
Risk Statements  12-14/15-22-34-66-67-19-11
Safety Statements  16-26-36/37/39-43-45-7/8
RIDADR  UN 3399 4.3/PG 1
WGK Germany  1
1-3-10
HazardClass  4.2
PackingGroup  I
HS Code  29319090
NFPA 704
3
2 2

METHYLMAGNESIUM IODIDE price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 254363 Methylmagnesium iodide solution 3.0?M in diethyl ether 917-64-6 100ML ₹8844.03 2022-06-14 Buy
Sigma-Aldrich(India) 254363 Methylmagnesium iodide solution 3.0?M in diethyl ether 917-64-6 800ML ₹35018.88 2022-06-14 Buy
TCI Chemicals (India) M0364 Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L) 917-64-6 100G ₹7100 2022-05-26 Buy
Product number Packaging Price Buy
254363 100ML ₹8844.03 Buy
254363 800ML ₹35018.88 Buy
M0364 100G ₹7100 Buy

METHYLMAGNESIUM IODIDE Chemical Properties,Uses,Production

Chemical Properties

Dark grey liquid

Uses

Methylmagnesium iodide solution can be used:

  • To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.
  • In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.
  • To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.
  • In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.

Definition

Available as solution inether.

Hazard

Flammable, dangerous fire and explosionrisk.

Global( 169)Suppliers
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GLR Innovations +91 9891111994 New Delhi, India 4542 58 Inquiry
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Azeocryst Organic Private Limited +91-8879077780 +91-8879077780 Maharashtra, India 32 58 Inquiry
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Sai Teja Drugs and Intermediates Pvt Ltd +91-9963142345 +91-9963142345 Telangana, India 38 58 Inquiry
S D Fine Chem Limited +91-9323715856 +91-9323715856 Maharashtra, India 368 58 Inquiry
Wellchem Laboratories +91-9820795238 +91-9892737187 Maharashtra, India 30 58 Inquiry
Almas Life Sciences 09441456585 Hyderabad, India 68 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Sai Teja Drugs and Intermediates Pvt. Ltd. 91-8685-223355 Telangana, India 22 58 Inquiry
METHYLMAGNESIUM IODIDE MAGNESIUM METHYL IODIDE iodomethyl-magnesiu methylmagnesiumiodidesol. Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L) iodomethylmagnesium METHYLMAGNESIUM IODIDE SOL., ~3 M IN DIE THYL ETHER METHYLMAGNESIUM IODIDE, 3.0M SOLUTION IN DIETHYL ETHER Methylmagnesium iodide, 2-3M in diethyl ether Methylmagnesium iodide solution 3.0 M in diethyl ether Methylmagnesium iodide, 3M solution in diethyl ether, AcroSeal Methyliodomagnesium Methylmagnesium iodide,3M solution in diethylether magnesium carbanide iodide Methylmagnesium iodine Methylmagnesium iodide 3M solution in DEE MethylMagnesiuM iodide, 3.0M solution in diethyl ether, J&KSeal MagnesiuM, iodoMethyl- MethylMagnesiuM iodide, 3.0 M in diethyl ether, SpcSeal Methyl magnesium iodide 3M ether solution methylmagnesium iodide 2M in THF nesium iodide Methylmagnesium bromide [solution in THF] Methylmagnesium Iodide, Diethyl Ether Solution (abt. 1mol/l) Methylmagnesium Iodide (3.0 M in Diethyl ether) 3.0 M in diethyl ether Methylmagnesium iodide solution CHLOROMETHYLMAGNESIUM Methylmagnesium iodide (6CI) Methylmagnesium iodide, 3M in diethyl ether Methyl magnesium iodide 1M in THF METHYL MAGNESIUM IODIDE IN ETHER Methyl Magnesium Iodide 3 Molar Solution in Diethyl Ether Methylmagnesium iodide, 3M in diethyl 917-64-6 CH3IMg CH3MgI Alkyl Organometallic Reagents Mg (Magnesium) Compounds Grignard Reagents & Alkyl Metals Typical Metal Compounds Grignard Reagents Classes of Metal Compounds Typical Metal Compounds Grignard Reagent Alkyl Chemical Synthesis Organic Bases Organometallic Reagents Synthetic Reagents AlkylChemical Synthesis Grignard Reagents Organic Bases Organometallic Reagents Synthetic Reagents Classes of Metal Compounds Grignard Reagents