DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE

DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE Structure
CAS No.
24074-26-8
Chemical Name:
DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE
Synonyms
Ethyl (diisopropyl phosphono)acetate;Ethyl 2-(diisopropoxyphosphoryl)acetate;Diisopropyl (carboethoxymethyl)phosphonate;ethyl 2-di(propan-2-yloxy)phosphorylacetate;DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE;Acetic acid, 2-[bis(1-methylethoxy)phosphinyl]-, ethyl ester
CBNumber:
CB4401506
Molecular Formula:
C10H21O5P
Molecular Weight:
252.24
MOL File:
24074-26-8.mol
Modify Date:
2022/11/11 11:01:00

DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE Properties

Boiling point 142-143 °C11 mm Hg(lit.)
Density 1.06 g/mL at 25 °C(lit.)
refractive index n20/D 1.427(lit.)
Flash point >230 °F

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3

DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE Chemical Properties,Uses,Production

Uses

Reactant for:

  • Preparation of spiroimine ring fragment of spirolides via stereoselective intermolecular Diels-Alder and aza-Wittig cyclization
  • Katsuki-Sharpless epoxidation reaction
  • Preparation of nine-membered diallylic sulfonamides as chiral building blocks
  • Alpha-phosphono lactams for subsequent Wadsworth-Emmons olefination, and Suzuki coupling reactions to yield diverse pyrrolidinone compounds
  • Synthesis of galactosylceramide analog that induces Th1-biased responses in human (NKT) cells
  • Stereoselective total synthesis of the ionophore antibiotic zincophorin (M144255)

DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE Preparation Products And Raw materials

Raw materials

Preparation Products

DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE Suppliers

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DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE Ethyl (diisopropyl phosphono)acetate Diisopropyl (carboethoxymethyl)phosphonate Acetic acid, 2-[bis(1-methylethoxy)phosphinyl]-, ethyl ester ethyl 2-di(propan-2-yloxy)phosphorylacetate Ethyl 2-(diisopropoxyphosphoryl)acetate 24074-26-8 C2H5O2CCH2POOCHCH322 C-C Bond Formation Synthetic Reagents Horner-Wadsworth-Emmons Reagents Olefination C-C Bond Formation Horner-Wadsworth-Emmons Reagents Olefination