Diethyl peroxydicarbonate

Diethyl peroxydicarbonate Structure
CAS No.
14666-78-5
Chemical Name:
Diethyl peroxydicarbonate
Synonyms
Diethyl peroxydiformate;Diethyl peroxydicarbonate;Bis(ethoxyformyl) peroxide;Bis(ethoxycarbonyl) peroxide;Peroxybis(formic acid ethyl) ester;Peroxydicarbonic acid diethyl ester;diethyl peroxydicarbonate, <= 27% in solution;ethoxycarbonyloxy ethyl carbonate[in solution, content ≤27%]
CBNumber:
CB4852100
Molecular Formula:
C6H10O6
Molecular Weight:
178.14
MOL File:
14666-78-5.mol
Modify Date:
2023/5/4 15:13:21

Diethyl peroxydicarbonate Properties

Boiling point 230.35°C (rough estimate)
Density 1.3253 (rough estimate)
refractive index 1.5860 (estimate)
EPA Substance Registry System Peroxydicarbonic acid, diethyl ester (14666-78-5)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS02
Signal word  Danger
Hazard statements  H226-H242-H315-H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362-P210-P220-P234-P280-P370+P378-P403+P235-P411-P420-P501
RIDADR  3115
HazardClass  5.2
PackingGroup  II

Diethyl peroxydicarbonate Chemical Properties,Uses,Production

General Description

Diethyl peroxydicarbonate is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. Diethyl peroxydicarbonate is generally stored or transported in a solvent slurry, water, alcohol, etc.

Reactivity Profile

Diethyl peroxydicarbonate decomposes violently or explosively at temperatures 0-10°C owing to self-accelerating exothermic decomposition. Several explosions were due to shock, heat or friction. Amines and certain metals can cause accelerated decomposition [Bretherick, 1979 p. 156]. Danger of explosion when dry.

Safety Profile

The impure material is a powerful explosive extremely sensitive to heat or impact. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES.

Diethyl peroxydicarbonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Diethyl peroxydicarbonate Diethyl peroxydiformate diethyl peroxydicarbonate, <= 27% in solution Bis(ethoxycarbonyl) peroxide Bis(ethoxyformyl) peroxide Peroxybis(formic acid ethyl) ester Peroxydicarbonic acid diethyl ester ethoxycarbonyloxy ethyl carbonate[in solution, content ≤27%] 14666-78-5