ETIOPORPHYRIN I

ETIOPORPHYRIN I Structure
CAS No.
448-71-5
Chemical Name:
ETIOPORPHYRIN I
Synonyms
Etioporphyrin;ETIOPORPHYRIN I;ethioporphyrin I;Mesoetioporphyrin;2,7,12,17-TETRAETHYL-3,8,13,18-TETRAMETHYL-21H,23H-PORPHINE;3,8,13,18-Tetraethyl-2,7,12,17-tetramethyl-21H,23H-porphine;2,7,12,17-Tetraethyl-3,8,13,18-tetramethyl-21H,23H-porphyrin;21H,23H-Porphine, 2,7,12,17-tetraethyl-3,8,13,18-tetramethyl-;2,7,12,17-tetraethyl-3,8,13,18-tetramethyl-21,22-dihydroporphine;2,7,12,17-tetraethyl-3,8,13,18-tetramethyl-21,22-dihydroporphyrin
CBNumber:
CB5125333
Molecular Formula:
C32H38N4
Molecular Weight:
478.67
MOL File:
448-71-5.mol
Modify Date:
2022/8/26 12:19:21

ETIOPORPHYRIN I Properties

Melting point >400 °C
Boiling point 792.7±55.0 °C(Predicted)
Density 1.101±0.06 g/cm3(Predicted)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338

ETIOPORPHYRIN I Chemical Properties,Uses,Production

Uses

Etioporphyrin I is used as a phosporescent when complexed with certain metals.

Purification Methods

Purify it by chromatography on an Al2O3 column (300g/300mg of porphyrin) and elute with CH2Cl2, evaporate the eluate and crystallise the residue from CH2Cl2/MeOH, pyridine or CHCl3/pet ether(purple prisms, m > 300o) [Smith J Chem Soc Perkin Trans 1 1471 1972]. The copper salt crystallises as red needles from pyridine/AcOH. It complexes with metals. The dihydrobromide [69150-58-9] M 640.5 separates from aetioporphyrin I in Et2O on addition of 10% of aqueous HBr after 2days [Fischer & Treibs Justus Liebigs Ann Chem 457 241 1927, Treibs & Dieter Justus Liebigs Ann Chem 513 88-91 1934]. [Beilstein 26 III/IV 1915.]

ETIOPORPHYRIN I Preparation Products And Raw materials

Raw materials

Preparation Products

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21H,23H-Porphine, 2,7,12,17-tetraethyl-3,8,13,18-tetramethyl- 3,8,13,18-Tetraethyl-2,7,12,17-tetramethyl-21H,23H-porphine Etioporphyrin 2,7,12,17-TETRAETHYL-3,8,13,18-TETRAMETHYL-21H,23H-PORPHINE ETIOPORPHYRIN I ethioporphyrin I 2,7,12,17-Tetraethyl-3,8,13,18-tetramethyl-21H,23H-porphyrin Mesoetioporphyrin 2,7,12,17-tetraethyl-3,8,13,18-tetramethyl-21,22-dihydroporphine 2,7,12,17-tetraethyl-3,8,13,18-tetramethyl-21,22-dihydroporphyrin 448-71-5 Porphyrins Synthetic Porphyrins