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POLY(METHYL METHACRYLATE)

POLY(METHYL METHACRYLATE) Structure
CAS No.
9010-88-2
Chemical Name:
POLY(METHYL METHACRYLATE)
Synonyms
METHYL METHACRYLATE POLYMER;POLY(METHYL METHACRYLATE), ISOTACTIC;LUCITE;Eudragit E 30D;Polyacrylic Resin III;METHYL METHACRYLATE RESIN;POLYBEAD(R) PMMA MICROSPHERES;POLY(METHYL METHACRYLATE) 600;POLYMETHYL METHACRYLATE BEADS;POLY(METHYL METHACRYLATE) 2'000
CBNumber:
CB5169353
Molecular Formula:
C10H16O4
Molecular Weight:
200.23
MOL File:
9010-88-2.mol
Modify Date:
2023/4/23 13:52:06

POLY(METHYL METHACRYLATE) Properties

Melting point 150 °C
Density 1.2 g/mL at 25 °C(lit.)
refractive index n20/D 1.49
solubility alcohols and aliphatic hydrocarbons: insoluble
form powder
EPA Substance Registry System Ethyl acrylate methyl methacrylate polymer (9010-88-2)

SAFETY

Risk and Safety Statements

Hazard Codes  Xn
Risk Statements  20/22
Safety Statements  36
WGK Germany  3
RTECS  TR0400000
Autoignition Temperature 580 °F

POLY(METHYL METHACRYLATE) price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 182249 Poly(methyl methacrylate-co-ethyl acrylate) ethyl acrylate <5?wt. %, average Mn ~39,500 by GPC, average Mw ~101,000 by GPC, powder 9010-88-2 25G ₹5239.3 2022-06-14 Buy
Sigma-Aldrich(India) 182249 Poly(methyl methacrylate-co-ethyl acrylate) ethyl acrylate <5?wt. %, average Mn ~39,500 by GPC, average Mw ~101,000 by GPC, powder 9010-88-2 1KG ₹16529.78 2022-06-14 Buy
Product number Packaging Price Buy
182249 25G ₹5239.3 Buy
182249 1KG ₹16529.78 Buy

POLY(METHYL METHACRYLATE) Chemical Properties,Uses,Production

Uses

Poly(methyl methacrylate-co-ethyl acrylate) (PMMAEA) copolymers may be used to prepare single phase mixture with phenolic derivative. PMMAEA may be used to form latex interpenetrating polymer networks (LIPNs). Membranes of PMMAEA were reportedly used for separation of heavy metal ions from aqueous solutions.

Preparation

Acrylic acid is H2C=CH-COOH and methacrylic acid is H2C=C(CH3)COOH. These compounds and their methyl esters are both quite reactive and difficult to store and handle. The monomer used to form poly(methyl methacrylate), 2-hydroxy-2-methylpropanenitrile, is prepared by the following reaction:
preparation of 2-methylpropanenitrile
2-Hydroxy-2-methylpropanenitrile is then reacted with methanol (or other alcohol) to yield methacrylate ester. Free-radical polymerization is initiated by peroxide or azo catalysts and produce poly(methyl methacrylate) resins having the following formula:
structure of Poly(methyl methacrylate)
Key properties are good resistance to heat, light, and weathering. This polymer is unaffected by most detergents, cleaning agents, and solutions of inorganic acids, alkalies, and aliphatic hydrocarbons. Poly(methyl methacrylate) has light transmittance of 92% with a haze of 1–3% and its clarity is equal to glass.

Industrial uses

Poly(methyl methacrylate), the polymerizedmethyl ester of methacrylic acid, is thermoplastic.The method of polymerization may be variedto achieve specific physical properties, orthe monomer may be combined with other components.Sheet materials may be prepared bycasting the monomer in bulk. Suspension polymerizationof the monomeric ester may be usedto prepare molding powders.
Conventional poly(methyl methacrylate) isamorphous; however, reports have been publishedof methyl methacrylate polymers of regularconfiguration, which are susceptible tocrystallization. Both the amorphous and crystallineforms of such crystallization-susceptible polymers possess physical properties that aredifferent from those of the conventional polymer,and suggest new applications.

POLY(METHYL METHACRYLATE) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 59)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Henan Tianfu Chemical Co.,Ltd. +86-0371-55170693 +86-19937530512 China 21677 55 Inquiry
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39916 58 Inquiry
Shaanxi Dideu Medichem Co. Ltd +86-029-81138252 +86-18789408387 China 2121 58 Inquiry
Dorne Chemical Technology co. LTD +86-86-13583358881 +8618560316533 China 3149 58 Inquiry
Dideu Industries Group Limited +86-29-89586680 +86-15129568250 China 26368 58 Inquiry
Hebei Guanlang Biotechnology Co., Ltd. +86-19930503259 +86-19930503259 China 18446 58 Inquiry
Shenzhen Monkono Technology Co.,Ltd +86-17063441314 China 677 58 Inquiry
Aladdin Scientific +1-+1(833)-552-7181 United States 52927 58 Inquiry
Hebei Fengmu Trading Co., Ltd. +8613393234347 China 2989 58 Inquiry
ABCR GmbH & CO. KG 49 721 95061 0 Germany 6846 75 Inquiry
POLYBEAD(R) PMMA MICROSPHERES POLYBEAD(R) POLY(METHYL METHACRYLATE) MICROSPHERES POLY(METHYL METHACRYLATE-CO-ETHYL ACRYLATE) POLY(METHYL METHACRYLATE) 10'000 Methylmethacrylate,ethylacrylatecopolymer Methylmethacrylate,polymerwithethylacrylate METHYL METHACRYLATE, POLYMERIZED METHYL METHACRYLATE RESIN METHACRYLIC ACID METHYL ESTER POLYMER LUCITE POLY(METHYL METHACRYLATE-CO-ETHYL ACRYLA TE), AVERAGE MW CA. 101,000(G Eudragit E 30D Poly(Methyl Methacrylate-co-ethyl acrylate) ethyl acrylate <5 wt. %, average Mn ~39,500 by GPC, average Mw ~101,000 by GPC, powder ETHYL ACRYLATE-METHYL METHACRYLATE LATEX POLY(METHYL METHACRYLATE) 100'000 POLY(METHYL METHACRYLATE) 150'000 POLY(METHYL METHACRYLATE) 2'000 POLY(METHYL METHACRYLATE) 20'000 POLY(METHYL METHACRYLATE) 2'480'000 POLY(METHYL METHACRYLATE) 300'000 POLY(METHYL METHACRYLATE) 5'000 POLY(METHYL METHACRYLATE) 50'000 POLY(METHYL METHACRYLATE) 500'000 POLY(METHYL METHACRYLATE) 600 POLY(METHYL METHACRYLATE) 75'000 POLY(METHYL METHACRYLATE) 8'000 POLY(METHYL METHACRYLATE) 800'000 POLYMETHYL METHACRYLATE BEADS 2-Propenoicacid,2-methyl-,methylester,Copolymerwithethyl2-propenoate 2-propenoicacid,2-methyl-,methylester,polymerwithethyl2-propenoate Ethylacrylate,copolymerwithmethylmethacrylate Ethylacrylate,methylmethacrylatecopolymer ethyl prop-2-enoate,methyl 2-methylprop-2-enoate Polyacrylic Resin III POLY(METHYL METHACRYLATE), ISOTACTIC METHYL METHACRYLATE POLYMER 9010-88-2 90011-14-7 CH2CCH3CO2CH3XCH2CHCO2C2H5Y Analytical Chromatography Product Catalog Alphabetic Analytical Standards Organic Soluble Polymers Polymer Standards POLB - POLY Chromatography Methacrylate PolymersSelf Assembly&Contact Printing PMMA-Based Resins Acrylics Hydrophobic Polymers Stamps for Nanoprint Lithography&Microcontact Printing Contact Printing Hydrophobic Polymers Materials Science Methacrylate Polymers Micro/NanoElectronics Microcontact Printing PMMA-Based Resins