(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Structure
CAS No.
380230-02-4
Chemical Name:
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
Synonyms
3,4-a']dinapht...;(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;]dinaphthalen-4-yl)bis(1-phenylethyl)amine;1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR);(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D;(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D;]dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;(S,S,S)-(3,5-Dioxa-4-phosphacyclohepa[2,1-a:3,4-a&rsquo
CBNumber:
CB5190531
Molecular Formula:
C36H30NO2P
Molecular Weight:
539.6
MOL File:
380230-02-4.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Properties

Melting point 88-89 °C
Boiling point 710.7±63.0 °C(Predicted)
alpha +13.1° (c 1.01, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka -0.57±0.20(Predicted)
form Powder
color off-white
Sensitive moisture sensitive
InChIKey LKZPDRCMCSBQFN-UIOOFZCWSA-N

SAFETY

Risk and Safety Statements

Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 665290 (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine 97% 380230-02-4 100MG ₹7837.3 2022-06-14 Buy
Sigma-Aldrich(India) 665290 (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine 97% 380230-02-4 100MG ₹7837.3 2022-06-14 Buy
Sigma-Aldrich 665290 (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine 97% 380230-02-4 500MG ₹25828.45 2022-06-14 Buy
Sigma-Aldrich(India) 665290 (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine 97% 380230-02-4 500MG ₹25828.45 2022-06-14 Buy
Sigma-Aldrich 665290 (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine 97% 380230-02-4 2G ₹85701.53 2022-06-14 Buy
Product number Packaging Price Buy
665290 100MG ₹7837.3 Buy
665290 100MG ₹7837.3 Buy
665290 500MG ₹25828.45 Buy
665290 500MG ₹25828.45 Buy
665290 2G ₹85701.53 Buy

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Chemical Properties,Uses,Production

Uses

The product may be used as a ligand in:

  • Iridium-catalyzed allylic etherification of acyclic, achiral allylic carbonates with potassium silanolates to form chiral allylic alcohols.
  • Palladium-catalyzed asymmetric allylic cyclisation of N-tosyl and N-benzyl carbonates to form the corresponding pyrrolidine and piperidine derivatives, respectively.
  • Intramolecular iridium-catalyzed allylic cyclizationof (E)-allylic methyl carbonates to form 2,5-trans/cis pyrrolidine derivatives.

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Preparation Products And Raw materials

Raw materials

Preparation Products

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Suppliers

Global( 54)Suppliers
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Dayang Chem (Hangzhou) Co.,Ltd. 571-88938639 +8617705817739 China 52861 58 Inquiry
Hefei TNJ Chemical Industry Co.,Ltd. +86-0551-65418684 +8618949823763 China 25363 58 Inquiry
PT CHEM GROUP LIMITED China 35426 58 Inquiry
GIHI CHEMICALS CO.,LIMITED +8618058761490 China 50003 58 Inquiry
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Aladdin Scientific +1-+1(833)-552-7181 United States 57511 58 Inquiry
Amadis Chemical Company Limited 571-89925085 China 131980 58 Inquiry
ABCR GmbH & CO. KG 49 721 95061 0 Germany 6846 75 Inquiry
United States Biological 800.520.3011 or 781.639.5092 United States 6256 80 Inquiry
Aikon International Limited 025-66113011 18112977050 China 16028 58 Inquiry
(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS(1-PHENYLETHYL)AMINE (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1S)-1-PHENYLETHYL]AMINE (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95% S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,min.95% 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95% 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine (S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,min.95% N,N-Bis((S)-1-phenylethyl)dinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine N,N-Bis[(1S)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)aMine 97% 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,95% ]dinaphthalen-4-yl)bis(1-phenylethyl)amine ]dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine. (S,S,S)-(3,5-Dioxa-4-phosphacyclohepa[2,1-a:3,4-a&rsquo (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D 1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1S)-1-phenylethyl]- 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,97% (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) 3,4-a']dinapht... (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine. N,N-Bis[(1S)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct,95% 380230-02-4 C36H30NO2P Privileged Ligands DSM MonoPhos Phosphoramidites Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Chiral Phosphine CPN