BENZYL 4-TOLUENESULFONATE

BENZYL 4-TOLUENESULFONATE Structure
CAS No.
1024-41-5
Chemical Name:
BENZYL 4-TOLUENESULFONATE
Synonyms
Benzyl Tosylate;BENZYL 4-TOLUENESULFONATE;Benzyl Alcohol Impurity 11;4-Methylbenzyl benzenesulfonate;benzyl 4-methylbenzenesulfonate;benzyl 4-methylbenzene-1-sulfonate;phenylmethyl 4-methylbenzenesulfonate;Benzenesulfonic acid, 4-methyl-, phenylmethyl ester
CBNumber:
CB5206030
Molecular Formula:
C14H14O3S
Molecular Weight:
262.32
MOL File:
1024-41-5.mol
MSDS File:
SDS
Modify Date:
2022/8/26 12:21:20

BENZYL 4-TOLUENESULFONATE Properties

Melting point 58 °C
Boiling point 412.7±24.0 °C(Predicted)
Density 1.222±0.06 g/cm3(Predicted)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H315-H318-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
Risk Statements  36/37/38
Safety Statements  26-36/37/39

BENZYL 4-TOLUENESULFONATE Chemical Properties,Uses,Production

Synthesis Reference(s)

Synthesis, p. 665, 1974 DOI: 10.1055/s-1974-34048

Purification Methods

Crystallise the ester from pet ether (b 40-60o), CHCl3/hexane or Et2O/*C6H6. Dry it in vacuo but NOT in a desiccator over CaCl2 as it causes hydrolysis of the ester. [Emmons & Ferris J Am Chem Soc 75 2257 1953, Beilstein 11 II 48, 11 III 207, 11 IV 273.]

BENZYL 4-TOLUENESULFONATE Preparation Products And Raw materials

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BENZYL 4-TOLUENESULFONATE phenylmethyl 4-methylbenzenesulfonate benzyl 4-methylbenzene-1-sulfonate benzyl 4-methylbenzenesulfonate Benzyl Tosylate Benzyl Alcohol Impurity 11 Benzenesulfonic acid, 4-methyl-, phenylmethyl ester 4-Methylbenzyl benzenesulfonate 1024-41-5 pharmacetical