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ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE

ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Structure
CAS No.
1235-21-8
Chemical Name:
ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
Synonyms
AURORA KA-1148;acetonyltriphenyl-phosphoniuchloride;OxopropyltriphenylphosphoniuM chlorid;ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE;Acetonyltriphenylphosphonium chloride,99%;Acetonyltriphenylphosphonium Chloride >2-oxopropyl(triphenyl)phosphanium chloride;ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE, 9 8%;(2-OXOPROPYL)-TRIPHENYLPHOSPHONIUM CHLORIDE;2-Oxopropyltriphenylphosphonium chloride 98%
CBNumber:
CB5414572
Molecular Formula:
C21H20ClOP
Molecular Weight:
354.81
MOL File:
1235-21-8.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Properties

Melting point 243-245 °C(lit.)
storage temp. Store below +30°C.
form solid
color White to Light yellow to Light orange
Water Solubility Soluble in hot water.
Sensitive Hygroscopic
CAS DataBase Reference 1235-21-8(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25-S24/25-S22-60-37-26
WGK Germany  3
RTECS  TA1841000
3
HS Code  29319019
Toxicity mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01535,
NFPA 704
1
2 0

ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 8.41028 Acetonyltriphenylphosphonium chloride for synthesis 1235-21-8 25G ₹7770 2022-06-14 Buy
ALFA India ALF-A14691-36 Acetonyltriphenylphosphonium chloride, 99% 1235-21-8 500g ₹12494 2022-05-26 Buy
ALFA India ALF-A14691-22 Acetonyltriphenylphosphonium chloride, 99% 1235-21-8 100g ₹2670 2022-05-26 Buy
TCI Chemicals (India) A1305 Acetonyltriphenylphosphonium Chloride 1235-21-8 25G ₹4500 2022-05-26 Buy
ALFA India ALF-A14691-14 Acetonyltriphenylphosphonium chloride, 99% 1235-21-8 25g ₹2279 2022-05-26 Buy
Product number Packaging Price Buy
8.41028 25G ₹7770 Buy
ALF-A14691-36 500g ₹12494 Buy
ALF-A14691-22 100g ₹2670 Buy
A1305 25G ₹4500 Buy
ALF-A14691-14 25g ₹2279 Buy

ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Chemical Properties,Uses,Production

Chemical Properties

WHITE TO SLIGHTLY BEIGE FINE CRYSTALLINE POWDER

Uses

Acetonyltriphenylphosphonium chloride is used to investigate the antimycobacterial activities of Me alkenyl quinolones. It is used as a reactant for synthesis of unsaturated esters and ketones containing multiple aromatic and heteroaromatic rings using Suzuki coupling - Wittig olefination.

Purification Methods

Recrystallise it from CHCl3/*C6H6/pet ether (b 60-80o) or by dissolving it in CHCl3 and pouring it into dry Et2O. max nm() 255(3,600), 262(3,700), 268(4,000) and 275(3,100). The iodide salt crystallises from H2O and has m 207-209o. [Ramirez & Dershowitz J Org Chem 22 41 1957.] Itisan IRRITANT and is hygroscopic. When shaken with a 10% aqueous solution of Na2CO3 (8hours) it gives acetylmethylene triphenyl phosphorane which is recrystallised from MeOH/H2O and after drying at 70o/0.1mm has m 205-206o. UV: nm() 268 (6600), 275 (6500) and 288 (5700), IR: max 1529 (s), 1470 (m), 1425 (s), max 1374 (m), 1105 and 978 (s) (cm-1). [Ramirez & Dershowitz J Org Chem 22 41, 44 1957, Beilstein 16 H 761, 16 II 373.]

ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 176)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
Clearsynth Labs 91-22-45045900 Maharashtra, India 3889 58 Inquiry
Chemical Centre 91-22-22031616 Maharashtra, India 29 58 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 16208 58 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29898 58 Inquiry
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39916 58 Inquiry
Career Henan Chemica Co +86-0371-86658258 +8613203830695 China 30253 58 Inquiry
OxopropyltriphenylphosphoniuM chlorid 2-Oxopropyltriphenylphosphonium chloride 98% Acetonyltriphenylphosphonium chloride for synthesis 2-oxopropyl(triphenyl)phosphanium chloride acetonyltriphenyl-phosphoniuchloride (2-OXOPROPYL)-TRIPHENYLPHOSPHONIUM CHLORIDE ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE AURORA KA-1148 ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE, 9 8% Acetonyltriphenylphosphonium chloride,99% (Acetylmethylene)triphenylphosphoniumchloride Acetonyltriphenylphosphonium Chloride > Phosphonium, (2-oxopropyl)triphenyl-, chloride (1:1) 1235-21-8 CH3COCH2PClC6H53 C21H20ClOP C21H20OPCl C21H20OP C21H20CIOP C-C Bond Formation Olefination Synthetic Reagents Wittig Reagents Phosphonium Compounds Wittig Reaction Wittig & Horner-Emmons Reaction Phosphonium Compounds Synthetic Organic Chemistry Wittig & Horner-Emmons Reaction Wittig Reaction