ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
![ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Structure](CAS/GIF/1235-21-8.gif)
- CAS No.
- 1235-21-8
- Chemical Name:
- ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE
- Synonyms
- AURORA KA-1148;acetonyltriphenyl-phosphoniuchloride;OxopropyltriphenylphosphoniuM chlorid;ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE;Acetonyltriphenylphosphonium chloride,99%;Acetonyltriphenylphosphonium Chloride >2-oxopropyl(triphenyl)phosphanium chloride;ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE, 9 8%;(2-OXOPROPYL)-TRIPHENYLPHOSPHONIUM CHLORIDE;2-Oxopropyltriphenylphosphonium chloride 98%
- CBNumber:
- CB5414572
- Molecular Formula:
- C21H20ClOP
- Molecular Weight:
- 354.81
- MOL File:
- 1235-21-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/4/23 13:52:06
Melting point | 243-245 °C(lit.) |
---|---|
storage temp. | Store below +30°C. |
form | solid |
color | White to Light yellow to Light orange |
Water Solubility | Soluble in hot water. |
Sensitive | Hygroscopic |
CAS DataBase Reference | 1235-21-8(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 22-24/25-S24/25-S22-60-37-26 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | TA1841000 | |||||||||
F | 3 | |||||||||
HS Code | 29319019 | |||||||||
Toxicity | mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01535, | |||||||||
NFPA 704 |
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ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE price More Price(5)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 8.41028 | Acetonyltriphenylphosphonium chloride for synthesis | 1235-21-8 | 25G | ₹7770 | 2022-06-14 | Buy |
ALFA India | ALF-A14691-36 | Acetonyltriphenylphosphonium chloride, 99% | 1235-21-8 | 500g | ₹12494 | 2022-05-26 | Buy |
ALFA India | ALF-A14691-22 | Acetonyltriphenylphosphonium chloride, 99% | 1235-21-8 | 100g | ₹2670 | 2022-05-26 | Buy |
TCI Chemicals (India) | A1305 | Acetonyltriphenylphosphonium Chloride | 1235-21-8 | 25G | ₹4500 | 2022-05-26 | Buy |
ALFA India | ALF-A14691-14 | Acetonyltriphenylphosphonium chloride, 99% | 1235-21-8 | 25g | ₹2279 | 2022-05-26 | Buy |
ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Chemical Properties,Uses,Production
Chemical Properties
WHITE TO SLIGHTLY BEIGE FINE CRYSTALLINE POWDER
Uses
Acetonyltriphenylphosphonium chloride is used to investigate the antimycobacterial activities of Me alkenyl quinolones. It is used as a reactant for synthesis of unsaturated esters and ketones containing multiple aromatic and heteroaromatic rings using Suzuki coupling - Wittig olefination.
Purification Methods
Recrystallise it from CHCl3/*C6H6/pet ether (b 60-80o) or by dissolving it in CHCl3 and pouring it into dry Et2O. max nm() 255(3,600), 262(3,700), 268(4,000) and 275(3,100). The iodide salt crystallises from H2O and has m 207-209o. [Ramirez & Dershowitz J Org Chem 22 41 1957.] Itisan IRRITANT and is hygroscopic. When shaken with a 10% aqueous solution of Na2CO3 (8hours) it gives acetylmethylene triphenyl phosphorane which is recrystallised from MeOH/H2O and after drying at 70o/0.1mm has m 205-206o. UV: nm() 268 (6600), 275 (6500) and 288 (5700), IR: max 1529 (s), 1470 (m), 1425 (s), max 1374 (m), 1105 and 978 (s) (cm-1). [Ramirez & Dershowitz J Org Chem 22 41, 44 1957, Beilstein 16 H 761, 16 II 373.]
ACETONYLTRIPHENYLPHOSPHONIUM CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3889 | 58 | Inquiry |
Chemical Centre | 91-22-22031616 | Maharashtra, India | 29 | 58 | Inquiry |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | China | 16208 | 58 | Inquiry |
career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29898 | 58 | Inquiry |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | China | 30253 | 58 | Inquiry |
Supplier | Advantage |
---|---|
TCI Chemicals (India) Pvt. Ltd. | 58 |
CHEMSWORTH | 30 |
A.J Chemicals | 58 |
Alfa Aesar | 58 |
Clearsynth Labs | 58 |
Chemical Centre | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | 58 |
career henan chemical co | 58 |
Chongqing Chemdad Co., Ltd | 58 |
Career Henan Chemica Co | 58 |
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