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ETHYL (DIPHENYLMETHYLSILYL)ACETATE

ETHYL (DIPHENYLMETHYLSILYL)ACETATE Structure
CAS No.
13950-57-7
Chemical Name:
ETHYL (DIPHENYLMETHYLSILYL)ACETATE
Synonyms
ethyl (methyldiphenylsilyl)acetate;ETHYL (DIPHENYLMETHYLSILYL)ACETATE;2-(Methyldiphenylsilyl)acetic acid ethyl ester
CBNumber:
CB5497193
Molecular Formula:
C17H20O2Si
Molecular Weight:
284.425
MOL File:
13950-57-7.mol
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ETHYL (DIPHENYLMETHYLSILYL)ACETATE Chemical Properties,Uses,Production

Physical properties

clear to light yellow liquids.

Uses

vinyl 1,1-dication synthetic equivalent in reactions with Grignard reagents; reagent for Peterson synthesis of α,β-un saturated esters.

Preparation

whereas the direct silylation of the lithium enolate of an ester normally results in the formation of a mixture of the α-silyl ester and the corresponding silyl ketene acetal, the same reaction with methyldiphenylchlorosilane gives exclusively the α-methyldiphenylsilyl ester. This direct C-silylation is the best general route to α-silyl esters.

ETHYL (DIPHENYLMETHYLSILYL)ACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

ketene

ETHYL (DIPHENYLMETHYLSILYL)ACETATE Suppliers

Global( 2)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
SIGMA-RBI 800 736 3690 (Orders) Switzerland 6913 91 Inquiry
Sigma-Aldrich 021-61415566 800-8193336 China 51471 80 Inquiry
Supplier Advantage
SIGMA-RBI 91
Sigma-Aldrich 80

13950-57-7(ETHYL (DIPHENYLMETHYLSILYL)ACETATE)Related Search:

PHENYLTRIMETHYLSILANE ETHYL (DIPHENYLMETHYLSILYL)ACETATE (TRIMETHYLSILYL)ACETIC ACID DIMETHYLPHENYLSILYLACETIC ACID 2-(METHYLDIPHENYLSILYL)ETHANOL
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ethyl (methyldiphenylsilyl)acetate 2-(Methyldiphenylsilyl)acetic acid ethyl ester ETHYL (DIPHENYLMETHYLSILYL)ACETATE 13950-57-7