CHLOROMETHYL PHENYL SULFIDE
- CAS No.
- 7205-91-6
- Chemical Name:
- CHLOROMETHYL PHENYL SULFIDE
- Synonyms
- (phenylthio)methyl chloride;Chlorothioanisole;α-Chlorothioanisole;ALPHA-CHLOROTHIOANISOLE;α-Chlorothioanisole >[(chloromethyl)thio]benzene;CHLOROMETHYL PHENYL SULFIDE;chloromethylsulfanylbenzene;chloromethylephenyl sulfide;CHLOROMETHYL PHENYL SULPHIDE
- CBNumber:
- CB5755381
- Molecular Formula:
- C7H7ClS
- Molecular Weight:
- 158.65
- MOL File:
- 7205-91-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/1/27 9:38:02
| Boiling point | 66 °C/0.2 mmHg (lit.) |
|---|---|
| Density | 1.184 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 214 °F |
| storage temp. | 2-8°C |
| solubility | sol most organic solvents; insol H2O |
| form | Liquid |
| color | Clear colorless to pale yellow |
| Sensitive | Stench |
| BRN | 1617369 |
| InChIKey | LLSMWLJPWFSMCP-UHFFFAOYSA-N |
| CAS DataBase Reference | 7205-91-6(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313 | |||||||||
| Safety Statements | 23-24/25 | |||||||||
| RIDADR | UN 3334 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-13 | |||||||||
| Hazard Note | Stench | |||||||||
| HazardClass | 4.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29309099 | |||||||||
| NFPA 704 |
|
CHLOROMETHYL PHENYL SULFIDE price More Price(4)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 216631 | Chloromethyl phenyl sulfide 97% | 7205-91-6 | 5G | ₹4270 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 216631 | Chloromethyl phenyl sulfide 97% | 7205-91-6 | 25G | ₹18140 | 2022-06-14 | Buy |
| TCI Chemicals (India) | C0912 | α-Chlorothioanisole min. 95.0 % | 7205-91-6 | 5G | ₹4300 | 2022-05-26 | Buy |
| TCI Chemicals (India) | C0912 | α-Chlorothioanisole min. 95.0 % | 7205-91-6 | 25G | ₹9100 | 2022-05-26 | Buy |
CHLOROMETHYL PHENYL SULFIDE Chemical Properties,Uses,Production
Uses
Reagent for the high-yield thiomethylation of O-silylated lactone and ester enolates in the synthesis of α-methylene lactones and esters.1
Synthesis
The two most convenient methods of chloromethyl phenyl sulfide are the reaction of Thioanisole with Sulfuryl Chloride and the reaction of Thiophenol with bromochloromethane using 1,8-Diazabicyclo[5.4.0]undec-7-ene or an alkali metal hydroxide as the base.
storage
Chloromethyl phenyl sulfideshould be handled in a well-ventilated fume hood and kept cooled. Freshly prepared material can be stored at 0-5 °C without any appreciable decomposition. It is advisable to use freshly prepared or distilled material for reactions.
Purification Methods
Dissolve the sulfide in CH2Cl2 or CCl4 and dry it (CaCl2), or pass it through a tube of CaCl2 and distil it using a fractionating column. Harmful vapours. It gives the sulfone [7205-98-3] (b 130o/1mm and m 53o from EtOH) [Beilstein 6 IV 1507] on oxidation with permonophthalic acid. [B.hme et al. Justus Liebigs Ann Chem 563 54 64 1949.] [Beilstein 6 III 1002.]
CHLOROMETHYL PHENYL SULFIDE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6768 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6100 | 58 | Inquiry |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | China | 29730 | 60 | Inquiry |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | China | 33024 | 60 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29858 | 58 | Inquiry |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49732 | 58 | Inquiry |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | China | 34563 | 58 | Inquiry |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | China | 52849 | 58 | Inquiry |
| CD Chemical Group Limited | +8615986615575 | China | 20342 | 58 | Inquiry |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531151365 | China | 18137 | 58 | Inquiry |
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