ChemicalBook > Product Catalog >Inorganic chemistry >Inorganic salts >Metal halide and Halogen salt >Metal fluoride and salt >Lithium tetrafluoroborate
Lithium tetrafluoroborate
- CAS No.
- 14283-07-9
- Chemical Name:
- Lithium tetrafluoroborate
- Synonyms
- LITHIUM BOROFLUORIDE;LiBF4;LiBF4.4H2O;ithium tetrafL;lithiumfluoborate;lithium fluoroborate;Lithium boridefluoride;LITHIUM TETRAFLUOROBORATE;tetrafluoro-borate lithium;Borate,tetrafluoro-,lithium
- CBNumber:
- CB6122283
- Molecular Formula:
- BF4Li
- Molecular Weight:
- 93.75
- MOL File:
- 14283-07-9.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/2/23 21:28:46
| Melting point | 293-300 °C (dec.) (lit.) |
|---|---|
| Density | 0.852 g/mL at 25 °C |
| vapor pressure | 10Pa at 20℃ |
| Flash point | 6 °C |
| storage temp. | Store below +30°C. |
| solubility | soluble in Acetonitrile, DMSO |
| form | powder |
| color | White to off-white |
| Specific Gravity | 0.852 |
| PH | 2.88 |
| Water Solubility | SOLUBLE |
| Sensitive | Hygroscopic |
| Merck | 14,5543 |
| Exposure limits |
ACGIH: TWA 2.5 mg/m3 NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3 |
| Stability | Stable. Incompatible with glass, acids, strong bases. Contact with acids releases toxic gas. Moisture-sensitive. |
| CAS DataBase Reference | 14283-07-9(CAS DataBase Reference) |
| EPA Substance Registry System | Borate(1-), tetrafluoro-, lithium (14283-07-9) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS05,GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H314-H341 | |||||||||
| Precautionary statements | P260-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | C,T,F,Xn | |||||||||
| Risk Statements | 20/21/22-31-34-36/37/38-23/24/25-11-36/38 | |||||||||
| Safety Statements | 22-26-27-36/37/39-45-25-16-36/37 | |||||||||
| RIDADR | UN 3260 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 3-10 | |||||||||
| Hazard Note | Corrosive/Hygroscopic | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28269090 | |||||||||
| Toxicity | LD50 orally in Rabbit: 1638 mg/kg LD50 dermal Rat > 2000 mg/kg | |||||||||
| NFPA 704 |
|
Lithium tetrafluoroborate price More Price(12)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 901695 | Lithium tetrafluoroborate ≥98%, acid <200 ppm, anhydrous | 14283-07-9 | 10G | ₹18261.78 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 901695 | Lithium tetrafluoroborate ≥98%, acid <200 ppm, anhydrous | 14283-07-9 | 50G | ₹55813.7 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 451622 | Lithium tetrafluoroborate ultra dry, powder, 99.99% trace metals basis | 14283-07-9 | 5G | ₹10283.75 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.14347 | Lithium tetrafluoroborate for synthesis | 14283-07-9 | 10G | ₹5740 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 451622 | Lithium tetrafluoroborate ultra dry, powder, 99.99% trace metals basis | 14283-07-9 | 25G | ₹34520.93 | 2022-06-14 | Buy |
Lithium tetrafluoroborate Chemical Properties,Uses,Production
Chemical Properties
white powder
Uses
Lithium tetrafluoroborate is a mild Lewis acid for Diels-Alder reactions. Catalyst for mild and efficient aminolysis of oxiranes. It is a reagent used in the preparation of rechargeable lithium-ion batteries.
General Description
This product has been enhanced for energy efficiency.
Purification Methods
Dissolve it in THF just below its solubility, filter from insoluble material and evaporate it to dryness in a vacuum below 50o. Wash the residue with dry Et2O, and pass dry N2 gas over the solid and finally heat it in an oven at 80-90o. Its solubility in Et2O is 1.3g in 100mL at 25o; in THF it is 71g in 100mL at 25o. It is hygroscopic and is an IRRITANT. [Elliott et al. J Am Chem Soc 74 5211 1952, 75 1753 1953.]
Lithium tetrafluoroborate Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 362)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| SYNOVA CHEMICALS | +91-9920741772 +91-9920741772 | Mumbai, India | 428 | 58 | Inquiry |
| Merck Ltd | +91-2262109800 +91-2262109000 | Maharashtra, India | 272 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6700 | 30 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6100 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6768 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6905 | 58 | Inquiry |
| Sisco Research Laboratories Pvt. Ltd. | +91-22-4268 5800 | Mumbai, India | 4315 | 58 | Inquiry |
| Triveni chemicals | 08048762458 | New Delhi, India | 6088 | 58 | Inquiry |
| Metal Trading | 07210141248 | Gujarat, India | 12 | 58 | Inquiry |
| Harshil Industries | 08046075068 | Gujarat, India | 63 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| SYNOVA CHEMICALS | 58 |
| Merck Ltd | 58 |
| CHEMSWORTH | 30 |
| A.J Chemicals | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| Sisco Research Laboratories Pvt. Ltd. | 58 |
| Triveni chemicals | 58 |
| Metal Trading | 58 |
| Harshil Industries | 58 |
Related articles
- Lithium Tetrafluoroborate: Applications in the Development of Lithium Batteries and its Toxicity
- Lithium tetrafluoroborate (LiBF4) is widely used as an electrolyte for primary and secondary batteries.
- Dec 10，2024
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LithiumTetrafluoroborate>
14283-07-9 Lithium tetrafluoroborate
Lithium Tetraflouroborate Dried, 99%, water 1%
LITHIUM BOROFLUORIDE
LiBF4
14283-07-9
BF4Li
LiBF4
BFLi2O2
B (Classes of Boron Compounds)
Tetrafluoroborates
Li (Lithium) Compounds
Typical Metal Compounds
Classes of Metal Compounds
halometallate salts
B (Classes of Boron Compounds)
Classes of Metal Compounds
Li (Lithium) Compounds
Tetrafluoroborates