(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Structure
CAS No.
1517-82-4
Chemical Name:
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
Synonyms
(S)-p-toL;(1R,2S,5R)-(-)-MenthyL;menthyl p-toluenesulfinate;(S)-(-)-MENTHYL P-TOLUENESULFINATE;Menthyl (S)-4-methylbenzenesulfinate;(?-(1R)-Menthyl (S)-p-toluenesulfinate;(-)-Menthyl (S)-4-methylbenzenesulfinate;(-)-(1R)-MENTHYL (S)-TOLUENE-4-SULFINATE;(-)-(1R)-Menthyl (S)-toluene-4-sulfinate;(1R,2S,5R)-MENTHYL (S)-P-TOLUENESULFINATE
CBNumber:
CB6129035
Molecular Formula:
C17H26O2S
Molecular Weight:
294.45
MOL File:
1517-82-4.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Properties

Melting point 99-104 °C
Boiling point 402.3±38.0 °C(Predicted)
Density 1.08
refractive index -199 ° (C=1.5, Acetone)
storage temp. -20°C
solubility Acetone (Slightly), Chloroform (Slightly)
form Solution
color Yellow to brown or gray
optical activity [α]20/D 195°, c = 2 in acetone
BRN 3207468

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Safety Statements  22-24/25
WGK Germany  3
HS Code  29309090

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 278750 (1R,2S,5R)-(−)-Menthyl (S)-p-toluenesulfinate 98% 1517-82-4 10G ₹15187.48 2022-06-14 Buy
TCI Chemicals (India) M1044 (1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate 1517-82-4 5G ₹6800 2022-05-26 Buy
TCI Chemicals (India) M1044 (1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate 1517-82-4 25G ₹20300 2022-05-26 Buy
Product number Packaging Price Buy
278750 10G ₹15187.48 Buy
M1044 5G ₹6800 Buy
M1044 25G ₹20300 Buy

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Chemical Properties,Uses,Production

Chemical Properties

White crystalline powder

Uses

(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate is a reactant used in the synthesis of sulfoxide pincer complexes of Mg, Rh and Ir.

General Description

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis.

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(S)-(-)-Menthyl p-toluenesulfinate, (-)-(1R)-Menthyl (S)-p-toluenesulfinate 4-Methylbenzenesulfinic acid (1R)-2α-isopropyl-5β-methylcyclohexane-1β-yl ester 4-Methylbenzenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester p-Toluenesulfinic acid (1R,1β)-2α-isopropyl-5β-methylcyclohexyl ester p-Toluenesulfinic acid (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl ester p-Toluenesulfinic acid (1R,3R,4S)-menthyl ester p-Toluenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester (1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate,98% [S(S)]-4-Methylbenzenesulfinic acid (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester Menthyl (S)-4-methylbenzenesulfinate (S)-((1R,2S,5R)-2-isopropyl-5-Methylcyclohexyl) 4-Methylbenzenesulfinate (-)-Menthyl (S)-4-methylbenzenesulfinate (1S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFITE (-)-(1R)-MENTHYL (S)-TOLUENE-4-SULFINATE (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE (1R,2S,5R)-MENTHYL (S)-P-TOLUENESULFINATE (S)-(-)-MENTHYL P-TOLUENESULFINATE (S)-(-)-P-TOLUENESULFINIC ACID L-MENTHYL ESTER (?-(1R)-Menthyl (S)-p-toluenesulfinate menthyl p-toluenesulfinate Benzenesulfinic acid, 4-methyl-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester, [S(S)]- (S)-p-toL (1R,2S,5R)-(-)-MenthyL (1R,2S,5R)-(-)-Menthyl(S)-p-Toluenesulfinate> 4-Methylbenzenesulfinic acid (1R,3R,4S)-p-menthane-3- (-)-(1R)-Menthyl (S)-toluene-4-sulfinate 1517-82-4 Organic Building Blocks Sulfonates/Sulfinates Chiral Building Blocks Terpenes Monocyclic Monoterpenes Asymmetric Synthesis Chiral Building Blocks Organic Building Blocks Sulfonates/Sulfinates chiral Asymmetric Synthesis Biochemistry Monocyclic Monoterpenes Synthetic Organic Chemistry Terpenes