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TRIMETHYL(PHENYLSELENO)SILANE

TRIMETHYL(PHENYLSELENO)SILANE Structure
CAS No.
33861-17-5
Chemical Name:
TRIMETHYL(PHENYLSELENO)SILANE
Synonyms
PHENYLTRIMETHYLSILYLSELENIDE;(TRIMETHYLSILYLSELENO)BENZENE;(PHENYLSELENO)TRIMETHYLSILANE;TRIMETHYL(PHENYLSELENO)SILANE;rimethyl(phenylselanyl)silane;TRIMETHYLSILYL PHENYL SELENIDE;triMethyl(phenylselanyl)silane;Benzene, [(trimethylsilyl)seleno]-;Trimethyl(phenylseleno)silane, tech.;Trimethyl(phenylseleno)silanetech.ca90%
CBNumber:
CB6147002
Molecular Formula:
C9H14SeSi
Molecular Weight:
229.25
MOL File:
33861-17-5.mol
Modify Date:
2022/12/21 16:56:50

TRIMETHYL(PHENYLSELENO)SILANE Properties

Melting point -14--9°
Boiling point 51-53 °C (0.3 mmHg)
Density d2020 1.1960
refractive index 1.5515-1.5555
solubility sol benzene, Et2O, THF, MeCN.
Specific Gravity 1.196
Hydrolytic Sensitivity 7: reacts slowly with moisture/water

SAFETY

Risk and Safety Statements

Hazard Codes  N-T
Risk Statements  50/53-33-23/25
Safety Statements  61-60-45-28A-20/21
TSCA  No

TRIMETHYL(PHENYLSELENO)SILANE Chemical Properties,Uses,Production

Chemical Properties

clear yellow liquid

Physical properties

bp 92–93 °C/5 mmHg.

Uses

Selenating reagent.

Preparation

Phenyl Trimethylsilyl Selenide is conveniently prepared by the reduction of diphenyl diselenide with sodium in THF, followed by silylation of thus formed PhSeNa with chlorotrimethylsilane. In a small scale reaction, silylation of PhSeLi, which can be prepared in situ from metallic selenium and phenyllithium in THF, is alternatively utilized.

TRIMETHYL(PHENYLSELENO)SILANE Preparation Products And Raw materials

Raw materials

Preparation Products

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Brunschwig chemie +31 (0)20 611 31 33 The Netherlands 4997 67 Inquiry
(PHENYLSELENO)TRIMETHYLSILANE PHENYLTRIMETHYLSILYLSELENIDE (TRIMETHYLSILYLSELENO)BENZENE TRIMETHYLSILYL PHENYL SELENIDE TRIMETHYL(PHENYLSELENO)SILANE Trimethyl(phenylseleno)silane,tech.ca90% Trimethyl(phenylseleno)silanetech.ca90% Trimethyl(phenylseleno)silane, tech., ca. 90% TRIMETHYL(PHENYLSELENO)SILANE, TECH., CA 90% Trimethyl(phenylseleno)silane, tech. Trimethyl(phenylseleno)silane,ca. 90%,tech. triMethyl(phenylselanyl)silane Benzene, [(trimethylsilyl)seleno]- rimethyl(phenylselanyl)silane 33861-17-5 C9H14SeSi