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BITTER ORANGE

BITTER ORANGE Structure
CAS No.
68916-04-1
Chemical Name:
BITTER ORANGE
Synonyms
FEMA 2823;Bigaradeoil;BITTER ORANGE;bitterorangeoil;Orangebitteroil;Neroli bigarade;Sour orange oil;Oils,orange,sour;oils,bitterorange;Nerolioil,selecta
CBNumber:
CB6206648
Molecular Formula:
Molecular Weight:
0
MOL File:
Mol file
Modify Date:
2023/5/25 18:01:14

BITTER ORANGE Properties

FEMA 2823 | ORANGE PEEL BITTER OIL (CITRUS AURANTIUM L.)
Odor at 100.00 %. orangeflower
Odor Type floral
EPA Substance Registry System Oils, orange, sour (68916-04-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS08,GHS07,GHS09
Signal word  Danger
Hazard statements  H410-H304-H317-H315
Precautionary statements  P273-P391-P501-P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P264-P280-P302+P352-P321-P332+P313-P362
Toxicity The acute oral LD50 value in rats was reported as > 5 g/kg (Owen, 1971a). The acute dermal LD50 value in rabbits was reported as > 10 g/kg (Owen, 1971b).

BITTER ORANGE Chemical Properties,Uses,Production

Description

Refer to ORANGE BLOSSOMS, ABSOLUTE.

Chemical Properties

Bitter orange oil is obtained by pressing fresh peel fromthe fruits of C. aurantium L. (Rutaceae). It is produced mainly in Mediterranean countries and is a pale yellow to yellowish-brown liquid with a slightly mandarin-like odor and a somewhat bitter aroma.
d2020 0.840–0.860; n20D 1.472–1.476; α20D +88 ° to +98 °; evaporation residue: 3.5–6%; solubility: 1 vol in ≤8 vol. 90% ethanol. Composition by GC: limonene 93–95%; linalyl acetate 0.5–1%; decanal tr. ?0.3% (data of Mediterranean type; data for American and Equatorial type may differ slightly).
Although limonene is also the main component, at 92.95–95%, the content of other constituents differs from that of sweet orange oil; that is, its aldehyde content is lower and its ester (e.g., linalyl and geranyl acetate) content is higher.
In addition to the fruits, other parts of bitter orange tree, C. aurantium L., also serve for the production of fragrant raw materials: Neroli oil and orange flower absolute are obtained from the flowers, and the twigs and leaves yield the so-called petitgrain bigarade oil.
Worldwide production of bitter orange oil ismuch lower than that of other pressed peel oils. The preferred quality is produced in Spain (Seville bitter orange oil). Bitter orange oil is predominantly used for flavoring alcoholic beverages (liqueurs).

Physical properties

Oil obtained by expression has a deep-yellow color.

Occurrence

Found in the fresh peel of the fruit Citrus aurantium Linne (Fam. Rutaceae).

Preparation

By the expression of the fresh peel of the fruit, Citrus aurantium Linne, by various methods, without the use of heat.

Essential oil composition

Dried flowers and leaves of bitter orange had a similar flavonoid pattern, but the flavonoid levels of flowers were higher than those of leaves. The mean levels of the principal flavonoid compounds were, respectively, total flavonoids 12.35 and 1.06%, neohesperidin 5.44 and 0.08%, naringin 1.93 and 0.06%, eriocitrin 0.38 and 0.25%.

BITTER ORANGE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 45)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Grassland Essential Oils 08066085837Ext 347 Pune, India 1 58 Inquiry
Sivaroma Naturals Private Limited 08046052702 Uttar Pradesh, India 44 58 Inquiry
M/S A And A Perfumes And Fragrances 08045907200 Uttar Pradesh, India 28 58 Inquiry
ANHUI WITOP BIOTECH CO., LTD +8615255079626 China 23556 58 Inquiry
Dideu Industries Group Limited +86-29-89586680 +86-15129568250 China 26165 58 Inquiry
Changsha Staherb Natural Ingredients Co., Ltd. +86-0731-84213302 +8618374838656 China 1025 58 Inquiry
GIHI CHEMICALS CO.,LIMITED +8618058761490 China 49999 58 Inquiry
Hengdian Group . / Zhejiang Hengdian Imp. & Exp. Co., Ltd. 0571-87632700 China 129 64 Inquiry
Jiangxi Xinsen Natural Vegetable Oil Co., Ltd. 0796-8284836 17379666713 China 290 58 Inquiry
Jiangxi Xuesong Natural Medicinal Oil Co. LTD 18679669723 18679669723 China 331 58 Inquiry
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