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DIETHYL DIETHYLMALONATE

DIETHYL DIETHYLMALONATE Structure
CAS No.
77-25-8
Chemical Name:
DIETHYL DIETHYLMALONATE
Synonyms
DEDEM;NSC 8710;DIETHYLMALONIC ESTER;ETHYL DIETHYLMALONATE;Diethyldiethylmalonat;DIETHYL DIETHYLMALOTE;DIETHYL DIETHYLMALONATE;Dithyl2,2-diethylmalonate;Diethyldiethylpropanedioate;Diethyl 2,2-diethylmalonate
CBNumber:
CB6315360
Molecular Formula:
C11H20O4
Molecular Weight:
216.27
MOL File:
77-25-8.mol
MSDS File:
SDS
Modify Date:
2024/6/17 17:12:53

DIETHYL DIETHYLMALONATE Properties

Boiling point 228-230 °C (lit.)
Density 0.99 g/mL at 25 °C (lit.)
refractive index n20/D 1.423(lit.)
Flash point 202 °F
storage temp. Sealed in dry,Room Temperature
solubility Chloroform, Methanol (Sparingly)
form Oil
color Clear Colourless
Specific Gravity 0.988 (20/4℃)
Merck 14,3823
LogP 2.463 (est)
CAS DataBase Reference 77-25-8(CAS DataBase Reference)
EPA Substance Registry System Propanedioic acid, diethyl-, diethyl ester (77-25-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
Safety Statements  24/25
WGK Germany  3
TSCA  Yes
HS Code  29171900
NFPA 704
0
0 0

DIETHYL DIETHYLMALONATE price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 156817 Diethyl diethylmalonate 98% 77-25-8 25G ₹4167.63 2022-06-14 Buy
TCI Chemicals (India) D0867 Diethyl Diethylmalonate min. 97.0 % 77-25-8 25ML ₹2800 2022-05-26 Buy
ALFA India ALF-B23810-36 Diethyl diethylmalonate, 98% 77-25-8 500g ₹24235 2022-05-26 Buy
TCI Chemicals (India) D0867 Diethyl Diethylmalonate min. 97.0 % 77-25-8 500ML ₹8000 2022-05-26 Buy
ALFA India ALF-B23810-22 Diethyl diethylmalonate, 98% 77-25-8 100g ₹12464 2022-05-26 Buy
Product number Packaging Price Buy
156817 25G ₹4167.63 Buy
D0867 25ML ₹2800 Buy
ALF-B23810-36 500g ₹24235 Buy
D0867 500ML ₹8000 Buy
ALF-B23810-22 100g ₹12464 Buy

DIETHYL DIETHYLMALONATE Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid. Quite powerful, fruity, Pear-like odor.

Uses

Diethyl Diethylmalonate is an intermediate in the synthesis of Barbital (B118500), a prototype of the barbiturate hypnotics.

Production Methods

This ester has been suggested for use in flavor compositions, but it is not sufficiently stable enough to become very popular. The ester has occasionally found use in perfume compositions, mainly as a modifier in fruity notes, winey top note bases, etc. Diethyl diethylmalonate is produced (several methods) e. g. by condensing Ethyl acetate with Ethyl oxalate, heat the resultant Oxaloacetic ester, and esterify the formed Diethyl malonic acid.

Synthesis Reference(s)

Journal of the American Chemical Society, 64, p. 578, 1942 DOI: 10.1021/ja01255a034

DIETHYL DIETHYLMALONATE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 207)Suppliers
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Enzal Chemicals India Limited +91-9930897773 +91-9930897773 New Delhi, India 25 58 Inquiry
SNA HEALTHCARE PVT LTD +91-8652842416 +91-8652842416 Mumbai, India 88 58 Inquiry
ALS INDIA LIFE SCIENCES +91-8977036379 +91-8977036379 Hyderabad, India 1879 58 Inquiry
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A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
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Reax Chemicals 08048372701Ext 416 Hyderabad, India 4223 58 Inquiry
Henan Fengda Chemical Co., Ltd +86-371-86557731 +86-13613820652 China 20323 58 Inquiry
Henan Tianfu Chemical Co.,Ltd. +86-0371-55170693 +86-19937530512 China 21675 55 Inquiry
DIETHYLMALONIC ESTER 2,2-diethyl-malonicaciddiethylester Diethyl 2,2-diethylmalonate Diethyldiethylpropanedioate Diethylmalonate diethyl ester Diethylpropanedioicaciddiethylester diethyl-propanedioicacidiethylester Malonic acid, diethyl-, diethyl ester Propanedioic acid, diethyl-, diethyl ester diethyl 3,3-pentanedicarboxylate 2,2-Diethylpropanedioic acid diethyl ester Pentane-3,3-dicarboxylic acid diethyl ester Diethyl diethylmalonate,98% ETHYL DIETHYLMALONATE DEDEM DIETHYLYLMALONIC ACID DIETHYL ESTER DIETHYLMALONIC ACID DIETHYL ESTER Diethyldiethylmalonat Diethyl DiethylMalonate Diethyl NSC 8710 Propanedioic acid,2,2-diethyl-, 1,3-diethyl ester Diethyl DiethylMalonate, 97.0%(GC) Dithyl2,2-diethylmalonate DIETHYL DIETHYLMALOTE DIETHYL DIETHYLMALONATE 2-ethoxycarbonyl-2-ethylbutanoate Diethyl Diethylmalonate > diethyl 2,2-diethylpropanedioate 77-25-8 C2H52CCO2C2H52 C2H52CCOOC2H52 Carbonyl Compounds C10 to C11 Building Blocks Organic Building Blocks Esters API intermediates Pharmaceutical Intermediates