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2-Nonenal

2-Nonenal  Structure
CAS No.
2463-53-8
Chemical Name:
2-Nonenal
Synonyms
Nsc20746;2-nonenal;FEMA 3213;NON-2-ENAL;T2 NONENAL;2-NONEN-1-AL;2-TRANS-NONENAL;β-Hexylacrolein;(2Z)-NON-2-ENAL;α-Nonenyl aldehyde
CBNumber:
CB6427997
Molecular Formula:
C9H16O
Molecular Weight:
140.22
MOL File:
2463-53-8.mol
MSDS File:
SDS
Modify Date:
2024/5/16 10:38:43

2-Nonenal Properties

Melting point -28°C (estimate)
Boiling point 88-90 °C12 mm Hg(lit.)
Density 0.846 g/mL at 25 °C(lit.)
vapor density >1 (vs air)
FEMA 3213 | 2-NONENAL
refractive index n20/D 1.453(lit.)
Flash point 184 °F
color White to sltly yellow liquid
Odor fatty, violet odor
Odor Type fatty
JECFA Number 1362
LogP 3.17
CAS DataBase Reference 2463-53-8(CAS DataBase Reference)
NIST Chemistry Reference 2-Nonenal(2463-53-8)
EPA Substance Registry System 2-Nonenal (2463-53-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3
RTECS  RA8509050
Toxicity LD50 orl-rat: 5 g/kg FCTOD7 20(Suppl),775,825 g/kg FCTOD7 20,775,82

2-Nonenal Chemical Properties,Uses,Production

Description

2-Nonenal has a very powerful, penetrating fatty odor in concentrated form. It is orris-like, waxy, and quite pleasant on dilution. The odor is reminiscent of dried orange peels. Prepared by oxidation of 9,10,12-trihydroxy stearic acid (Criegee reaction).

Chemical Properties

2-Nonenal has a very powerful, penetrating, fatty odor in concentrated form. The odor is orris-like, waxy and quite pleasant on dilution. The odor is also reported as reminiscent of dried orange peels

Occurrence

Reported found in orris oil, melon, peach, asparagus, carrot, peas, tomato, wheat and crisp breads, Russian cheeses, caviar, butter, fish oil, cooked beef, mutton, pork, and their fats, hop oil, cognac, roasted filberts and peanuts, soybean, beans, sesame seed, mango, rice, beer, and potato chips

Uses

The concentration in a perfume oil may be of the order of magnitude of 0.01 to 0.03%. An addition of 0.02% of 2-Nonenal to a normal grade of "gamma" -Methylionone will produce a distinctly ("orrisy") perceptible effect, desirable and attractive in the opinion of many perfumers.

Preparation

By oxidation of 9,10,12-trihydroxystearic acid (Criegee reaction)

Definition

ChEBI: An enal consisting of non-2-ene having an oxo group at the 1-position.

Safety Profile

Moderately toxic by skin contact. Mddly toxic by ingestion. A severe skin irritant. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.

2-Nonenal Preparation Products And Raw materials

Raw materials

Preparation Products

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NON-2-ENAL TIMTEC-BB SBB006609 TRANS-2-NONEN-1-AL 2-TRANS-NONENAL NONEN-2-AL-1 100 P. TRANS-2-NONENAL, NATURAL α-Nonenyl aldehyde β-Hexylacrolein Nsc20746 2-NONEN-1-AL 2-nonenal ALPHA-NONENYL ALDEHYDE BETA-HEXYLACROLEIN FEMA 3213 T2 NONENAL (2Z)-NON-2-ENAL 2-Nonenal USP/EP/BP 2463-53-8 2-Nonenal 2-Nonenal (6CI, 7CI, 8CI, 9CI, ACI) 2463-53-8 C9 Carbonyl Compounds Building Blocks Aldehydes Organic Building Blocks aldehyde Flavor