(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester

CAS No.: 13811-71-7

Chemical Name:: (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester

Synonyms: DET;D-DET;D-tartrate;DIETHYL D-TARTRATE;(-)-Diethyl D-tartrate;D(-)diethyl tartarate;(2R,3R)-diethyl 2,3-dihydroxysuccinate;ETHYL TARTRATE;diethyl (2S,3S)-2,3-dihydroxybutanedioate;(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl

CBNumber:: CB7105982

Molecular Formula:: C8H14O6

Molecular Weight:: 206.19

MOL File:: 13811-71-7.mol

MSDS File:: SDS

Modify Date:: 2024/8/19 17:35:41

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(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Properties

Melting point	17 °C
Boiling point	162 °C/19 mmHg (lit.)
alpha	-9 º (neat)
Density	1.205 g/mL at 20 °C (lit.)
refractive index	n20/D 1.446(lit.)
Flash point	200 °F
storage temp.	Store below +30°C.
solubility	Chloroform (Slightly), Water (Slightly)
pka	11.61±0.20(Predicted)
form	Viscous Liquid
color	Clear colorless
Specific Gravity	1.21
optical activity	[α]23/D 8.5°, neat
Water Solubility	insoluble
Merck	14,3855
BRN	1727143
CAS DataBase Reference	13811-71-7(CAS DataBase Reference)
NIST Chemistry Reference	Butanedioic acid, 2,3-dihydroxy-, diethyl ester, [S-(R,R)]-(13811-71-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H227

Precautionary statements

P210e-P280a-P370+P378a-P403+P235-P501a

Hazard Codes

Risk Statements

36/37/38

Safety Statements

24/25-36-26

WGK Germany

Hazard Note

Irritant

HS Code

29181300

NFPA 704

	1
0		0

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester price More Price(12)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	213969	(−)-Diethyl D-tartrate ≥99%	13811-71-7	5G	₹1948.5	2022-06-14	Buy
Sigma-Aldrich(India)	213969	(−)-Diethyl D-tartrate ≥99%	13811-71-7	25G	₹6083.65	2022-06-14	Buy
Sigma-Aldrich(India)	8.18685	(2S,3S)-(-)-Diethyl tartrate for synthesis	13811-71-7	25ML	₹14860	2022-06-14	Buy
Sigma-Aldrich(India)	213969	(−)-Diethyl D-tartrate ≥99%	13811-71-7	500G	₹14862.73	2022-06-14	Buy
ALFA India	ALF-A17992-22	(-)-Diethyl D-tartrate, 99%	13811-71-7	100g	₹12938	2022-05-26	Buy

Product number	Packaging	Price	Buy
213969	5G	₹1948.5	Buy
213969	25G	₹6083.65	Buy
8.18685	25ML	₹14860	Buy
213969	500G	₹14862.73	Buy
ALF-A17992-22	100g	₹12938	Buy

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Chemical Properties,Uses,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Diethyl D(-)-tartrate is mainly used in chiral pharmaceuticals, chiral intermediates and chiral catalysts. It can be used with titanium in enolic asymmetric epoxidization. The compound d-alpha-tocopherol is the principal compound present in natural vitamin E sources. At present, d-alpha-tocopherol and other tocopherol derivatives are used in pharmaceuticals, foods and animal feeds. It is used as a food additive.

Purification Methods

Distil the esters under high vacuum and store them under vacuum or in an inert atmosphere in a desiccator in round bottomed flasks equiped with a vacuum stopcock. They have also been distilled by Kügelrohr distillation and/or by 'wiped-film' molecular distillation. They are slightly soluble in H2O but miscible with EtOH and Et2O. [Gao et al. J Am Chem Soc 109 5770 (5771) 1987, IR: Pristera Anal Chem 25 844 1953, Beilstein 3 III 1025 for D-(-), 3 IV 1232 for L(+).]

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Preparation Products And Raw materials

Raw materials

DL-Tartaric acid

Preparation Products

(-)-DIOP (R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Suppliers

Global( 571)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
GLR Innovations	+91 9891111994	New Delhi, India	4542	58	Inquiry
KAIVAL CHEMICALS Pvt ltd	+91-8160398972 +91-8160398972	Gujarat, India	50	58	Inquiry
HEMA LABORATORIES	+919700665792	Karnataka, India	15	58	Inquiry
Laksh Finechem Pvt.Ltd.	+91-9978522233 +91-78522233	Gujarat, India	55	58	Inquiry
Rivashaa Agrotech Biopharma Pvt. Ltd.	+91-26463395 +91-7926462688	Gujarat, India	1615	58	Inquiry
Ralington Pharma	+91-7948911722 +91-9687771722	Gujarat, India	1350	58	Inquiry
Zehron Chemicals Pvt Ltd	+91-9879531306 +91-8980766306	Gujarat, India	13	58	Inquiry
JSK Chemicals	+919879767970	Gujarat, India	3756	58	Inquiry
Integrin Life Sciences. Pvt. Ltd.	+91-4040265469 +91-9849990870	Hyderabad, India	90	58	Inquiry
Everest Organics Limited	+91-4040028838 +91-9440409996	Hyderabad, India	61	58	Inquiry

Supplier	Advantage
GLR Innovations	58
KAIVAL CHEMICALS Pvt ltd	58
HEMA LABORATORIES	58
Laksh Finechem Pvt.Ltd.	58
Rivashaa Agrotech Biopharma Pvt. Ltd.	58
Ralington Pharma	58
Zehron Chemicals Pvt Ltd	58
JSK Chemicals	58
Integrin Life Sciences. Pvt. Ltd.	58
Everest Organics Limited	58

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Spectrum

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester(13811-71-7)IR (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester(13811-71-7)Raman (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester(13811-71-7)FT-IR

13811-71-7((2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester)Related Search:

2,3-Di-O-para-toluoyl-D-tartaric acid (-)-Dibenzoyl-L-tartaric acid monohydrate (+)-Dimethyl L-tartrate (-)-DIBUTYL-D-TARTRATE (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester

Bis(diethyl-D-tartrate glycolato)diboron Diethyl succinate Bis(diethyl-L-tartrate glycolato)diboron (2R,3R)(+)-DIHYDROXYBUTANE-1,4-DIOIC ACID DIETHYL ESTER Bis(diisopropyl-L-tartrate glycolato)diboron

Bis(diisopropyl-D-tartrate glycolato)diboron Diisopropyl D-tartrate (-)-DIBENZYL D-TARTRATE (-)-DI-TERT-BUTYL D-TARTRATE 3-PYRIDYLMETHYL D-TARTRATE

(2S,3S)-(+)-DIETHYL 2,3-O-BENZYLIDENETARTRATE

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(-)-Diethyl D-tartrate, Made froM unnatural tartaric acid, 99% 25ML (R,R)-(+)-Weinsaeure-diethylester (-)-Diethyl (2S,3S)-2,3-dihydroxybutane-1,4-dioate, (-)-Diethyl (2S,3S)-2,3-dihydroxysuccinate D-(-)-TARTARIC ACID DIETHYL ESTER (2S,3S)-(-)-DIETHYL TARTRATE (2S,3S)(-)-DIHYDROXYBUTANE-1,4-DIOIC ACID DIETHYL ESTER diethyl [S-(R*,R*)]-tartrate MINUS-TARTARIC ACID DIETHYL ESTER DIETHYL D-TARTRATE, 99+% D (-)Diethy tartrate (-)-Diethyl D-tartrate, made from unnatural tartaric acid, 99% Butanedioic acid, 2,3-dihydroxy-, diethyl ester, S-(R*,R*)- Diethyl-L-(+)-Tartarte D-(-)-WEINSURE-DIETHYLESTER (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Diethyl D- tartrate D-Tartaric acid diethyl ester D-ethyl tartrate Diethyl-D(-)-Tartrate99.0%Min (-)-Diethyl d-tartrate, 99%, made from unnatural tartaric acid (2S,3S)-2,3-Dihydroxysuccinic acid diethyl ester Diethyl dextro-tartrate (2S,3S)(-)-Dihydroxy EsoMeprazo interMediate C D- two ethyl acetate Dihydroxybutane-1,4-dioic acid diethyl ester D-Tartaric Acid Diethyl Ester,99%e.e. (2S,3S)-(-)-Diethyl tartrate for synthesis dlethyl-tartrate (-)-DIETHYL-2,3-DIHYDROXYSUCCINATE (-)-DIETHYL-D-TARTRATE DIETHYL D-(-)-TARTRATE [-]-TARTARIC ACID DIETHYL ESTER D(-)-DIETHYL TARTRATE D-(-)-Diethyl L-tartrate (-)-Diethyl D-tartrate >=99% Diethyl Tartrate D(-) (-)-Diethyl (2S,3S)-2,3-dihydroxybutane-1,4-dioate, (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester 13811-71-7 3S)(-)-Dihydroxybutane-1 4-dioic acid diethyl ester diethyl laevo-tartrate DI-ETHYL-D-TARTRATE (Pure) 13811-71-7 Diethyl-D-Tartarate (13811-71-7) (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester in stock Factory Butanedioic acid, 2,3-dihydroxy-, 1,4-diethyl ester, (2S,3S)- D-tartrate (2R,3R)-diethyl 2,3-dihydroxysuccinate (-)-Diethyl D-tartrate (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl D(-)diethyl tartarate ETHYL TARTRATE DIETHYL D-TARTRATE DET D-DET diethyl (2S,3S)-2,3-dihydroxybutanedioate (-)-Diethyl tartrate D-(-)-Tartaric Acid Diethyl Ester Diethyl-D-tartrate ( - ) Di Ethyl D Tartrate