2,3,4,6-Tetra-O-benzyl-D-glucopyranose
![2,3,4,6-Tetra-O-benzyl-D-glucopyranose Structure](CAS/GIF/4132-28-9.gif)
- CAS No.
- 4132-28-9
- Chemical Name:
- 2,3,4,6-Tetra-O-benzyl-D-glucopyranose
- Synonyms
- (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)Methyl)tetrahydro-2H-pyran-2-ol;2,3,4, 6-4-o-benzyl-d-pyranoglucose;ucopyranose;2,3,4,6-Tetra-O-benz;Voglibose Impurity 4;Garlic oil 8000-78-0;benzyl-D-glucopyranose;Voglibose Intermediates;2,3,4,6-TETRABENZYL-D-GLUCOSE;Tetra-O-benzyl-D-glucopyranose
- CBNumber:
- CB7194124
- Molecular Formula:
- C34H36O6
- Molecular Weight:
- 540.65
- MOL File:
- 4132-28-9.mol
- Modify Date:
- 2023/11/17 16:15:53
Melting point | 145-149 °C(lit.) |
---|---|
Boiling point | 672.4±55.0 °C(Predicted) |
Density | 1.22±0.1 g/cm3(Predicted) |
storage temp. | Sealed in dry,Store in freezer, under -20°C |
solubility | Soluble in chloroform |
pka | 11.87±0.70(Predicted) |
form | Solid |
color | White to Off-White |
optical activity | [α]20/D +49±2°, c = 2% in dioxane |
InChIKey | OGOMAWHSXRDAKZ-BKJHVTENSA-N |
SMILES | OC1O[C@H](COCC2=CC=CC=C2)[C@@H](OCC2=CC=CC=C2)[C@H](OCC2=CC=CC=C2)[C@H]1OCC1=CC=CC=C1 |
CAS DataBase Reference | 4132-28-9(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P280-P271 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36-24/25 | |||||||||
WGK Germany | 3 | |||||||||
HS Code | 29400090 | |||||||||
NFPA 704 |
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2,3,4,6-Tetra-O-benzyl-D-glucopyranose price More Price(6)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | T0531 | 2,3,4,6-Tetra-O-benzyl-D-glucopyranose ≥98% (TLC) | 4132-28-9 | 5G | ₹24161.4 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | T0531 | 2,3,4,6-Tetra-O-benzyl-D-glucopyranose ≥98% (TLC) | 4132-28-9 | 25G | ₹68727.93 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 86730 | 2,3,4,6-Tetra-O-benzyl-D-glucopyranose ≥98.0% (TLC) | 4132-28-9 | 1G | ₹3258.33 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 86730 | 2,3,4,6-Tetra-O-benzyl-D-glucopyranose ≥98.0% (TLC) | 4132-28-9 | 5G | ₹11755.95 | 2022-06-14 | Buy |
TCI Chemicals (India) | T1914 | 2,3,4,6-Tetra-O-benzyl-D-glucopyranose | 4132-28-9 | 1G | ₹3500 | 2022-05-26 | Buy |
2,3,4,6-Tetra-O-benzyl-D-glucopyranose Chemical Properties,Uses,Production
Description
2,3,4,6-Tetra-O-benzyl-D-glucopyranose is an important D-glucopyranose derivative, which is often used as a pharmaceutical intermediate in the synthesis of derivatives for the treatment of Alzheimer's disease, diabetes, and cancer.
Chemical Properties
White Crystaline Solid
Uses
2,3,4,6-Tetra-O-benzyl-D-glucopyranose (cas# 4132-28-9) is a compound useful in organic synthesis. For example, it enables the preparation of α-glucopyranosyl chloride as well as 1-C-α-D-glucopyranosyl derivatives; it can also be used in the preparation of important D-glucopyranosyl derivatives for glucosylation and other reactions.
Synthesis
Add 19.4g of 2,3,4,6-tetra-O-benzyl-β-D-glucosinolate to 500mL of acetone, and add 18.7g of N-bromosuccinyl in batches with stirring Imine (NBS), after the addition, react at 25°C for 0.5h. Most of the acetone was evaporated under reduced pressure, and a white solid was precipitated, which was diluted by adding 200 mL of 1mol/L hydrochloric acid and allowed to stand at -18°C for 3h. After suction filtration, the filter cake was washed with cold absolute ethanol, and recrystallized with absolute ethanol-cyclohexane to obtain 15.6 g of white flocculent solid 2,3,4,6-Tetra-O-benzyl-D-glucopyranose with a yield of 96.6%.
2,3,4,6-Tetra-O-benzyl-D-glucopyranose Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
SYNGREEN LIFESCIENCES PVT.LTD | +919849474297 | Telangana, India | 82 | 58 | Inquiry |
chromsynth pvt ltd | +919704220374 | Hyderabad, India | 244 | 58 | Inquiry |
JLS Laboratories Pvt Limited | +91 8790545679 | Hyderabad, India | 62 | 58 | Inquiry |
Hyderabad | +91-9676447615 +91-9676447615 | Telangana, India | 192 | 58 | Inquiry |
Vardhaman P Golechha | 9704422000 | Telangana, India | 294 | 58 | Inquiry |
SVH BIOSCIENCES | +91-6303499280 +91-6303499280 | Hyderabad, India | 478 | 58 | Inquiry |
AVIGYABIOSCIENCES PRIVATE LIMITED | +91-9849533087 +91-9849533087 | Telangana, India | 156 | 58 | Inquiry |
Ceyone Life Sciences | +91-8455293199 +91-9348570999 | AndhraPradesh, India | 20 | 58 | Inquiry |
Oceanic Pharmachem Pvt., Ltd. (OPPL) | 91-22-42128600 | Maharashtra, India | 947 | 58 | Inquiry |
Supplier | Advantage |
---|---|
GLR Innovations | 58 |
SYNGREEN LIFESCIENCES PVT.LTD | 58 |
chromsynth pvt ltd | 58 |
JLS Laboratories Pvt Limited | 58 |
Hyderabad | 58 |
Vardhaman P Golechha | 58 |
SVH BIOSCIENCES | 58 |
AVIGYABIOSCIENCES PRIVATE LIMITED | 58 |
Ceyone Life Sciences | 58 |
Oceanic Pharmachem Pvt., Ltd. (OPPL) | 58 |