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DIETHYL (CHLOROMETHYL)PHOSPHONATE

DIETHYL (CHLOROMETHYL)PHOSPHONATE Structure
CAS No.
3167-63-3
Chemical Name:
DIETHYL (CHLOROMETHYL)PHOSPHONATE
Synonyms
NSC 67753;Diethyl (chloromethyl);DIETHYL (CHLOROMETHYL)PHOSPHONATE;[DIETHYL-(CHLORMETHYL)]-PHOSPHONAT;Diethyl chloromethylphosphonate 97%;Diethyl P-(chloromethyl)phosphonate;Diethyl (chloromethyl)phosphonate,98%;Diethyl (Chloromethyl)phosphonate >Diethyl(chloromethyl)phosphonate, 97 %;(chloromethyl)-phosphonicacidiethylester
CBNumber:
CB7297881
Molecular Formula:
C5H12ClO3P
Molecular Weight:
186.57
MOL File:
3167-63-3.mol
MSDS File:
SDS
Modify Date:
2024/7/8 20:25:11

DIETHYL (CHLOROMETHYL)PHOSPHONATE Properties

Boiling point 109-110 °C10 mm Hg(lit.)
Density 1.2 g/mL at 25 °C(lit.)
refractive index n20/D 1.437(lit.)
Flash point 188 °F
storage temp. 2-8°C
form Liquid
Specific Gravity 1.2
color Clear colorless to light yellow
BRN 1363361
EPA Substance Registry System Phosphonic acid, (chloromethyl)-, diethyl ester (3167-63-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
Hazard Note  Irritant
HS Code  29319090
NFPA 704
1
1 0

DIETHYL (CHLOROMETHYL)PHOSPHONATE price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 263613 Diethyl chloromethylphosphonate 97% 3167-63-3 1ML ₹9764.15 2022-06-14 Buy
TCI Chemicals (India) D4588 Diethyl (Chloromethyl)phosphonate min. 98.0 % 3167-63-3 1G ₹6200 2022-05-26 Buy
TCI Chemicals (India) D4588 Diethyl (Chloromethyl)phosphonate min. 98.0 % 3167-63-3 5G ₹19800 2022-05-26 Buy
Product number Packaging Price Buy
263613 1ML ₹9764.15 Buy
D4588 1G ₹6200 Buy
D4588 5G ₹19800 Buy

DIETHYL (CHLOROMETHYL)PHOSPHONATE Chemical Properties,Uses,Production

Chemical Properties

Clear colorless to light yellow liquid

Uses

Reactant involved in:

  • Subsequent alkylation after nucleophilic substitution
  • One-pot alkylation-boration of α-haloalkylphosphonates
  • Synthesis of cyclpentane and pyrrolidine derivatives via regioselective insertion reactions
  • Phosphorylation leading to P-containing cyclopropanes
  • Wadsworth-Emmons reactions
  • Ring expansion of zircnacycles via carbenoid insertion

Synthesis Reference(s)

Tetrahedron Letters, 28, p. 3799, 1987 DOI: 10.1016/S0040-4039(00)96387-1

DIETHYL (CHLOROMETHYL)PHOSPHONATE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 133)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Shaanxi Dideu Medichem Co. Ltd +86-029-81138252 +86-18789408387 China 3957 58 Inquiry
Capot Chemical Co.,Ltd. 571-85586718 +8613336195806 China 29798 60 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 18642 58 Inquiry
Zhejiang ZETian Fine Chemicals Co. LTD +8618957127338 China 2136 58 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29824 58 Inquiry
Zhengzhou Alfa Chemical Co.,Ltd +8618530059196 China 13341 58 Inquiry
ANHUI WITOP BIOTECH CO., LTD +8615255079626 China 23555 58 Inquiry
Alfa Chemistry United States 2344 58 Inquiry
Aston Chemical 13000000000 United States 1634 58 Inquiry
(chloromethyl)-phosphonicacidiethylester DIETHYL (CHLOROMETHYL)PHOSPHONATE [DIETHYL-(CHLORMETHYL)]-PHOSPHONAT Diethyl(chloromethyl)phosphonate, 97 % (Chloromethyl)phosphonic acid diethyl ester Diethyl (chloromethyl)phosphonate,98% NSC 67753 Diethyl chloromethylphosphonate 97% Diethyl (chloromethyl) 1-[chloromethyl(ethoxy)phosphoryl]oxyethane Phosphonic acid P -(chloromethyl)-diethyl ester Diethyl (Chloromethyl)phosphonate > Diethyl P-(chloromethyl)phosphonate 3167-63-3 C5H12ClO3P ClCH2POOC2H52 C-C Bond Formation Olefination Synthetic Reagents Horner-Wadsworth-Emmons Reagents C-C Bond Formation Horner-Wadsworth-Emmons Reagents Olefination