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PENTAERYTHRITOL TRIALLYL ETHER

PENTAERYTHRITOL TRIALLYL ETHER Structure
CAS No.
1471-17-6
Chemical Name:
PENTAERYTHRITOL TRIALLYL ETHER
Synonyms
Triallyl pentaerythritol;PENTAERITHRITOLTRIALLYLETHER;Pentaerythrityl triallyl ether;PENTAERYTHRITOL TRIALLYL ETHER;Pentaerythritol Triallyl Ether,>75%;1-(2-naphthalenyl)-N-phenylethanimine;3-allyloxy-2,2-bis(allyloxymethyl)propan-1-ol;3-(allyloxy)-2,2-bis[(allyloxy)methyl]propanol;3-prop-2-enoxy-2,2-bis(prop-2-enoxymethyl)propan-1-ol;Pentaerythritol triallyl ether / Allyl Pentaerythritol
CBNumber:
CB7359246
Molecular Formula:
C14H24O4
Molecular Weight:
256.34
MOL File:
1471-17-6.mol
Modify Date:
2023/5/17 14:12:08

PENTAERYTHRITOL TRIALLYL ETHER Properties

Boiling point 156-161°C 3mm
Density 0.9850
refractive index 1.4650 (estimate)
storage temp. 2-8°C
pka 14.35±0.10(Predicted)
EPA Substance Registry System Pentaerythritol triallyl ether (1471-17-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H412
Precautionary statements  P273-P305+P351+P338
Risk Statements  10-36/37/38
Safety Statements  16-26-36/37/39
RIDADR  1993

PENTAERYTHRITOL TRIALLYL ETHER Chemical Properties,Uses,Production

Application

Crosslinkers and thickeners for superabsorbent polymers (SAP), unsaturated polyesters, UV curing resins, polyurethane resins, Carbomers.Also used in adhesives in powders coatings and emulsions.

Synthesis

1.jpg
3-(Prop-2-ynyloxy)-2,2-bis((prop-2-ynyloxy)methyl)propan-1-ol (35). An aqueous solution of NaOH (40 wt %, 10 mL) was added to a solution of pentaerythritol (2.00 g, 14.7 mmol) in 15 mL of dimethylsulfoxide (DMSO). The solution was stirred at rt for 30 min. Propargyl bromide (97%, 9.8 mL, 110 mmol) was then added, and the solution was kept at rt for an additional 10 h. The reaction mixture was then poured into 150 mL of EtOAc and washed with H2O (50 mL × 2) as well as brine (50 mL). The organic layer was dried by Na2SO4 and filtered. The filtrate was concentrated, and the residue was purified by FC (EtOAc/hexane = 1/4). 2.29 g of yellowish oil 35 (yield: 62%). 1H NMR (200 MHz, CDCl3) δ: 4.13 (d, 6H, J = 2.4 Hz), 3.69 (d, 2H, J = 6.4 Hz), 3.56 (s, 6H), 2.43 (t, 3H, J = 2.4 Hz).

PENTAERYTHRITOL TRIALLYL ETHER Preparation Products And Raw materials

Raw materials

Preparation Products

PENTAERYTHRITOL TRIALLYL ETHER Suppliers

Global( 82)Suppliers
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PENTAERYTHRITOL TRIALLYL ETHER 3-(allyloxy)-2,2-bis[(allyloxy)methyl]propanol PENTAERITHRITOLTRIALLYLETHER Pentaerythrityl triallyl ether 3-allyloxy-2,2-bis(allyloxymethyl)propan-1-ol 3-prop-2-enoxy-2,2-bis(prop-2-enoxymethyl)propan-1-ol 1-Propanol, 3-(2-propenyloxy)-2,2-bis[(2-propenyloxy)Methyl]- 1-(2-naphthalenyl)-N-phenylethanimine Triallyl pentaerythritol Pentaerythritol Triallyl Ether,>75% 1-Propanol, 3-(2-propen-1-yloxy)-2,2-bis[(2-propen-1-yloxy)methyl]- Pentaerythritol triallyl ether / Allyl Pentaerythritol 1471-17-6