DIETHYL PHENYLTHIOMETHYLPHOSPHONATE

DIETHYL PHENYLTHIOMETHYLPHOSPHONATE Structure
CAS No.
38066-16-9
Chemical Name:
DIETHYL PHENYLTHIOMETHYLPHOSPHONATE
Synonyms
NSC 202497;LABOTEST-BB LT00453966;DIETHYL PHENYLTHIOMETHYLPHOSPHONATE;Diethyl phenylthiomethanephosphonate;Diethyl methylthiobenzyl phosphonate;diethoxyphosphorylmethylsulfanylbenzene;Diethyl (phenylsulfanyl)methylphosphonate;Diethyl[(phenylthio)methyl]phosphonate, 97 %;Phosphonic acid, [(phenylthio)methyl]-, diethyl ester;Phosphonic acid, P-[(phenylthio)methyl]-, diethyl ester
CBNumber:
CB7362624
Molecular Formula:
C11H17O3PS
Molecular Weight:
260.29
MOL File:
38066-16-9.mol
MSDS File:
SDS
Modify Date:
2025/1/9 11:48:14

DIETHYL PHENYLTHIOMETHYLPHOSPHONATE Properties

Boiling point 146-148 °C (0.5 mmHg)
Density 1.17
refractive index 1.53-1.533
Flash point 146-148°C/0.5mm
solubility Difficult to mix.
form Liquid
Specific Gravity 1.174
BRN 1246215
CAS DataBase Reference 38066-16-9(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  37/39-26
HS Code  2931499090
NFPA 704
0
2 0

DIETHYL PHENYLTHIOMETHYLPHOSPHONATE Chemical Properties,Uses,Production

Chemical Properties

clear light yellow liquid

Uses

Diethyl phenylthiomethylphosphonate is used to produce Diethylphosphorylmethylphenylsulfoxid, Chemical reagents, pharmaceutical research, pharmaceutical intermediates.

Application

Diethyl phenylthiomethylphosphonate used for the conversion of aldehydes and ketones to vinyl sulfides, which can be hydrolyzed to yield  homologated aldehydes and ketones.

Preparation

The Arbuzov reaction between phenylthiomethyl chloride (Chloromethyl Phenyl Sulfide) and Triethyl  Phosphite is the most commonly used method of preparation (eq 1).
DIETHYL PHENYLTHIOMETHYLPHOSPHONATE

Synthesis Reference(s)

Synthesis, p. 309, 1978 DOI: 10.1055/s-1978-24736

DIETHYL PHENYLTHIOMETHYLPHOSPHONATE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 51)Suppliers
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Diethyl (phenylsulfanyl)methylphosphonate Diethyl methylthiobenzyl phosphonate Phosphonic acid, [(phenylthio)methyl]-, diethyl ester LABOTEST-BB LT00453966 DIETHYL PHENYLTHIOMETHYLPHOSPHONATE Diethyl phenylthiomethanephosphonate NSC 202497 Diethyl[(phenylthio)methyl]phosphonate, 97 % Phosphonic acid, P-[(phenylthio)methyl]-, diethyl ester diethoxyphosphorylmethylsulfanylbenzene 38066-16-9 C11H17O3PS