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Polyaniline

Polyaniline Structure
CAS No.
25233-30-1
Chemical Name:
Polyaniline
Synonyms
Pani;Anirido;Chebi:53198;POLYANILINE;VERSICON(R);Nigraniline;Pernigraniline;Aniline polyMer;Leucoemeraldine;Poly(benzenamine)
CBNumber:
CB7372142
Molecular Formula:
C6H7N
Molecular Weight:
93.13
MOL File:
25233-30-1.mol
MSDS File:
SDS
Modify Date:
2024/4/15 13:16:09

Polyaniline Properties

Melting point >330 °C(lit.)
Boiling point 116 °C
Density 1.36 g/mL at 25 °C
refractive index 1.85
Flash point 23 °C
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Soluble in sulfuric acid and methanesulfonic acid.
form powder (Infusible)
color Dark green
InChI InChI=1S/C6H7N/c7-6-4-2-1-3-5-6/h1-5H,7H2
InChIKey PAYRUJLWNCNPSJ-UHFFFAOYSA-N
SMILES NC1C=CC=CC=1

SAFETY

Risk and Safety Statements

Hazard Codes  Xn,T,F
Risk Statements  10-20/21-38-67-36-11-61
Safety Statements  25-45-26-16-53
WGK Germany  3
10
NFPA 704
0
0 0

Polyaniline price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 556459 Polyaniline (emeraldine base) average Mw ~5,000 25233-30-1 5G ₹16118.43 2022-06-14 Buy
Sigma-Aldrich(India) 576379 Polyaniline (emeraldine base) average Mw ~100,000 25233-30-1 5G ₹20459.25 2022-06-14 Buy
Sigma-Aldrich(India) 556459 Polyaniline (emeraldine base) average Mw ~5,000 25233-30-1 25G ₹32485.83 2022-06-14 Buy
Sigma-Aldrich(India) 556386 Polyaniline (emeraldine base) average Mw ~50,000 25233-30-1 5G ₹10673.45 2022-06-14 Buy
Sigma-Aldrich(India) 556386 Polyaniline (emeraldine base) average Mw ~50,000 25233-30-1 25G ₹33654.93 2022-06-14 Buy
Product number Packaging Price Buy
556459 5G ₹16118.43 Buy
576379 5G ₹20459.25 Buy
556459 25G ₹32485.83 Buy
556386 5G ₹10673.45 Buy
556386 25G ₹33654.93 Buy

Polyaniline Chemical Properties,Uses,Production

Description

Polyaniline (PANI) is one kind of conductive polymer. It has shown great potential as supercapacitors electrode due to its advantages such as environment friendly, inexpensive, various redox states and excellent electrical conductivity (30–200 S cm? 1). Unfortunately, the solubility of PANI in all kinds of solvents is very poor. Thus, it is really hard to assemble the PANI into sensors. Referring to its chemical structure, many benzene ring structures exist in the molecular backbone, which induce adjacent molecules to form hydrogen bonds, resulting in a high rigidity. Therefore, even a low-concentration solution shows a strong gelation tendency[1].

Uses

Conductive polymerPolyaniline is used in chemical vapor sensors, supercapacitors and biosensors. It is also useful for manufacture of electrical conducting yarns, antistatic coatings, electromagnetic shielding, flexible electrodes and printed circuit board. Further, it is used in antistatic and ESD coatings and corrosion protection.

Definition

ChEBI: A macromolecule composed of repeating imino-1,4-phenylene units.

General Description

Polyaniline (PAni) emeraldine salt can be prepared by protonation of PAni emeraldine base (PAni-EB). PAni-EB forms at pH>7. Its mechanism against corrosive agents has been explained in a study.

Advantages

Polyaniline (PANI) is one of the conducting polymers most used as an anti-corrosion coating. It has the following advantages over other conducting polymers: (1) it can be synthesized easily via chemical or electrochemical means, (2) it can be doped and undoped easily by treatment with aqueous acid and base, (3) it cannot be degraded easily, and (4) the aniline monomer is relatively cheap. The first report of its synthesis dates back to 1862, and its primary application was as a textile dye. It was only during the 1960s that PANI's electrical property was realized[2].

References

[1] Deshmukh, Kalim et al. “Biopolymer Composites With High Dielectric Performance: Interface Engineering.”Biopolymer Composites in Electronics (2017): 27-128.
[2] Leon, A. and R. Advíncula. “Conducting Polymers with Superhydrophobic Effects as Anticorrosion Coating.” Intelligent Coatings for Corrosion Control (2015): 409-430.

Polyaniline Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 125)Suppliers
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Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
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POLYANILINE POLYANILINE, WATER-SOLUBLE VERSICON(R) POLYANILINE, LEUCOMERALDINE BASE Polyaniline, emeraldine salt from p-toluenesulfonic acid Polyaniline, emeraldine salt from hydrochloric acid LEB, Leucoemeraldine base polyaniline Polyaniline, emerladine salt from hydrochloric acid Chebi:53198 Pani Polyaniline (emeraldine base),Emeraldine base polyaniline Polyaniline (leucoemeraldine base),LEB, Leucoemeraldine base polyaniline POLYANILINE, EMERALDINE BASE, AVERAGE M Aniline polyMer Polyaniline (eMeraldine base) average Mw ~100,000 Polyaniline (eMeraldine base) average Mw ~5,000 Polyaniline (eMeraldine base) average Mw ~50,000 Polyaniline (eMeraldine base) average Mw ~65,000 Polyaniline (emeraldine base) average Mw ~10,000 Polyaniline (emeraldine base) average Mw ~20,000 Anirido poly(aniline) macromolecule Conductive Polyaniline POLYANILINE ISO 9001:2015 REACH average Mw ~100,000 Leucoemeraldine Nigraniline Pernigraniline Poly(benzenamine) Polyaniline average Mw ~20,000 Polyaniline average Mw ~10,000 Polyaniline average Mw ~100,000 Polyaniline average Mw ~5,000 Polyaniline average Mw ~65,000 Polyaniline average Mw ~50,000 25233-30-1 C6H7Nx Polymers for ISE Ion Sensor Materials Analytical Chromatography Product Catalog