1-CHLOROBENZOTRIAZOLE

1-CHLOROBENZOTRIAZOLE Structure
CAS No.
21050-95-3
Chemical Name:
1-CHLOROBENZOTRIAZOLE
Synonyms
NSC 186037;N-Chlorobenzotriazole;1-CHLOROBENZOTRIAZOLE;1-chloro-1H-benzotriazole;1H-Benzotriazole, 1-chloro-;1-Chloro-1H-1,2,3-benzotriazole;1-chloro-1H-benzo[d][1,2,3]triazole
CBNumber:
CB7843615
Molecular Formula:
C6H4ClN3
Molecular Weight:
153.57
MOL File:
21050-95-3.mol
MSDS File:
SDS
Modify Date:
2025/1/27 9:38:02

1-CHLOROBENZOTRIAZOLE Properties

Melting point 104-106?C
Boiling point 252.42°C (rough estimate)
Density 1.3647 (rough estimate)
refractive index 1.6010 (estimate)
storage temp. -20°C Freezer, Under Inert Atmosphere
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
pka -0.96±0.30(Predicted)
form Solid
color White to Off-White

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xn
Risk Statements  22-36/37/38
Safety Statements  26
WGK Germany  3
HS Code  29339900

1-CHLOROBENZOTRIAZOLE Chemical Properties,Uses,Production

Chemical Properties

White Solid

Application

Used as positive halogen reagent for mild oxidations and selective chlorinations.

Synthesis

1-Chlorobenzotriazole is prepared by treat benzotriazole with sodium hypochlorite in 50% aq acetic acid. The reagent quickly precipitates and is obtained in nearly quantitative yield after recrystallization from CH2Cl2/petroleum ether.

storage

1-Chlorobenzotriazole may ignite spontaneously; reacts explosively with DMSO; light sensitive; stable to air and moisture in brown bottles; storage recommended at 0 °C; discard or repurify if discoloration occurs. This reagent should be handled in a fume hood.

1-CHLOROBENZOTRIAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-CHLOROBENZOTRIAZOLE 1-chloro-1H-benzotriazole 1-Chloro-1H-1,2,3-benzotriazole N-Chlorobenzotriazole NSC 186037 1-chloro-1H-benzo[d][1,2,3]triazole 1H-Benzotriazole, 1-chloro- 21050-95-3 Aromatics Heterocycles