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1,5-Cyclooctadiene

1,5-Cyclooctadiene Structure
CAS No.
111-78-4
Chemical Name:
1,5-Cyclooctadiene
Synonyms
COD;Cycloocta-1,5-diene;1,5-COD;CIS,CIS-1,5-CYCLOOCTADIENE;1,5-CycL;ooctadiene;1,5-CYCLOOCTADIENE;1.5-cyclooctandiene;1,5-Cyclooctanediene;Cyclooctadiene, 1,5-
CBNumber:
CB7852853
Molecular Formula:
C8H12
Molecular Weight:
108.18
MOL File:
111-78-4.mol
MSDS File:
SDS
Modify Date:
2023/12/26 11:30:52

1,5-Cyclooctadiene Properties

Melting point -69 °C (lit.)
Boiling point 149-150 °C (lit.)
Density 0.882 g/mL at 25 °C (lit.)
vapor pressure 25.8 mm Hg ( 37.7 °C)
refractive index n20/D 1.493
Flash point 89 °F
storage temp. 2-8°C
solubility soluble in Chloroform
form Liquid
color Clear colorless
Odor Threshold 0.00084ppm
Water Solubility 780 mg/L (20 ºC)
BRN 2036542
Stability Stable. Flammable.
LogP 3.16 at 20℃
CAS DataBase Reference 111-78-4(CAS DataBase Reference)
NIST Chemistry Reference 1,5-Cyclooctadiene(111-78-4)
EPA Substance Registry System 1,5-Cyclooctadiene (111-78-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H226-H302+H332-H304-H410
Precautionary statements  P210-P233-P273-P301+P310-P304+P340+P312-P331
Hazard Codes  Xn,N,Xi
Risk Statements  10-36/38-42/43-65-50/53-22-43-19-20/22-52/53-36/37/38
Safety Statements  26-36-61-60-16-37/39
RIDADR  UN 2520 3/PG 3
WGK Germany  3
RTECS  GX9620000
10-23
Autoignition Temperature 431 °F
HazardClass  3.2
PackingGroup  III
HS Code  29021990
NFPA 704
3
0

1,5-Cyclooctadiene price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) C109207 1,5-Cyclooctadiene contains 50-150?ppm 4-tert-Butylcatechol, 99% 111-78-4 500ML ₹2435.18 2022-06-14 Buy
Sigma-Aldrich(India) C109207 1,5-Cyclooctadiene contains 50-150?ppm 4-tert-Butylcatechol, 99% 111-78-4 100ML ₹2435.18 2022-06-14 Buy
Sigma-Aldrich(India) C109207 1,5-Cyclooctadiene contains 50-150?ppm 4-tert-Butylcatechol, 99% 111-78-4 1L ₹7942.58 2022-06-14 Buy
Sigma-Aldrich(India) C109207 1,5-Cyclooctadiene contains 50-150?ppm 4-tert-Butylcatechol, 99% 111-78-4 4L ₹15196.73 2022-06-14 Buy
Sigma-Aldrich(India) 246050 1,5-Cyclooctadiene purified by redistillation, ≥99% 111-78-4 100ML ₹2938.65 2022-06-14 Buy
Product number Packaging Price Buy
C109207 500ML ₹2435.18 Buy
C109207 100ML ₹2435.18 Buy
C109207 1L ₹7942.58 Buy
C109207 4L ₹15196.73 Buy
246050 100ML ₹2938.65 Buy

1,5-Cyclooctadiene Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Uses

Cycloocta-1,5-diene is produced from petroleum distillation fractions and is used as an intermediate in the plastics industry, as a synthetic lubricant, and in numerous other applications.

Carcinogenicity

None of the components present in this material at concentrations of 0.1% are listed by IARC, NTP, or OSHA as a carcinogen.

Purification Methods

Purify it by GLC. It has been purified via the AgNO3 salt. This is prepared by shaking with a solution of 50% aqueous AgNO3 w/w several times (e.g. 3 x 50mLand4x50mL) at 70ofor ca 20minutes to get a good separation of layers. The upper layers are combined and further extracted with AgNO3 at 40o (2 x 20 mL). The upper layer (19 mL) of original hydrocarbon mixture gives colourless needles of the AgNO3 complex on cooling. The adduct is recrystallised from MeOH (and cooling to 0o). The hydrocarbon is recovered by steam distilling the salt. The distillate is extracted with Et2O, dried (MgSO4), filtered, evaporated and distilled. [Jones J Chem Soc 312 1954,[Beilstein 5 H 116, 5 IV 403.]

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1,5-CYCLOOCTADIENE 1,5-CYCLOOCTADIENE, REDISTILLED, 99+% 1,5-Cyclooctadiene, stabilized, 97% CIS,CIS-1,5-CYCLOOCTADIENE , STABILIZED WITH 50-200PPM IRGANOX 1076 1,5-Cyclooctadiene [stabilized with Octadecyl 3-(3',5'-Di-tert-butyl-4'-hydroxyphenyl)propionate] Cyclooctadiene, 1,5- 1,5-Cyclooctanediene cis,cis-1,5-Cyclooctadiene: 99%, stabilized with 50-200ppm Irganox 1076 1,5-Cyclooctadiene,99%,stabilized 1,5-Cyclooctadiene ,98.5% [stabilized] [stabilized with Octadecyl 3-(3 ,5 -Di-tert-butyl-4 -hydroxyphenyl)propionate] 1,5-Cyclooctadiene  1,5-Cyclooctadiene, 99+%, stabilized, purified by redistillation, AcroSeal 1,5-Cyclooctadiene contains 50-150 ppM 4-tert-Butylcatechol, 99% 1,5-Cyclooctadiene purified by redistillation, >=99% 1,5-Cyclooctadiene(COD) 1,5-CYCLOOCTADIENE, 98+%1,5-CYCLOOCTADIENE, 98+%1,5-CYCLOOCTADIENE, 98+%1,5-CYCLOOCTADIENE, 98+% 1,5-Cyclooctadiene[stabilizedwithOctadecyl3-(3',5'-Di-tert-butyl-4'-hydroxyphenyl)propionate]> 1,5-CycL ooctadiene 1,5-Cyclooctadiene ISO 9001:2015 REACH (5Z)-cycloocta-1,5-diene Cycloocta-1,5-diene COD CIS,CIS-1,5-CYCLOOCTADIENE 1,5-COD 1.5-cyclooctandiene 1,5-Cyclooctadiene, stabilized with Octadecyl 3-(3',5'-Di-tert-butyl-4'-hydroxyphenyl)propionate,≥ 98.0% 111-78-4 Alkenes Building Blocks Cyclic Organic Building Blocks Alkenes Cyclic Organic Building Blocks