ChemicalBook > Product Catalog >Organic Chemistry >Hydrocarbons and derivatives >Aromatic hydrocarbons >4,4'-Divinylbiphenyl

4,4'-Divinylbiphenyl

4,4'-Divinylbiphenyl Structure
CAS No.
4433-13-0
Chemical Name:
4,4'-Divinylbiphenyl
Synonyms
4,4'-Divinylbiphenyl;4,4'-Divinylbiphenyl;4,4-Divinyl-p-biphenyl;4,4'-Divinyl-1,1'-biphenyl;4,4'-Divinyl-1,1'-biphenyl;4,4'-Diethenyl-1,1'-biphenyl;1,1'-Biphenyl,4,4'-diethenyl-;1-ethenyl-4-(4-ethenylphenyl)benzene
CBNumber:
CB7971639
Molecular Formula:
C16H14
Molecular Weight:
206.28
MOL File:
4433-13-0.mol
MSDS File:
SDS
Modify Date:
2022/11/15 9:03:10

4,4'-Divinylbiphenyl Properties

Melting point 153 °C(Solv: water (7732-18-5); ethanol (64-17-5))
Boiling point 341.6±22.0 °C(Predicted)
Density 0.998±0.06 g/cm3(Predicted)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335-H413
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338-P273

4,4'-Divinylbiphenyl Chemical Properties,Uses,Production

Preparation

The preparation of 4,4'-Divinylbiphenyl is as follows: Reaction flask (10 mL) equipped with stirring bar was charged with 4-vinylphenylboronic acid (135mg, 0.91 mmol), ethanol (96%) (2 mL), [{Pd(μ-OH)Cl(IPr)}2] (510-4 g, 4.55 × 10-7 mol). Reactionmixture was stirred at 22 C for 6 h. After completion of the reaction solvent was evaporated, theresidue was dissolved in hexane (5 mL) and extracted with water (2 × 2 mL). The organic layer wasdried over magnesium sulphate, and hexane was evaporated under reduced pressure. 176 mg of 4,4'-divinylbiphenyl was obtained as a white solid. Yield = 93%. 

4433-13-0.png

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4,4'-Divinylbiphenyl 4,4'-Diethenyl-1,1'-biphenyl 4,4-Divinyl-p-biphenyl 1,1'-Biphenyl,4,4'-diethenyl- 4,4'-Divinyl-1,1'-biphenyl 1-ethenyl-4-(4-ethenylphenyl)benzene 4,4'-Divinyl-1,1'-biphenyl 4,4'-Divinylbiphenyl 4433-13-0