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4-AMINO-2,6-DIBROMOPHENOL

4-AMINO-2,6-DIBROMOPHENOL Structure
CAS No.
609-21-2
Chemical Name:
4-AMINO-2,6-DIBROMOPHENOL
Synonyms
ASISCHEM U70323;TIMTEC-BB SBB006577;4-amino-2,6-dibromo-pheno;4-AMINO-2,6-DIBROMOPHENOL;2,6-DIBROMO-4-AMINOPHENOL;3,5-DIBROMO-4-HYDROXYANILINE;Phenol, 4-amino-2,6-dibromo-;4-hydroxy-3,5-dibromoaniline;4-Amino-2,6-dibromophenol,99%;1-CYANO-3,5-DIBROMO-4-HYDROXYBENZENE
CBNumber:
CB8107059
Molecular Formula:
C6H5Br2NO
Molecular Weight:
266.92
MOL File:
609-21-2.mol
Modify Date:
2022/11/25 16:07:05

4-AMINO-2,6-DIBROMOPHENOL Properties

Melting point 195-196 °C(lit.)
Boiling point 295.6±40.0 °C(Predicted)
Density 2.0444 (rough estimate)
refractive index 1.6400 (estimate)
storage temp. 2-8°C(protect from light)
pka 7.17±0.23(Predicted)
BRN 2803732
CAS DataBase Reference 609-21-2(CAS DataBase Reference)
EPA Substance Registry System Phenol, 4-amino-2,6-dibromo- (609-21-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39-36
WGK Germany  3
TSCA  Yes
HazardClass  IRRITANT
HS Code  29222900
NFPA 704
0
2 0

4-AMINO-2,6-DIBROMOPHENOL Chemical Properties,Uses,Production

Chemical Properties

beige to pale brown crystalline powder

Synthesis

The synthesis of 4-amino-2,6-dibromophenol is as follows:4-Nitro-2,6-dibromophenol (2.97g, 10mmol) was dissolved in ethanol (15ml) and water (3ml), and acetic acid (1ml) was added. Then heat and stir to raise the temperature to 80°C, and add iron powder (1.68g, 30mmol) in batches. After the addition is complete, the reaction solution is kept warm for 30 minutes, heating is stopped, filtered while hot, the filtrate is concentrated under reduced pressure, then ethyl acetate and water are added to the concentrated residue to extract, the organic phases are combined and dried, filtered, and the solvent is removed under reduced pressure. The residue was finally separated by column chromatography (ethyl acetate/petroleum ether=1/3) to obtain 4-amino-2,6-dibromophenol (2.52g, 94.4% yield).
synthesis of 4-AMINO-2,6-DIBROMOPHENOL        

4-AMINO-2,6-DIBROMOPHENOL Preparation Products And Raw materials

Raw materials

Preparation Products

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ASISCHEM U70323 4-hydroxy-3,5-dibromoaniline 4-amino-2,6-dibromo-pheno Phenol, 4-amino-2,6-dibromo- TIMTEC-BB SBB006577 4-AMINO-2,6-DIBROMOPHENOL 3,5-DIBROMO-4-HYDROXYANILINE 2,6-DIBROMO-4-AMINOPHENOL 4-Amino-2,6-dibromophenol,99% 1-CYANO-3,5-DIBROMO-4-HYDROXYBENZENE 2-propenoic acid 2-[2-[2-[2-[2-(1-oxoprop-2-enoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethyl ester 609-21-2 H2NC6H2Br2OH AMINE Building Blocks Phenols Oxygen Compounds Organic Building Blocks Building Blocks C6 to C8 Chemical Synthesis Organic Building Blocks Oxygen Compounds Phenol&Thiophenol&Mercaptan Anilines, Amides & Amines Bromine Compounds Phenols