VINCLOZOLIN
- CAS No.
- 50471-44-8
- Chemical Name:
- VINCLOZOLIN
- Synonyms
- M2;VORLAN;RONILAN;bas352f;Ornalin;Ronilon;BAS 352;Ranilan;FLOTILLA;BAS 352 F
- CBNumber:
- CB8108814
- Molecular Formula:
- C12H9Cl2NO3
- Molecular Weight:
- 286.11
- MOL File:
- 50471-44-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/5/4 17:34:39
| Melting point | 108℃ |
|---|---|
| Boiling point | 131℃ (0.05mmHg) |
| Density | 1.51 g/cm3 |
| vapor pressure | 1.3 x 10-4 Pa (20 °C) |
| refractive index | 1.6100 (estimate) |
| Flash point | 2 °C |
| storage temp. | APPROX 4°C |
| solubility | DMF: 30 mg/ml,DMSO: 30 mg/ml,Ethanol: 30 mg/ml,Ethanol:PBS(pH 7.2) (1:1): 0.5 mg/ml |
| Water Solubility | 3.4 mg l-1 (20 °C) |
| pka | -3.43±0.40(Predicted) |
| Merck | 13,10046 |
| BRN | 8331312 |
| EPA Substance Registry System | Vinclozolin (50471-44-8) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS07,GHS08,GHS09 |
|---|---|
| Signal word | Danger |
| Hazard statements | H317-H351-H360FD-H411 |
| Precautionary statements | P201-P261-P273-P280-P308+P313-P391 |
| Hazard Codes | T,N,Xn,F |
| Risk Statements | 60-61-40-43-51/53-36-20/21/22-11 |
| Safety Statements | 53-45-61-36-26-16-36/37 |
| RIDADR | UN3077 9/PG 3 |
| WGK Germany | 3 |
| RTECS | RP8530000 |
| HS Code | 29349990 |
| Toxicity | LD50 orally in rats: 10 g/kg (Hess, Locher) |
VINCLOZOLIN price More Price(2)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 90413 | Vinclozolin certified reference material, TraceCERT? | 50471-44-8 | 50MG | ₹19755.63 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 45705 | Vinclozolin PESTANAL?, analytical standard | 50471-44-8 | 250MG | ₹7631.63 | 2022-06-14 | Buy |
VINCLOZOLIN Chemical Properties,Uses,Production
Uses
Vinclozolin is a non-systemic, contact fungicide that controls fruit rot, brown rot, mould and blight caused by Botrytis spp., Sclerotinia spp., Monilia spp., etc. in vines, fruits, vegetables, oilseed rape, ornamentals, hops, turf and strawberries. Vinclozolin exhibits both preventive and curative activities.
General Description
Colorless crystals with slight aromatic odor. Used as a fungicide.
Air & Water Reactions
Hydrolysis rapidly occurs under alkaline conditions
Reactivity Profile
A halogenated dicarboximide. Organic amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).
Agricultural Uses
Fungicide: Vinclozolin is a non-systemic fungicide which has been used on vines (such as grapes), strawberries, raspberries, chicory grown for Belgian endive, lettuce, kiwi, canola, succulent beans, and dry bulb onions. Import tolerances have been established to permit. Not approved for use in EU countries . Registered for use in the U.S.
Trade name
BAS-352-F®; BAS-35204-F®; CURALAN®; FLOTILLA®; FUMITE RONALIN®; MASCOT® contact turf fungicide; ORNALIN®[C]; POWERDRIVE®; RONILAN®; RONILAN-DF®; RONALINE-FL®; TOUCHE®; VINCHLOZOLINE®; VINCLOZOLINE®; VORLAND®
Safety Profile
Low toxicity by ingestion and inhalation. Mutation data reported. When heated to decomposition it emits very toxic fumes of Cland NOx.
Metabolic pathway
The fungicides, chlozolinate, vinclozolin, and procymidone, are added to wine after fermentation and the degradation products are isolated and identified. Chlozolinate undergoes a rapid hydrolytic loss of the ethoxycarbonyl substituent to give an oxazolidine that further undergoes hydrolytic cleavage to give 3' ,5' -dichloro-2-hydroxypropanilide. The oxazolidine ring of vinclozolin undergoes a similar hydrolysis reaction to give the corresponding anilide, 3' ,5'-dichloro-2-hydroxy-2-methylbut-3-eneanilide. Both of these anilides are stable in wine for 150 days. A different degradation behavior is observed with procymidone and leads to the formation of 3,5- dichloroaniline, which, in turn, breaks down in wine.
Purification Methods
Crystallise the fungicide from Me2CO/H2O. Its solubility at 20o (w/w%) is 44 (Me2CO), 32 (CHCl3), 25 (EtOAc) and 10 (H2O). It irritates the eyes and skin. [GP 2,207,576 1973, Chem Abstr 79 137120 1973.]
VINCLOZOLIN Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| Pharmaffiliates Analytics and Synthetics P. Ltd | +91-172-5066494 | Haryana, India | 6773 | 58 | Inquiry |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
| TargetMol Chemicals Inc. | +1-781-999-5354 +1-00000000000 | United States | 19892 | 58 | Inquiry |
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | China | 30253 | 58 | Inquiry |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | China | 34571 | 58 | Inquiry |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | China | 52861 | 58 | Inquiry |
| ZHEJIANG JIUZHOU CHEM CO., LTD | +86-0576225566889 +86-13454675544 | China | 19947 | 58 | Inquiry |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | China | 49999 | 58 | Inquiry |
| SUZHOU SENFEIDA CHEMICAL CO.,LTD | +86-0512-83500002 +8615195660023 | China | 23053 | 58 | Inquiry |
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