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(2S,5S)-(-)-2-TERT-BUTYL-3-METHYL-5-BENZYL-4-IMIDAZOLIDINONE

(2S,5S)-(-)-2-TERT-BUTYL-3-METHYL-5-BENZYL-4-IMIDAZOLIDINONE Structure
CAS No.
346440-54-8
Chemical Name:
(2S,5S)-(-)-2-TERT-BUTYL-3-METHYL-5-BENZYL-4-IMIDAZOLIDINONE
Synonyms
(2S,5S)-5-Benzyl-2-(tert-butyl)-3-MethyliMidazolidin-4-one;MACMILLAN ORGANOCATALYST(TM) SS246;(2S 5S)-2-(1' 1'-DIMETHYLETHYL)-3-METHY&;(2S,5S)-2-TERT-BUTYL-3-METHYL-5-BENZYL-&;(2S,5S)-2-(1?,1?-dimethylethyl)-3-methyl-5-phe...;(2S,5S)-5-BENZYL-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE;(2S,5S)-2-T-BUTYL-3-METHYL-5-PHENYLMETHYL-4-IMIDAZOLIDINONE;(2S,5S)-(-)-2-TERT-BUTYL-3-METHYL-5-BENZYL-4-IMIDAZOLIDINONE;(2S,5S)-2-TERT-BUTYL-3-METHYL-5-PHENYLMETHYL-4-IMIDAZOLIDINONE;(2S,5S)-(-)-2-tert-Butyl-3-Methyl-5-benzyl-4-iMidazolidinone 97%
CBNumber:
CB8117249
Molecular Formula:
C15H22N2O
Molecular Weight:
246.35
MOL File:
346440-54-8.mol
MSDS File:
SDS
Modify Date:
2025/1/27 9:38:02
Request For Quotation

(2S,5S)-(-)-2-TERT-BUTYL-3-METHYL-5-BENZYL-4-IMIDAZOLIDINONE Properties

Melting point 93-100 °C(lit.)
Boiling point 378.0±35.0 °C(Predicted)
Density 1.040±0.06 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
form powder to crystal
pka 5.59±0.60(Predicted)
color White to Light yellow

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
Safety Statements  22-24/25
WGK Germany  3
HS Code  29339900

(2S,5S)-(-)-2-TERT-BUTYL-3-METHYL-5-BENZYL-4-IMIDAZOLIDINONE price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 663107 (2S,5S)-(−)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone 97% 346440-54-8 500MG ₹16897.83 2022-06-14 Buy
Sigma-Aldrich(India) 663107 (2S,5S)-(−)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone 97% 346440-54-8 1G ₹20610.8 2022-06-14 Buy
TCI Chemicals (India) B4138 (2S,5S)-(-)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone 346440-54-8 200MG ₹5700 2022-05-26 Buy
TCI Chemicals (India) B4138 (2S,5S)-(-)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone 346440-54-8 1G ₹25500 2022-05-26 Buy
Product number Packaging Price Buy
663107 500MG ₹16897.83 Buy
663107 1G ₹20610.8 Buy
B4138 200MG ₹5700 Buy
B4138 1G ₹25500 Buy

(2S,5S)-(-)-2-TERT-BUTYL-3-METHYL-5-BENZYL-4-IMIDAZOLIDINONE Chemical Properties,Uses,Production

Uses

(2S,5S)-(-)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone is a second-generation MacMillan catalyst, which can be used as a chiral organocatalyst in:

  • The chiral transformation reaction, including Friedel-Crafts and Mukaiyama-Michael reactions.
  • The preparation of substituted spiroundecenetriones via asymmetric domino Knoevenagel/Diels-Alder reactions.
  • The asymmetric synthesis of β-hydroxy aldehydes and their dimethylacetals via aldehyde-aldehyde aldol condensation reaction.
  • The enantioselective α-fluorination of aldehydes using N-fluorobenzenesulfonamide as a fluorinating agent.
  • The stereoselective preparation of (oxomethyl)oxabicyclo[3.2.1]octenones and tricyclic pyrroles via [4+3] cycloaddition of (trialkylsiloxy)pentadienals to furans.

General Description

(2S,5S)-(-)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone is a chiral imidazolidinone organocatalyst, developed by MacMillan and co-workers.

(2S,5S)-(-)-2-TERT-BUTYL-3-METHYL-5-BENZYL-4-IMIDAZOLIDINONE Preparation Products And Raw materials

Raw materials

Ethyl L-phenylalaninate hydrochloride methyl 3-phenyl-L-alaninate 2R,5S)-5-benzyl-2-tert-butyl-3-MethyliMidazolidin-4-one L-Phenylalanine methylamide Methyl L-phenylalaninate hydrochloride
Pivaldehyde L-Phenylalanine
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Preparation Products

2-(4-nitrophenyl)malononitrile

(2S,5S)-(-)-2-TERT-BUTYL-3-METHYL-5-BENZYL-4-IMIDAZOLIDINONE Suppliers

Global( 72)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6768 58 Inquiry
Henan Fengda Chemical Co., Ltd +86-371-86557731 +86-13613820652 China 20235 58 Inquiry
CONIER CHEM AND PHARMA LIMITED +8618523575427 China 49732 58 Inquiry
Zhengzhou Alfa Chemical Co.,Ltd +8618530059196 China 12162 58 Inquiry
Career Henan Chemica Co +86-0371-86658258 +8613203830695 China 30231 58 Inquiry
Hefei TNJ Chemical Industry Co.,Ltd. +86-0551-65418684 +8618949823763 China 25356 58 Inquiry
Henan Aochuang Chemical Co.,Ltd. +86-0371-63689365 +8618638391208 China 9297 58 Inquiry
Shaoxin Catsyn Co., Ltd. +undefined-0575-82040869 +86-0575-82040869; China 6114 58 Inquiry
Zhengzhou Anbu Chem Co.,Ltd +86-0371-88006763; +8615988602810 China 2998 58 Inquiry
Shanghai Acmec Biochemical Technology Co., Ltd. +86-18621343501; +undefined18621343501 China 33338 58 Inquiry
Supplier Advantage
TCI Chemicals (India) Pvt. Ltd. 58
Henan Fengda Chemical Co., Ltd 58
CONIER CHEM AND PHARMA LIMITED 58
Zhengzhou Alfa Chemical Co.,Ltd 58
Career Henan Chemica Co 58
Hefei TNJ Chemical Industry Co.,Ltd. 58
Henan Aochuang Chemical Co.,Ltd. 58
Shaoxin Catsyn Co., Ltd. 58
Zhengzhou Anbu Chem Co.,Ltd 58
Shanghai Acmec Biochemical Technology Co., Ltd. 58

346440-54-8((2S,5S)-(-)-2-TERT-BUTYL-3-METHYL-5-BENZYL-4-IMIDAZOLIDINONE)Related Search:

(2S,5S)-(-)-2-TERT-BUTYL-3-METHYL-5-BENZYL-4-IMIDAZOLIDINONE
MACMILLAN ORGANOCATALYST(TM) SS246 (2S,5S)-2-TERT-BUTYL-3-METHYL-5-BENZYL-& (2S 5S)-2-(1' 1'-DIMETHYLETHYL)-3-METHY& (2S,5S)-5-Benzyl-2-tert-butyl-3-methyl-4-imidazolidinone, (2S,5S)-2-tert-Butyl-3-methyl-5-phenylmethyl-4-imidazolidinone (2S,5S)-()-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone,(2S,5S)-2-tert-Butyl-3-methyl-5-phenylmethyl-4-imidazolidinone, (2S,5S)-5-Benzyl-2-tert-butyl-3-methyl-4-imidazolidinone (2S,5S)-(-)-2-tert-Butyl-3-Methyl-5-benzyl-4-iMidazolidinone 97% (2S,5S)-(-)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone (2S,5S)-5-BENZYL-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE (2S,5S)-2-T-BUTYL-3-METHYL-5-PHENYLMETHYL-4-IMIDAZOLIDINONE (2S,5S)-(-)-2-TERT-BUTYL-3-METHYL-5-BENZYL-4-IMIDAZOLIDINONE (2S,5S)-2-TERT-BUTYL-3-METHYL-5-PHENYLMETHYL-4-IMIDAZOLIDINONE (2S,5S)-2-(1,1-dimethylethyl)-3-methyl-5-phenylmethyl-4-imidazolidinone 4-Imidazolidinone, 2-(1,1-dimethylethyl)-3-methyl-5-(phenylmethyl)-, (2S,5S)- (2S,5S)-2-(1?,1?-dimethylethyl)-3-methyl-5-phe... (2S,5S)-5-Benzyl-2-(tert-butyl)-3-MethyliMidazolidin-4-one 346440-54-8 Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents