AURANTIOL

AURANTIOL Structure
CAS No.
89-43-0
Chemical Name:
AURANTIOL
Synonyms
AURALVA;AURANTIOL;AURANTION;AURANTIUM;201-908-1;Hydroxycitronellal;Hydroxycitronellal methyl anthranilate;METHYL ANTHRANILATE HYDROXY CITRONELLAL;HYDROXYCITRONELLYLIDENE METHYLANTHRANILATE;HYDROXYCITRONELLAL-METHYLANTHRANILATE SCHIFF'S BASE
CBNumber:
CB8125415
Molecular Formula:
C18H27NO3
Molecular Weight:
305.41
MOL File:
89-43-0.mol
MSDS File:
SDS
Modify Date:
2023/5/25 18:01:19

AURANTIOL Properties

Boiling point 445.7±45.0 °C(Predicted)
Density 1.01±0.1 g/cm3(Predicted)
Flash point 97℃
solubility Almost insoluble in water, soluble in alcohol and oils, poorly soluble in Propylene glycol.
form Intensely yellow, viscous to very viscous liquid
pka 15.31±0.29(Predicted)
Odor at 50.00 % in dipropylene glycol. floral lily orange blossom sweet
Odor Type floral
LogP 5.417 (est)
EPA Substance Registry System Benzoic acid, 2-[(7-hydroxy-3,7-dimethyloctylidene)amino]-, methyl ester (89-43-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H317-H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P261-P272-P280-P302+P352-P333+P313-P321-P363-P501
Toxicity The acute oral LD50 value in rats was reported as > 5 g/kg (Moreno, 1973). The acute dermal LD50 value in rabbits was reported as > 2 g/kg (Moreno, 1973).
NFPA 704
1
0 0

AURANTIOL Chemical Properties,Uses,Production

Chemical Properties

Viscous, colorless, or faintly yellow liquid; sweet lily-type odor.Soluble in alcohol (50%), fixed oils; slightly soluble in water, glycerol, and mineral oil. Combustible.

Occurrence

Has apparently not been reported to occur in nature.

Uses

Perfumery (fixative, muguet odor), flavoring, soap and cosmetic fragrances.

Preparation

By hydration of citronellal (Bedoukian, 1967).

Application

This Schiff-s base Aurantiol is the most widely used of all Schiff's bases known in perfumery. Its low cost and considerable strength, its tenacity and versatility are virtues that make the product applicable in fragrances of all price levels and for numerous purposes. Obviously and almost inevitably used in Orange blossom, Neroli and related heavy florals, it finds use in smaller amounts in countless other fragrant types: Citrus blends, Ambres, and Orientals. Chyprcs, etc. It forms the steady undertone in many such sweet florals, in Honeysuckle, Frangipanni, Magnolia, exotic florals, etc. In the Citrus Cologne types, it has the ability to appear even in the initial notes, besides being a fixative. Used for nearly 50 years, it has been brought "back to life" several times, e. g., when the fruity-musky perfume was fashionable (and still is, to a certain degree), that perfume had a solid undertone of this type of material, backed up by Ethylene brassylate and Undecanolide in unusually high proportions. This base has a perceptible effect in a perfume oil at concentrations beginning well below 1%, but is often used at a much higher level.

Trade name

Aurantiol Pure (Givaudan).

AURANTIOL Preparation Products And Raw materials

Global( 100)Suppliers
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Flowersynth +91-9845115120 +91-9886340888 Karnataka, India 45 58 Inquiry
Arpan Aromatics +91-9824514546 +91-9824029204 Gujarat, India 59 58 Inquiry
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Xiamen AmoyChem Co., Ltd +86-592-6051114 +8618959220845 China 6387 58 Inquiry
CONIER CHEM AND PHARMA LIMITED +8618523575427 China 49391 58 Inquiry
SCHIFF'S BASE-HYDROXYCITRONELLAL AND METHYL ANTHRANILATE methyl 2-[(7-hydroxy-3,7-dimethyloctylidene)amino]benzoate Hydroxycitronellal methyl anthranilate Methyl-2-[(7-hydroxy-3,7-dimethyloctyliden)amino]benzoat 2-(3,7-Dimethyl-7-hydroxyoctylideneamino)benzoic acid methyl ester 2-[(7-Hydroxy-3,7-dimethyloctylidene)amino]benzoic acid methyl ester Hydroxycitronellal 2-[(7-hydroxy-3,7-dimethyloctylidene)amino]-benzoicacimethylester Benzoicacid,2-[(7-hydroxy-3,7-dimethyloctylidene)amino]-,methylester HYDROXYCITRONELLAL-METHYLANTHRANILATE SCHIFF'S BASE HYDROXYCITRONELLYLIDENE METHYLANTHRANILATE AURALVA AURANTIOL AURANTION AURANTIUM METHYL N-3,7-DIMETHYL-7-HYDROXYOCTYLIDENEANTHRANILATE N-(7-HYDROXY-3 7-DIMETHYLOCTYLIDENE)ANTHRANILIC ACID METHYL ESTER METHYL ANTHRANILATE HYDROXY CITRONELLAL 201-908-1 89-43-0