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Stannic oxide

Stannic oxide Structure
CAS No.
18282-10-5
Chemical Name:
Stannic oxide
Synonyms
TIN OXIDE;TIN DIOXIDE;TIN(IV) OXIDE;tin(iv);stannicdioxide[qr];STANNICOXIDE,POWDER,REAGENT;Tin ash;dioxotin;c.i.77861;t10(oxide)
CBNumber:
CB8130822
Molecular Formula:
O2Sn
Molecular Weight:
150.71
MOL File:
18282-10-5.mol
MSDS File:
SDS
Modify Date:
2024/8/28 13:53:26

Stannic oxide Properties

Melting point 1127 °C
Boiling point 1800-900°C
Density 6.95 g/mL at 25 °C(lit.)
refractive index 1.9968
Flash point 1800-1900°C
storage temp. Store at +5°C to +30°C.
solubility Soluble in hot concentrated alkalis, and concentrated acids. Insoluble in alcohol.
form nanopowder
color White to slightly gray
Specific Gravity 7
PH 4-5 (50g/l, H2O, 20℃)(slurry)
Water Solubility INSOLUBLE
Hydrolytic Sensitivity 6: forms irreversible hydrate
Crystal Structure Rutile type
crystal system square
Sublimation 1800-1900 ºC
Merck 14,8778
Space group P42/mnm
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.47370.47370.31859090900.0715
Exposure limits ACGIH: TWA 2 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 2 mg/m3
Stability Stable.
CAS DataBase Reference 18282-10-5(CAS DataBase Reference)
EPA Substance Registry System Tin dioxide (18282-10-5)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS08
Signal word  Danger
Hazard statements  H302-H317-H319-H372
Precautionary statements  P260-P280-P301+P312-P302+P352-P305+P351+P338-P314
OEB B
OEL TWA: 2 mg/m3
HS Code  2825908590
Toxicity LD50 orally in Rabbit: > 20000 mg/kg
NFPA 704
0
1 0

Stannic oxide price More Price(32)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 549657 Tin(IV) oxide nanopowder, ≤100?nm avg. part. size 18282-10-5 5G ₹8627.53 2022-06-14 Buy
Sigma-Aldrich(India) 549657 Tin(IV) oxide nanopowder, ≤100?nm avg. part. size 18282-10-5 25G ₹22992.3 2022-06-14 Buy
Sigma-Aldrich(India) 244651 Tin(IV) oxide ?325?mesh, 99.9% trace metals basis 18282-10-5 100G ₹4102.68 2022-06-14 Buy
Sigma-Aldrich(India) 244651 Tin(IV) oxide ?325?mesh, 99.9% trace metals basis 18282-10-5 500G ₹13942.6 2022-06-14 Buy
Sigma-Aldrich(India) 204714 Tin(IV) oxide ≥99.99% trace metals basis 18282-10-5 5G ₹11193.05 2022-06-14 Buy
Product number Packaging Price Buy
549657 5G ₹8627.53 Buy
549657 25G ₹22992.3 Buy
244651 100G ₹4102.68 Buy
244651 500G ₹13942.6 Buy
204714 5G ₹11193.05 Buy

Stannic oxide Chemical Properties,Uses,Production

Chemical Properties

white or off-white powder

Physical properties

White or grayish powder; tetragonal crystals; density 6.85 g/cm3; refractive index 2.006; Mohs hardness 6.5; melts at 1,630°C; insoluble in water; soluble in hot concentrated alkalies.

Uses

Stannic oxide (SnO2) is a whitish powder used as a ceramic glaze and polishing agent.

Preparation

Tin(II) oxide is prepared by heating tin(II) hydroxide. The latter is obtained as a white precipitate by reacting Sn2+ ions with hydroxide ions: Sn2+(aq) + 2OHˉ(aq) → Sn(OH)2 (s) Sn(OH)2 ?→ ?? SnO(s) + H2O(g).

General Description

White or off-white crystalline solid or powder. Mp 1127°C, Sublimes: 1800-1900°C, density: 6.95 g cm-3. Insoluble in water. Soluble in concentrated sulfuric acid, hydrochloric acid. Occurs in nature as the mineral cassiterite. Used as a catalyst, in putty, as a polishing powder for steel and glass, in ceramic glazes and colors. Flowers of tin refers to the material collected as the result of condensation after sublimation.

Reactivity Profile

TIN(IV) OXIDE is non-flammable and non-combustible. Reacts vigorously with strong reducing agents. Incompatible with chlorine trifluoride.

Purification Methods

Reflux it repeatedly with fresh HCl until the acid shows no tinge of yellow. The oxide is then dried at 110o.

Stannic oxide Preparation Products And Raw materials

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