ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Phosphine ligand >(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

CAS No.: 192138-05-9

Chemical Name:: (R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

Synonyms: (R)-3,5-t-Bu-MeOBIPHEP;SL-A121-1;(R)-(6，6′-Dimethoxybiphenyl-2，2′-diyl)bis[bis(3，5-di-tert-butylphenyl)phosphine;(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine];(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(3-tert-butylphenyl)-[2-[2-(3-propan-2-ylphenyl)phosphanylphenyl]phenyl]phosphane;(R)-2,2'-Bis[bis(3,5-di-tert-butylphenyl)phosphino]-6,6'- dimethoxy-1,1'-biphenyl;(R)-(+)-2,2'-Bis[di-(3,5-di-t-butylphenyl)-phosphino]- 6,6'-dimethoxy-1,1'-biphenyl

CBNumber:: CB91180980

Molecular Formula:: C70H96O2P2

Molecular Weight:: 1031.46

MOL File:: 192138-05-9.mol

MSDS File:: SDS

Modify Date:: 2023/5/4 15:12:56

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(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Properties

Boiling point	856.5±65.0 °C(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Powder
color	white

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H319-H335-H315
Precautionary statements	P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
WGK Germany	3
HS Code	29319090

(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% price More Price(4)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	29524	(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] ≥97%, optical purity ee: ≥99%	192138-05-9	100MG	₹9103.83	2022-06-14	Buy
Sigma-Aldrich(India)	29524	(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] ≥97%, optical purity ee: ≥99%	192138-05-9	500MG	₹38342.15	2022-06-14	Buy
Sigma-Aldrich(India)	29524	(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] ≥97%, optical purity ee: ≥99%	192138-05-9	1G	₹56744.65	2022-06-14	Buy
Sigma-Aldrich(India)	29524	(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] ≥97%, optical purity ee: ≥99%	192138-05-9	5G	₹326990.78	2022-06-14	Buy

Product number	Packaging	Price	Buy
29524	100MG	₹9103.83	Buy
29524	500MG	₹38342.15	Buy
29524	1G	₹56744.65	Buy
29524	5G	₹326990.78	Buy

(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Uses,Production

Chemical Properties

White powder

Uses

(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] can be used as a ligand to prepare:

1,2-Dihydropyridines through Rh-catalyzed cycloaddition of diynes to sulfonimines.
Enantiorich disubstituted γ-lactams via intramolecular allylic alkylation reaction using Pd catalyst.
A Ru-metal complex, which acts as a hydrogenation catalyst applicable in the synthesis of an organic building block (S)-3-fluoromethyl-γ-butyrolactone.

General Description

sold in collaboration with Solvias AG

(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers

Global( 30)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	China	12962	58	Inquiry
Aladdin Scientific	+1-+1(833)-552-7181	United States	57511	58	Inquiry
Aladdin Scientific	+1-+1(833)-552-7181	United States	52927	58	Inquiry
Shanghai Aladdin Biochemical Technology Co.,Ltd.	+86-18521732826	China	48467	58	Inquiry
Nantong Hanfang Biotechnology Co. , Ltd.	18616537568	China	30968	58	Inquiry
Leshan Bangsheng New Materials Co., Ltd	0833-2599138 19162614312	China	556	58	Inquiry
Shanghai Anyinuo Biomedical Technology Co., Ltd.	021-34625901	China	5774	58	Inquiry
Jiangsu Qianyu Molecular Technology Co., Ltd	18552882512	China	1054	58	Inquiry
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.	0371-0371-65511006 18625597674	China	953	55	Inquiry
Zhengzhou Allchem Chemical Co., Ltd	17734807184	China	7255	58	Inquiry

Supplier	Advantage
Zhengzhou Alfa Chemical Co.,Ltd	58
Aladdin Scientific	58
Aladdin Scientific	58
Shanghai Aladdin Biochemical Technology Co.,Ltd.	58
Nantong Hanfang Biotechnology Co. , Ltd.	58
Leshan Bangsheng New Materials Co., Ltd	58
Shanghai Anyinuo Biomedical Technology Co., Ltd.	58
Jiangsu Qianyu Molecular Technology Co., Ltd	58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.	55
Zhengzhou Allchem Chemical Co., Ltd	58

(R)-(+)-2,2''-BIS[DI(3,5-DI-T-BUTYLPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97% (R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] (R)-3,5-t-Bu-MeOBIPHEP, SL-A121-1, (R)-2,2μ-Bis[bis(3,5-di-tert-butyl)phosphino]-6,6μ-dimethoxy-1,1μ-biphenyl (R)-(+)-2,2'-Bis[di-(3,5-di-tert-butylphenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl SL-A121-1 (R)-(+)-2,2'-Bis[di-(3,5-di-t-butylphenyl)-phosphino]- 6,6'-dimethoxy-1,1'-biphenyl (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] >=97%, optical purity ee: >=99% (3-tert-butylphenyl)-[2-[2-(3-propan-2-ylphenyl)phosphanylphenyl]phenyl]phosphane Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis[3,5-bis(1,1-dimethylethyl)phenyl]- (R)-2,2'-Bis[bis(3,5-di-tert-butylphenyl)phosphino]-6,6'- dimethoxy-1,1'-biphenyl (R)-3,5-t-Bu-MeOBIPHEP -diyl)bis[bis(3，5-di-tert-butylphenyl)phosphine -Dimethoxybiphenyl-2，2′ (R)-(6，6′ (R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-(+)-2,2''-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6''-dimethoxy-1,1''-biphenyl (R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 192138-05-9 C70H96O2P2 Chiral Phosphine MeOBIPHEP Series