Name: (R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Brand: chemicalbook
SKU: 192138-05-9

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(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

₹9103.83 - ₹326990.78
Product name: (R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
CAS: 192138-05-9
MF: C70H96O2P2
MW: 1031.46
EINECS:
MDL Number:MFCD09753001
Synonyms:(R)-(+)-2,2''-BIS[DI(3,5-DI-T-BUTYLPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine];(R)-3,5-t-Bu-MeOBIPHEP, SL-A121-1, (R)-2,2μ-Bis[bis(3,5-di-tert-butyl)phosphino]-6,6μ-dimethoxy-1,1μ-biphenyl;(R)-(+)-2,2'-Bis[di-(3,5-di-tert-butylphenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl;SL-A121-1;(R)-(+)-2,2'-Bis[di-(3,5-di-t-butylphenyl)-phosphino]- 6,6'-dimethoxy-1,1'-biphenyl;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] >=97%, optical purity ee: >=99%

Price4 Properties Safety Information Description

4 prices

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ManufacturerSigma-Aldrich(India)
Product number29524
Product description(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] ≥97%, optical purity ee: ≥99%
Packaging100MG
Price₹9103.83
Updated2022-06-14
Buy

ManufacturerSigma-Aldrich(India)
Product number29524
Product description(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] ≥97%, optical purity ee: ≥99%
Packaging500MG
Price₹38342.15
Updated2022-06-14
Buy

ManufacturerSigma-Aldrich(India)
Product number29524
Product description(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] ≥97%, optical purity ee: ≥99%
Packaging1G
Price₹56744.65
Updated2022-06-14
Buy

ManufacturerSigma-Aldrich(India)
Product number29524
Product description(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] ≥97%, optical purity ee: ≥99%
Packaging5G
Price₹326990.78
Updated2022-06-14
Buy

Manufacturer	Product number	Product description	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	29524	(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] ≥97%, optical purity ee: ≥99%	100MG	₹9103.83	2022-06-14	Buy
Sigma-Aldrich(India)	29524	(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] ≥97%, optical purity ee: ≥99%	500MG	₹38342.15	2022-06-14	Buy
Sigma-Aldrich(India)	29524	(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] ≥97%, optical purity ee: ≥99%	1G	₹56744.65	2022-06-14	Buy
Sigma-Aldrich(India)	29524	(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] ≥97%, optical purity ee: ≥99%	5G	₹326990.78	2022-06-14	Buy

Properties

Boiling point :856.5±65.0 °C(Predicted)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Powder
color :white

Symbol(GHS):

Signal word:

Warning

Hazard statements:

Code	Hazard statements	Hazard class	Category	Signal word	P-Codes
H315	Causes skin irritation	Skin corrosion/irritation	Category 2	Warning	P264, P280, P302+P352, P321,P332+P313, P362
H319	Causes serious eye irritation	Serious eye damage/eye irritation	Category 2A	Warning	P264, P280, P305+P351+P338,P337+P313P
H335	May cause respiratory irritation	Specific target organ toxicity, single exposure;Respiratory tract irritation	Category 3	Warning

Precautionary statements:

P264	Wash hands thoroughly after handling.
P264	Wash skin thouroughly after handling.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352	IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321	Specific treatment (see … on this label).
P332+P313	IF SKIN irritation occurs: Get medical advice/attention.
P362	Take off contaminated clothing and wash before reuse.

(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] can be used as a ligand to prepare:

1,2-Dihydropyridines through Rh-catalyzed cycloaddition of diynes to sulfonimines.
Enantiorich disubstituted γ-lactams via intramolecular allylic alkylation reaction using Pd catalyst.
A Ru-metal complex, which acts as a hydrogenation catalyst applicable in the synthesis of an organic building block (S)-3-fluoromethyl-γ-butyrolactone.