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METAPHOSPHORIC ACID

METAPHOSPHORIC ACID Structure
CAS No.
10343-62-1
Chemical Name:
METAPHOSPHORIC ACID
Synonyms
Phosphenic acid;M-PHOSPHORIC ACID;METAPHOSPHORIC ACID;PHOSPHORIC ACID, META;Metaphosphoric acid (HPO3);Phosphorus hydoxide dioxide;VITREOUS SODIUM ACID METAPHOSPHATE;Metaphosphoric acid (HPO3) (7CI,8CI,9CI);META-PHOSPHORIC ACID PIECES FOR ANALYSIS
CBNumber:
CB9139332
Molecular Formula:
HO3P
Molecular Weight:
79.98
MOL File:
10343-62-1.mol
MSDS File:
SDS
Modify Date:
2023/5/4 17:34:30

METAPHOSPHORIC ACID Properties

form pieces
color Clear
Water Solubility dissolves very slowly in cold H2O to form H3PO4, formation of H3PO4 accelerated by boiling; soluble alcohol [MER06]

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P305+P351+P338-P310
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3260 8/PG 3
WGK Germany  3
3

METAPHOSPHORIC ACID Chemical Properties,Uses,Production

Description

Metaphosphoric acid is a singularly anhydrous version of orthophosphoric acid and is sometimes used as a water- or moisture-absorbing reagent. Metaphosphoric acid has phosphorus in the formal oxidation state of +5. Although it has several CAS numbers: 10343-62-1, 135306-83-1, 13566-25-1, and 37267-86-0, only the last two are associated with the IUPAC name “phosphenic acid”.
Metaphosphoric acid units can be bonded together in rings (cyclic structures), chains (catena), or branched by condensation yielding water as each acid unit is added. These structures consist of linked metaphosphoric acid molecules. For example, trimetaphosphoric acid is the simplest cyclophosphoric acid. Metaphosphoric acid would need to share the doubly bonded oxygen with neighboring phosphorus atoms to form polymers itself. Many oligamers are possible with the alkaline earths but the trimetaphosphates and hexametaphosphates seem to be the most prevalent.

Chemical Properties

transparent, glass-like solid or soft silky masses; hygroscopic; volatilizes at red heat (HPO3)n [MER06]

METAPHOSPHORIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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M-PHOSPHORIC ACID PHOSPHORIC ACID, META VITREOUS SODIUM ACID METAPHOSPHATE METAPHOSPHORIC ACID Metaphosphoric acid (HPO3) Phosphorus hydoxide dioxide META-PHOSPHORIC ACID PIECES FOR ANALYSIS Phosphenic acid Metaphosphoric acid (HPO3) (7CI,8CI,9CI) 10343-62-1 HPO3 C8H19O8P General Use Inorganic Acids Puriss p.a. ACS Synthetic Reagents Analytical Chromatography Product Catalog Analytical Reagents