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(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Structure
CAS No.
149341-33-3
Chemical Name:
(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
Synonyms
R-QUINAR;(R)-QUINAP;(S)-QUINAP;(S)-(−(S)-(−)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline;(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE;(S)-(-)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE;(S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline;(S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline,98%
CBNumber:
CB9159161
Molecular Formula:
C31H22NP
Molecular Weight:
439.49
MOL File:
149341-33-3.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06
Request For Quotation

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Properties

Melting point 220-230 °C
Boiling point 588.1±38.0 °C(Predicted)
storage temp. 2-8°C
pka 4.45±0.30(Predicted)
form Crystalline Powder
color White to off-white
BRN 6664856

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-22
Safety Statements  37/39-26
WGK Germany  3
HS Code  29334990

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 743585 (S)-(−)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline ≥95.0% (qNMR) 149341-33-3 50MG ₹10446.13 2022-06-14 Buy
Sigma-Aldrich(India) 743585 (S)-(−)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline ≥95.0% (qNMR) 149341-33-3 250MG ₹46385.13 2022-06-14 Buy
Product number Packaging Price Buy
743585 50MG ₹10446.13 Buy
743585 250MG ₹46385.13 Buy

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Chemical Properties,Uses,Production

Chemical Properties

white to off-white crystalline powder

Uses

(S)-QUINAP can be used as a ligand:

  • In the asymmetric hydrosilylation of alkyl and α, β-unsaturated ketones in the presence of Fe(OAc)2.??????
  • For the synthesis of chiral organoboron compounds by copper-catalyzed β-borylation of α,β-unsaturated esters.

[Ir(cod)Cl]2 treated with ligand (S)-QUINAP forms an iridium complex. This complex is used as a catalyst for the enantioselective hydrogenation of olefins. (S)-QUINAP–Rh complex can be employed as a catalyst in enantioselective hydroboration/oxidation of perfluoroalkenes.

General Description

(S)-QUINAP is a bidentate ligand used in catalytic asymmetric hydroboration, hydrogenation, oxidation, and allylic alkylation reactions.

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Suppliers

Global( 21)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Capot Chemical Co.,Ltd. 571-85586718 +8613336195806 China 29798 60 Inquiry
Aladdin Scientific +1-+1(833)-552-7181 United States 52927 58 Inquiry
ABCR GmbH & CO. KG 49 721 95061 0 Germany 6846 75 Inquiry
Jiangsu aikang biomedical research and development co., LTD 025-66110311 13155353615 China 15527 58 Inquiry
Beijing Jin Ming Biotechnology Co., Ltd. 010-60605840 15801484223; China 29778 58 Inquiry
Shanghai Chiral bio-compound co., Ltd. 021-5068 3667/17749785980/1029026415; 17749785980 China 2884 58 Inquiry
Sigma-Aldrich 021-61415566 800-8193336 China 51471 80 Inquiry
Shanghai Zunlijia Life Technology Co., Ltd 021-34045219 13195660927 China 2303 58 Inquiry
Shanghai Maclean Biochemical Technology Co., LTD 021-50706066 15221275939 China 29802 58 Inquiry
HONEST JOY HOLDINGS LIMITED +86-755-26404303 United States 6702 54 Inquiry
Supplier Advantage
Capot Chemical Co.,Ltd. 60
Aladdin Scientific 58
ABCR GmbH & CO. KG 75
Jiangsu aikang biomedical research and development co., LTD 58
Beijing Jin Ming Biotechnology Co., Ltd. 58
Shanghai Chiral bio-compound co., Ltd. 58
Sigma-Aldrich 80
Shanghai Zunlijia Life Technology Co., Ltd 58
Shanghai Maclean Biochemical Technology Co., LTD 58
HONEST JOY HOLDINGS LIMITED 54

149341-33-3((R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE)Related Search:

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE (R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE DIPHENYL(O-TOLYL)PHOSPHINE
(S)-QUINAP (R)-QUINAP R-QUINAR (S)-(-)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE (S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline S-QUINAP (S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline,98% (S)-(-)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE;(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE (S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline >=95.0% (qNMR) (R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE (S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline Isoquinoline, 1-[2-(diphenylphosphino)-1-naphthalenyl]-, (1S)- (S)-(&minus )-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline (S)-(− 149341-33-3 organophosphine ligand