2,6-NAPHTHALENEDICARBOXYLIC ACID

- CAS No.
- 1141-38-4
- Chemical Name:
- 2,6-NAPHTHALENEDICARBOXYLIC ACID
- Synonyms
- NAPHTHALENE-2,6-DICARBOXYLIC ACID;2,6-NAPHTHALIC ACID;2,6-NAPTHALENEDICARBOXYLIC ACID;DK7461;NSC 96410;JACS-1141-38-4;TIMTEC-BB SBB008377;Adiphenine Impurity 11;Naphthaline-2,6-dicarbonic acid;2,6-NAPHTHALENEDICARBOXYLIC ACID
- CBNumber:
- CB9215403
- Molecular Formula:
- C12H8O4
- Molecular Weight:
- 216.19
- MOL File:
- 1141-38-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/3/16 22:27:45
Melting point | >300 °C (lit.) |
---|---|
Boiling point | 316.6°C (rough estimate) |
Density | 1.5 |
refractive index | 1.7080 (estimate) |
storage temp. | Sealed in dry,Room Temperature |
solubility | very faint turbidity in hot Pyridine |
pka | 3.69±0.30(Predicted) |
form | Powder |
color | white |
Water Solubility | 3μg/L at 20℃ |
BRN | 2051257 |
InChI | InChI=1S/C12H8O4/c13-11(14)9-3-1-7-5-10(12(15)16)4-2-8(7)6-9/h1-6H,(H,13,14)(H,15,16) |
InChIKey | RXOHFPCZGPKIRD-UHFFFAOYSA-N |
SMILES | C1=C2C(C=C(C(O)=O)C=C2)=CC=C1C(O)=O |
LogP | 2.22 |
CAS DataBase Reference | 1141-38-4(CAS DataBase Reference) |
EPA Substance Registry System | 2,6-Naphthalenedicarboxylic acid (1141-38-4) |
2,6-NAPHTHALENEDICARBOXYLIC ACID price More Price(11)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 301353 | 2,6-Naphthalenedicarboxylic acid 95% | 1141-38-4 | 5G | ₹4524.85 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 301353 | 2,6-Naphthalenedicarboxylic acid 95% | 1141-38-4 | 5G | ₹4524.85 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 523763 | 2,6-Naphthalenedicarboxylic acid 99% | 1141-38-4 | 5G | ₹8021.33 | 2022-06-14 | Buy |
Sigma-Aldrich | 301353 | 2,6-Naphthalenedicarboxylic acid 95% | 1141-38-4 | 25G | ₹13661.15 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 301353 | 2,6-Naphthalenedicarboxylic acid 95% | 1141-38-4 | 25G | ₹13661.15 | 2022-06-14 | Buy |
2,6-NAPHTHALENEDICARBOXYLIC ACID Chemical Properties,Uses,Production
Chemical Properties
BEIGE POWDER
Uses
2,6-naphthalenedicarboxylic acid is an important product for the manufacture of high strength and excellent dyeing properties of polyester fibers and F class insulation material, is an important monomer performance PEN, PBN, liquid crystal polymer (LCP) and polyurethane resin pharmaceutical and fine chemicals raw material.
General Description
This product has been enhanced for energy efficiency.
Synthesis
2,6-Naphthalenedicarboxylic acid (2,6-NDA) is selectively synthesized from 2-naphthoic acid (2-NCA) and carbon tetrachloride in aqueous sodium hydroxide solution under mild conditions using cyclodextrin (β-CyD) as a catalyst[1]. The specific reaction steps are as follows:
Three mmol of 2-naphthalenecarboxylic acid/2-NCA), 0,8 mmol(0,05 g) of copper powder, and 3,0 mmol of β-CyD were added to 30 mL of 30 wt.-% aqueous sodium hydroxide solution. The reaction was started with the addition of 8,5 mmol of carbon tetrachloride and was continued at 60°C for 7 h with magnetic stirring under nitrogen. Then, the residual carbon tetrachloride was removed by evaporation under reduced pressure.
References
[1] HIDEFUMI HIRAI; Rikinori T; Hisashi Mihori. Selective synthesis of 2,6-naphthalenedicarboxylic acid using cyclodextrin as catalyst[J]. Macromolecular Rapid Communications, 1993, 14 7: 439-443. DOI:10.1002/marc.1993.030140712.
2,6-NAPHTHALENEDICARBOXYLIC ACID Preparation Products And Raw materials
Raw materials
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