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2,6-NAPHTHALENEDICARBOXYLIC ACID

2,6-NAPHTHALENEDICARBOXYLIC ACID Structure
CAS No.
1141-38-4
Chemical Name:
2,6-NAPHTHALENEDICARBOXYLIC ACID
Synonyms
NAPHTHALENE-2,6-DICARBOXYLIC ACID;2,6-NAPHTHALIC ACID;2,6-NAPTHALENEDICARBOXYLIC ACID;DK7461;NSC 96410;JACS-1141-38-4;TIMTEC-BB SBB008377;Adiphenine Impurity 11;Naphthaline-2,6-dicarbonic acid;2,6-NAPHTHALENEDICARBOXYLIC ACID
CBNumber:
CB9215403
Molecular Formula:
C12H8O4
Molecular Weight:
216.19
MOL File:
1141-38-4.mol
MSDS File:
SDS
Modify Date:
2025/3/16 22:27:45

2,6-NAPHTHALENEDICARBOXYLIC ACID Properties

Melting point >300 °C (lit.)
Boiling point 316.6°C (rough estimate)
Density 1.5
refractive index 1.7080 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility very faint turbidity in hot Pyridine
pka 3.69±0.30(Predicted)
form Powder
color white
Water Solubility 3μg/L at 20℃
BRN 2051257
InChI InChI=1S/C12H8O4/c13-11(14)9-3-1-7-5-10(12(15)16)4-2-8(7)6-9/h1-6H,(H,13,14)(H,15,16)
InChIKey RXOHFPCZGPKIRD-UHFFFAOYSA-N
SMILES C1=C2C(C=C(C(O)=O)C=C2)=CC=C1C(O)=O
LogP 2.22
CAS DataBase Reference 1141-38-4(CAS DataBase Reference)
EPA Substance Registry System 2,6-Naphthalenedicarboxylic acid (1141-38-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  24/25
WGK Germany  3
TSCA  T
HazardClass  IRRITANT
HS Code  29173990
NFPA 704
0
0 0

2,6-NAPHTHALENEDICARBOXYLIC ACID price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 301353 2,6-Naphthalenedicarboxylic acid 95% 1141-38-4 5G ₹4524.85 2022-06-14 Buy
Sigma-Aldrich(India) 301353 2,6-Naphthalenedicarboxylic acid 95% 1141-38-4 5G ₹4524.85 2022-06-14 Buy
Sigma-Aldrich(India) 523763 2,6-Naphthalenedicarboxylic acid 99% 1141-38-4 5G ₹8021.33 2022-06-14 Buy
Sigma-Aldrich 301353 2,6-Naphthalenedicarboxylic acid 95% 1141-38-4 25G ₹13661.15 2022-06-14 Buy
Sigma-Aldrich(India) 301353 2,6-Naphthalenedicarboxylic acid 95% 1141-38-4 25G ₹13661.15 2022-06-14 Buy
Product number Packaging Price Buy
301353 5G ₹4524.85 Buy
301353 5G ₹4524.85 Buy
523763 5G ₹8021.33 Buy
301353 25G ₹13661.15 Buy
301353 25G ₹13661.15 Buy

2,6-NAPHTHALENEDICARBOXYLIC ACID Chemical Properties,Uses,Production

Chemical Properties

BEIGE POWDER

Uses

2,6-naphthalenedicarboxylic acid is an important product for the manufacture of high strength and excellent dyeing properties of polyester fibers and F class insulation material, is an important monomer performance PEN, PBN, liquid crystal polymer (LCP) and polyurethane resin pharmaceutical and fine chemicals raw material.

General Description

This product has been enhanced for energy efficiency.

Synthesis

2,6-Naphthalenedicarboxylic acid (2,6-NDA) is selectively synthesized from 2-naphthoic acid (2-NCA) and carbon tetrachloride in aqueous sodium hydroxide solution under mild conditions using cyclodextrin (β-CyD) as a catalyst[1]. The specific reaction steps are as follows:
2,6-NAPHTHALENEDICARBOXYLIC ACID synthesis
Three mmol of 2-naphthalenecarboxylic acid/2-NCA), 0,8 mmol(0,05 g) of copper powder, and 3,0 mmol of β-CyD were added to 30 mL of 30 wt.-% aqueous sodium hydroxide solution. The reaction was started with the addition of 8,5 mmol of carbon tetrachloride and was continued at 60°C for 7 h with magnetic stirring under nitrogen. Then, the residual carbon tetrachloride was removed by evaporation under reduced pressure.

References

[1] HIDEFUMI HIRAI; Rikinori T; Hisashi Mihori. Selective synthesis of 2,6-naphthalenedicarboxylic acid using cyclodextrin as catalyst[J]. Macromolecular Rapid Communications, 1993, 14 7: 439-443. DOI:10.1002/marc.1993.030140712.

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TIMTEC-BB SBB008377 2,6-NAPHTHALENEDICARBOXYLIC ACID 2,6-NAPHTHALENEDICARBOXYLIC ACID, 99.5+% 2,6-NAPHTHALENEDICARBOXYLIC ACID 98+% Naphthalene-2,6-dicarboxylic acid, 98+% Naphthalene-2,6-dicarboxylic acid 99% 2,6-Naphthalenedicarboxylic acid,97% Naphthaline-2,6-dicarbonic acid NSC 96410 2,6-Naphthalenedicarboxylic acid 99% 2,6-Naphthalenedicarboxylic acid, min. 98% 2,6-Naphthalenedicarboxylic acid,neat,neat JACS-1141-38-4 2,6-NaphthalenedicarboxylicAcid> NAPHTHALENE-2,6-DICARBOXYLIC ACID 2,6-NAPHTHALIC ACID 2,6-NAPTHALENEDICARBOXYLIC ACID DK7461 2,6-Naphthalenedicarboxylic acid (8CI, 9CI, ACI) 2,6-Naphthalenedicarboxylic Acid, ≥ 98.0% Adiphenine Impurity 11 1141-38-4 C11 to C12 Carboxylic Acids Carbonyl Compounds Organic Building Blocks Building Blocks Achiral Oxygen Naphthalene derivatives Aromatics Intermediates & Fine Chemicals Pharmaceuticals Carboxylic Acid MonomersAlternative Energy Physisorption Materials for Hydrogen Storage Monomers Polymer Science C11 to C12 Carbonyl Compounds Carboxylic Acids Intermediates of Dyes and Pigments