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2-Hydroxypropyl methacrylate

2-Hydroxypropyl methacrylate  Structure
CAS No.
27813-02-1
Chemical Name:
2-Hydroxypropyl methacrylate
Synonyms
HYDROXYPROPYL METHACRYLATE;METHACRYLIC ACID 2-HYDROXYPROPYL ESTER;methacrylic acid, monoester with propane-1,2-diol;2HPMA;rocryl410;Photomer 2317;2-Hydroxypropyl meth;Dimethicone 9006-65-9;Hydroxy propyl ethacrylate;2-HYDROXYPROYL METHACRYLATE
CBNumber:
CB9299748
Molecular Formula:
C7H12O3
Molecular Weight:
144.17
MOL File:
27813-02-1.mol
MSDS File:
SDS
Modify Date:
2024/7/4 21:45:01

2-Hydroxypropyl methacrylate Properties

Melting point -58°C
Boiling point 57 °C/0.5 mmHg (lit.)
Density 1.066 g/mL at 25 °C (lit.)
vapor density >1 (vs air)
vapor pressure 0.05 mm Hg ( 20 °C)
refractive index n20/D 1.447(lit.)
Flash point 206 °F
storage temp. 2-8°C
solubility 107g/l
form Liquid
color Clear
Specific Gravity 1.066
PH 6 (50g/l, H2O, 20℃)
Water Solubility Soluble in water.
BRN 1752228
InChIKey GNSFRPWPOGYVLO-UHFFFAOYSA-N
LogP 0.97 at 20℃
CAS DataBase Reference 27813-02-1(CAS DataBase Reference)
EPA Substance Registry System Hydroxypropyl methacrylate (27813-02-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS08
Signal word  Danger
Hazard statements  H315-H317-H319-H335-H340-H350
Precautionary statements  P201-P202-P280-P302+P352-P305+P351+P338-P308+P313
Hazard Codes  Xi,T
Risk Statements  36/37/38-43-36-46-45
Safety Statements  26-36/37-37/39-24/25-45-53
WGK Germany  1
RTECS  UD3442500
TSCA  Yes
HS Code  29161490
Toxicity rat,LD50,oral,11200mg/kg (11200mg/kg),LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMAGASTROINTESTINAL: OTHER CHANGESLUNGS, THORAX, OR RESPIRATION: DYSPNEA,National Technical Information Service. Vol. OTS0544834,
NFPA 704
1
2 1

2-Hydroxypropyl methacrylate price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 268542 Hydroxypropyl methacrylate Mixture of hydroxypropyl and hydroxyisopropyl methacrylates, 97%, contains 180-220?ppm monomethyl ether hydroquinone as inhibitor 27813-02-1 100ML ₹2316.55 2022-06-14 Buy
Sigma-Aldrich(India) 268542 Hydroxypropyl methacrylate Mixture of hydroxypropyl and hydroxyisopropyl methacrylates, 97%, contains 180-220?ppm monomethyl ether hydroquinone as inhibitor 27813-02-1 100ML ₹2316.55 2022-06-14 Buy
Sigma-Aldrich 268542 Hydroxypropyl methacrylate Mixture of hydroxypropyl and hydroxyisopropyl methacrylates, 97%, contains 180-220?ppm monomethyl ether hydroquinone as inhibitor 27813-02-1 1L ₹7382.65 2022-06-14 Buy
Sigma-Aldrich(India) 268542 Hydroxypropyl methacrylate Mixture of hydroxypropyl and hydroxyisopropyl methacrylates, 97%, contains 180-220?ppm monomethyl ether hydroquinone as inhibitor 27813-02-1 1L ₹7382.65 2022-06-14 Buy
Sigma-Aldrich 268542 Hydroxypropyl methacrylate Mixture of hydroxypropyl and hydroxyisopropyl methacrylates, 97%, contains 180-220?ppm monomethyl ether hydroquinone as inhibitor 27813-02-1 18L ₹41005.1 2022-06-14 Buy
Product number Packaging Price Buy
268542 100ML ₹2316.55 Buy
268542 100ML ₹2316.55 Buy
268542 1L ₹7382.65 Buy
268542 1L ₹7382.65 Buy
268542 18L ₹41005.1 Buy

2-Hydroxypropyl methacrylate Chemical Properties,Uses,Production

Description

Hydroxypropyl methacrylate(HPMA) is a clear, colorless liquid with a pungent, sweet odor. The product contains low levels of a polymerization inhibitor along with small amounts of methacrylic acid, and propylene oxide. HPMA is used in the manufacture of acrylic polymers for adhesives, inks, and coatings for automotive, appliance and metal applications. The added hydroxyl groups improve adhesion to surfaces, incorporate cross-link sites, and impart corrosion, fogging, and abrasion resistance.

Chemical Properties

Clear colorless liquid

Uses

Monomer for acrylic resins, nonwoven fabric binders, detergent lubricating-oil additives.

Application

2-Hydroxypropyl Methacrylate (HPMA) used in the preparation of solid and emulsion polymers, acrylic dispersions in combination with other (meth) acrylates, which are used in various industries, especially for textile coatings and dressings. HPMA is widely used in the production of acrylic polyols for automotive components, refurbishment coatings, and industrial coatings. HPMA is also used as a comonomer in styrene-based unsaturated polyesters, PMMA-based acrylic resins, and vinyl ester formulations in anchor bolts and chemical anchors.HPMA is particularly useful as a hydrophobic hydroxy monomer in the manufacture of sealants for vacuum impregnation of cast aluminum components. HPMA is also widely used in the production of flexible UV-curable photopolymer printing plates.

General Description

White liquid with a light unpleasant odor. May float or sink in water.

Reactivity Profile

2-Hydroxypropyl methacrylate polymerization: May polymerize when hot or when exposed to ultraviolet light and free-radical catalysts [USCG, 1999].

Health Hazard

Inhalation causes coughing and irritation of nose and throat; lung injury may occur. Ingestion causes irritation and burning of mouth and stomach. Contact of vapor with eyes causes irritation. Liquid may cause severe eye burns and irritation of skin.

Fire Hazard

Behavior in Fire: Compound may polymerize when hot and burst container.

Safety

2-Hydroxypropyl Methacrylate (2-HPMA) is a combustible substance. With intense healing, it forms explosive vapors with air. Vapors are heavier than air and may spread along with floors. In the case of fire, the formation of harmful gaseous products is possible. Contact with skin may cause an allergic reaction. When working with 2-Hydroxypropyl Methacrylate (2-HPMA), sanitary rules for organizing technological processes and hygienic requirements for production equipment must be strictly observed.

2-Hydroxypropyl methacrylate Preparation Products And Raw materials

Global( 416)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
Ultraseal India Neeta Estate 07387708114 Pune, India 1 58 Inquiry
Jp Dyechem Pvt. Ltd +91-22 2560 2525 Mumbai, India 18 58 Inquiry
Ankush Enterprise 09223444216 Mumbai, India 26 58 Inquiry
Global Impex. 91-22-67422603 Maharashtra, India 38 58 Inquiry
Dharani Export-Import Services (P) Ltd. 91-461-2330856 Tamil Nadu, India 171 58 Inquiry
JP Dyechem Pvt. Ltd. 91-22-25602525 Maharashtra, India 57 58 Inquiry
Ultimate Chem (India) Pvt., Ltd. 91-22-29201582 Maharashtra, India 117 58 Inquiry
Kowa India Pvt., Ltd. 91-22-28524680 Maharashtra, India 54 58 Inquiry
2-Propenoicacid,2-methyl-,monoesterwith1,2-propanediol METHACRYLIC ACID HYDROXYPROPYL ESTER HYDROXYPROPYL METHACRYLATE, MIXTURE OF I SOMERS, STAB. HYDROXYPROPYL METHACRYLATE, 97%, MIXTURE OF ISOMERS METHACRYLIC ACID HYDROXYPROPYL ESTER (MIXTURE OF 2-HYDROXY-N-PROPYL AND 2-HYDROXY-1-METHYLETHYL METHACRYLATE)(STABILIZED WITH MEHQ) 95+% 2-HYDROXYPROYL METHACRYLATE METHACRYLICACID,1,2-PROPANEDIOLESTER Methacrylsurehydroxypropylester Hydroxypropyl methacrylate, mixture of isomers, 98%, stab. with ca 0.02% 4-methoxyphenol Hydroxypropyl Methacrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Methacrylate) (stabilized with MEHQ) 2-Hydroxypropyl meth Hydroxypropyl methacrylate Mixture of hydroxypropyl and hydroxyisopropyl methacrylates .beta.-Hydroxypropylmethacrylate 1,2-propanediol,2-methyl,monomethacrylate 1,2-propanediol,monomethacrylate 2-hydroxypropylmethacrylate,mixtureofisomers 2-methyl-2-propenoicaci2-hydroxymethylethylester 2-Hydroxy Propyl Methacrylate (HPMA) 1,2-Propandiol 2-methylpropenoate Monoester of methacrylic adid with propyleneglycol methacrylicacid,esterwith1,2-propanediol methacrylicacid,monoesterwith1,2-propanediol rocryl410 2-HYDROXYPROPYL METHACRYLATE Hydroxypropyl methacrylate, mixture of isomers, stabilized, 97+% Hydroxypropyl Methacrylate HPMA (Mixture of 2-Hydroxypropyl and 2-Hydroxy-1-Methylethyl Methacrylate) (stabilized with MEHQ) Hydroxypropyl Methacrylate  Hydroxypropyl Methacrylate, 97+%, Mixture of isoMers, stabilized Methacrylic Acid Hydroxypropyl Ester Propylene Glycol Monomethacrylate Hydroxypropyl Methacrylate (stabilized with MEHQ) Hydroxy propyl ethacrylate 2-HYDROXYPROPYL METHACRYLATE (MIXTURE OF 2-Hydroxypropyl Methacrylate, 98%, Mixture of isoMers, stabilized Hydroxypropyl Methacrylate, Mixture of isoMers, stabilized Hydroxypropyl methacrylate, 96.5% Hydroxypropyl methacrylate, mixture of isomers, stabilized with &ap:0.02% 4-methoxyphenol PROPYLENE GLYCOL MONOMETHACRYLATE Hydroxypropyl Methacrylate Mixture of hydroxypropyl and hydroxyisopropyl Methacrylates, 97%, contains 180-220 ppM MonoMethyl ether hydroquinone as inhibitor HPMA,2-Hydroxypropyl methacrylate Photomer 2317 2-Hydroxypropyl Methacrylate,mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl methacrylate,stabilized with MEHQ HydroxypropylMethacrylate(mixtureof2-Hydroxypropyland2-Hydroxy-1-methylethylMethacrylate)(stabilizedwithMEHQ)> Hydroxypropyl Methacrylate(mixture of Hydroxypropyl and Hydoxyisopropyl Methacrylates) 99% 2-Hydroxypropyl Methacrylate CAS 27813-02-1 in Stock METHACRYLIC ACID 2-HYDROXYPROPYL ESTER HYDROXYPROPYL METHACRYLATE methacrylic acid, monoester with propane-1,2-diol Dimethicone 9006-65-9 Sinomer? HPMA / 2-Hydroxypropyl methacrylate 2-Hydroxypropyl methacrylate (mixture of 2-Hydroxypropyl methacrylate and 2-Hydroxy-1-methylethyl Methacrylate) Hydroxypropyl methacrylate,mixture of isomers Hydroxypropyl methacrylate(7.4cp(30°c)) 2HPMA Hydroxypropyl Methacrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Methacrylate, stabilized with MEHQ, ≥ 95.0% 27813-02-1 CH2CCH3CO2CH2CHOHCH3 CH2CCH3COOC3H6OH