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ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organotitanium >Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene

Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene

Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene Structure
CAS No.
125051-32-3
Chemical Name:
Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene
Synonyms
784;Irgacure 784;Bis(2,6-difluoro-3-(1-hydropyrro-1-yl)-phenyl)titanocene;Photoinitiator-784;photo sensitizer 784;LS 784;PI 784;uv-784;FMT,784;APi-784
CBNumber:
CB9370465
Molecular Formula:
C30H12F4N2Ti
Molecular Weight:
524.3
MOL File:
125051-32-3.mol
MSDS File:
SDS
Modify Date:
2024/7/29 15:17:36
Request For Quotation

Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene Properties

Melting point 160-170°C
Density 1.43 at 20℃
vapor pressure 0-0.001Pa at 25-50℃
storage temp. below 5° C
form Powder
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
InChI InChI=1S/2C10H6F2N.2C5.Ti/c2*11-8-3-4-10(9(12)7-8)13-5-1-2-6-13;2*1-2-4-5-3-1;/h2*1-6H;;;/q4*-1;+4
InChIKey HRVFAWAOUBYIBB-UHFFFAOYSA-N
SMILES FC1=C(N2C=CC=C2)C=CC(F)=[C-]1[Ti+4]12345678([C-]9=C(C=CC(N%10C=CC=C%10)=C9F)F)(C9=C1[C-]2C3=C49)C1=C5C6=C7[C-]81
LogP 9.5 at 20℃
Surface tension 72.4mN/m at 10g/L and 20℃
EPA Substance Registry System Titanium, bis(.eta.5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- (125051-32-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS08,GHS09
Signal word  Danger
Hazard statements  H228-H361f-H373-H411
Precautionary statements  P210-P280-P260-P308+P313
Hazard Codes  F,Xn,N
Risk Statements  36/37/38-51/53-62-48/22-11
Safety Statements  26-36/37/39-61-36/37-33-22-7
TSCA  Yes
HS Code  2914199090

Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene Chemical Properties,Uses,Production

Description

Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene, also known as Photosensitizer Irgacure 784 or HRcure-784, is an excellent photoinitiator used in a variety of holography material systems. It belongs to titanium‐complex free radical photoinitiator. As a highly active orange solid photoinitiator, Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene has good photoactivity, thermal stability, and low toxicity. Irgacure 784 has high solubility doped in liquid methyl methacrylate (MMA) monomer, far more than the photoinitiator PQ[1-2].

Uses

BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE is a highly active orange solid photoinitiator with good photoactivity, thermal stability and low toxicity. As an active diluent, it is mainly used for UV and visible light curing of unsaturated prepolymers together with single or multi-functional vinyl monomers and oligomers.

Hazard

Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]; Flammable solid [Danger Flammable solids]; Suspected of damaging fertility or the unborn child [Warning Reproductive toxicity]

Properties and Applications

Photoinitiator 784 (also known as HRcure-784) is a highly active orange solid photoinitiator with good photo activity, thermal stability, and low toxicity. As an active diluent, it is mainly used with mono or multifunctional vinyl monomers and oligomers for UV and visible light curing unsaturated prepolymers. It is especially suitable for curing photosensitive resins for imaging or information storage in high-tech and high-value-added fields, information storage equipment, such as photosensitive layers, holography, laser direct imaging, stereolithography, etc. It can initiate the polymerization of unsaturated resins under the action of visible light or ultraviolet light. It can also be used for UV coatings, UV inks, and UV adhesives.
Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene

References

[1] Liu Y, et al. Volume holographic recording in Irgacure 784-doped PMMA photopolymer. Optics Express, 2017; 25: 20654-20662.
[2] Li Z, et al. Near‐Infrared‐Induced Cationic Polymerization Initiated by Using Upconverting Nanoparticles and Titanocene. Macromolecular Rapid Communications, 2019; 40: 1900047.

Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene Preparation Products And Raw materials

Raw materials

Preparation Products

Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene Suppliers

Global( 234)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Jiangxi Lotchem Co.,Ltd. +8615270827708 CHINA 338 58 Inquiry
Tianjin Huiren Chemtech Co., Ltd +86-86-22-23707858 +86-86-13672008665 China 171 58 Inquiry
Hebei Guanlang Biotechnology Co., Ltd. +8619930503259 China 18433 58 Inquiry
Wuhan Kemi-Works Chemical Co., Ltd. +86-2785736489 +8618171418573 China 725 58 Inquiry
Wuhan Fortuna Chemical Co.,Ltd +8618007136271 China 5774 58 Inquiry
Hebei Mojin Biotechnology Co., Ltd +8613288715578 China 12455 58 Inquiry
Hebei Yanxi Chemical Co., Ltd. +86-17531190177; +8617531190177 China 5873 58 Inquiry
Hebei Guanlang Biotechnology Co,.LTD +86-19930503253; +8619930503252 China 5832 58 Inquiry
Henan Fengda Chemical Co., Ltd +86-371-86557731 +86-13613820652 China 20296 58 Inquiry
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Supplier Advantage
Jiangxi Lotchem Co.,Ltd. 58
Tianjin Huiren Chemtech Co., Ltd 58
Hebei Guanlang Biotechnology Co., Ltd. 58
Wuhan Kemi-Works Chemical Co., Ltd. 58
Wuhan Fortuna Chemical Co.,Ltd 58
Hebei Mojin Biotechnology Co., Ltd 58
Hebei Yanxi Chemical Co., Ltd. 58
Hebei Guanlang Biotechnology Co,.LTD 58
Henan Fengda Chemical Co., Ltd 58
Hebei Zhuanglai Chemical Trading Co.,Ltd 58

Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene Spectrum

BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE(125051-32-3)FT-IR

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Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene
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)phenyl]- titanium,bis(.eta.5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1h-pyrrol-1-yl BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE bis(cyclopentadienyl)bis(2,6-difluoro-3-(1H-pyrro Bis(η5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanium 1-(2,4-Difluorophenyl)-1H-pyrrole titanium complex Titanium, bis(.eta.5-2,4-cyclopentadien-1-yl)bis2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl- Titanium, bis(hapto-5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- bis(η-cyclopentadienyl)-bis(2,6-difluoro-3-[pyrrol-1-yl]-phenyl)titanium Bis(cyclopenta-1,3-diene)bis(1-(2,4-difluorophenyl)-3H-pyrrol-3-yl)titanium Photoinitiator FMT Bis(cyclopenta-1,3-diene)bis(1-(2,4-difluorophenyl OMNIRED 784 BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE###125051-32-3 HRcure-784 Bis(.eta.5-2,4-cylcopentadien-1-yl)-bis(2,6-difluoro-3-(1H-pyrrol-1-yl)-Phenyl)titanium Titanium, bis(h5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- Bis(2,6-difluoro-3-(1-hydropyrrol-1-yl)phenyl)titanocene 99% LS 784 PI 784 Titanium, bis(η5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- YF-PI 784 Double (1-(2,4-difluorophenyl)-3-pyrrole) titanium dihydroxide BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE ISO 9001：2015 REACH Bis(cyclopenta-1,3-diene)bis(1-(2,4-difluorophenyl)-3h-pyrrol-3-yl)titanium, 98 Easepi 784 FMT,784 Photoinitiator JMT-784 Bis (eta 5-2,4-cyclopentadien-1-yl) Photoinitiator-784 Bis(2,6-difluoro-3-(1-hydropyrro-1-yl)-phenyl)titanocene photo sensitizer 784 Irgacure 784 784 Dicyclopentadienylbis[2,6-difluoro-3-(1-pyrrolyl)phenyl]titanium lencolo 5021 Sinocure? 784 / Omnirad 784 / Irgacure 784 UV Photoinitiator 784 APi-784 Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene uv-784 Titanium,bis(h5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- Titanium, bis(h5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- 125051-32-3 12051-32-3 C30H22F4N2Ti C30H24F4N2Ti argon ion laser scanning, holographic laser imaging, polyimide light curing, solidifying, PCB ink, PCB solder resist and light curing dental materials OLED