2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine

 化学構造式
1646906-26-4
CAS番号.
1646906-26-4
化学名:
别名:
英語名:
2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine
英語别名:
PO-T2T, >2,4,6-Tris[3-(diphenylphosphoryl)phenyl]-1,3,5-triazine;1,3,5-Triazine, 2,4,6-tris[3-(diphenylphosphinyl)phenyl]-
CBNumber:
CB03312953
化学式:
C57H42N3O3P3
分子量:
909.88
MOL File:
1646906-26-4.mol

2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine 物理性質

比重(密度) :
1.35±0.1 g/cm3(Predicted)
貯蔵温度 :
15-25°C
酸解離定数(Pka):
0.00±0.10(Predicted)
外見 :
powder/crystals
色:
Off-white
融点 :
TGA 460 °C(0.5% weight loss)
Fluorescene:
λem295 nm, 378 nm(in DCM)
Absorption:
λmax272 nm (in DCM)

安全性情報

2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine 価格

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2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine 化学特性,用途語,生産方法

説明

PO-T2T, namely2,4,6-tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazineis electron deficient with a triazine centre and three diphenylphosphines.

使用

PO-T2T is an electron transport/hole blocking material in OLED, or an electron acceptor material in organic electronics.

An efficient action of radical-based OLEDs, whose emission originates from a spin doublet, rather than a singlet or triplet exciton was demonstrated in a study published in Nature.
While the emission process is still spin-allowed in these OLEDs, the efficiency limitations imposed by triplet excitons are circumvented for doublets. Using a luminescent radical emitter, an OLED with maximum external quantum efficiency of 27% at a wavelength of 710nm-the highest reported value for deep-red and infrared LEDs was achieved. In this very efficient OLEDs, selective hole injection into the HOMO and electron injection to the SOMO was achieved imploying TAPC as the hole transport layer, and PO-T2T as the electron transport layer to form the fluorescent doublet excited state with near-unity internal quantum efficiency.

2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine 上流と下流の製品情報

原材料

準備製品


2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine 生産企業

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  • 1646906-26-4
  • 2,4,6-Tris[3-(diphenylphosphoryl)phenyl]-1,3,5-triazine
  • 1,3,5-Triazine, 2,4,6-tris[3-(diphenylphosphinyl)phenyl]-
  • PO-T2T, >
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