2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine

2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine 구조식 이미지
카스 번호:
1646906-26-4
상품명:
2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine
동의어(영문):
PO-T2T, >2,4,6-Tris[3-(diphenylphosphoryl)phenyl]-1,3,5-triazine;1,3,5-Triazine, 2,4,6-tris[3-(diphenylphosphinyl)phenyl]-
CBNumber:
CB03312953
분자식:
C57H42N3O3P3
포뮬러 무게:
909.88
MOL 파일:
1646906-26-4.mol
MSDS 파일:
SDS

2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine 속성

밀도
1.35±0.1 g/cm3(Predicted)
저장 조건
15-25°C
산도 계수 (pKa)
0.00±0.10(Predicted)
물리적 상태
powder/crystals
색상
회백색
녹는점
TGA 460 °C(0.5% weight loss)
Fluorescene
λem295 nm, 378 nm(in DCM)
Absorption
λmax272 nm (in DCM)

안전

2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine C화학적 특성, 용도, 생산

개요

PO-T2T, namely2,4,6-tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazineis electron deficient with a triazine centre and three diphenylphosphines.

용도

PO-T2T is an electron transport/hole blocking material in OLED, or an electron acceptor material in organic electronics.

An efficient action of radical-based OLEDs, whose emission originates from a spin doublet, rather than a singlet or triplet exciton was demonstrated in a study published in Nature.
While the emission process is still spin-allowed in these OLEDs, the efficiency limitations imposed by triplet excitons are circumvented for doublets. Using a luminescent radical emitter, an OLED with maximum external quantum efficiency of 27% at a wavelength of 710nm-the highest reported value for deep-red and infrared LEDs was achieved. In this very efficient OLEDs, selective hole injection into the HOMO and electron injection to the SOMO was achieved imploying TAPC as the hole transport layer, and PO-T2T as the electron transport layer to form the fluorescent doublet excited state with near-unity internal quantum efficiency.

2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine 준비 용품 및 원자재

원자재

준비 용품


2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine 공급 업체

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