ピクリルスルホン酸

ピクリルスルホン酸 化学特性,用途語,生産方法

定義

ChEBI: The arenesulfonic acid that is benzenesulfonic acid with three nitro substituents in the 2-, 4- and 6-positions.

一般的な説明

A detonating explosive substance derived from an organic sulfonic acid. Primary hazard is blast of an instantaneous explosion, not flying projectiles or fragments. Under prolonged exposure to fire or heat the containers may explode violently.

空気と水の反応

Soluble in water. Solution exhibits a strong acidic reaction.

反応プロフィール

2,4,6-TRINITROBENZENESULFONIC ACID is a nitroaryl oxidizing acid. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.

健康ハザード

Fire may produce irritating, corrosive and/or toxic gases.

火災危険

MAY EXPLODE AND THROW FRAGMENTS 1600 meters (1 MILE) OR MORE IF FIRE REACHES CARGO.

純化方法

Recrystallise TNBS from 1M HCl, or a mixture of EtOH (50mL), H2O (30mL) and conc HCl (70mL) for 65g of acid, and dry it at 100o. The diethanolamine salt had m 182-183o [Golumbic J Org Chem 11 518 1946]. [Beilstein 11 III 161.]

ピクリルスルホン酸 上流と下流の製品情報

原材料

準備製品

2508-19-2(ピクリルスルホン酸 )キーワード:

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• 2508-19-2
• 2,4,6-TRINITOBENZENESULFONIC ACID
• Trinitrobenzene sulphonic acid
• 2,4,6-trinitro-benzenesulfonicaci
• 2,4,6-trinitrobenzenesulfonicacidsol.
• Picrylsulfonic acid soluti
• Picrylsulfonic Acid, 5 Percent (w/v) Solution in Methanol
• 2,4,6-Trinitrobenzenesulfonic acid(5% in H2O)
• 2,4,6-Trinitrophenylsulfonic acid
• NSC 127994
• 2,4,6-Trinitrobenzenesulfonic acid Picrylsulfonic acid solution TNBS
• 2,4,6-Trinitrobenzenesulfonic acid (TNBS)
• 2,4,6-trinitrobenzenesulfonic acid solution
• picrylsulfonic acid hydrate 5% (W/V)*aqueous solu
• 2,4,6-TRINITROBENZENESULFONIC ACID
• 2,4,6-TRINITROBENZENESULPHONIC ACID
• 2,4,6-TRINITROBENZENESULFONIC ACID SOL., 0.5 M IN ETHANOL
• PICRYLSULFONIC ACID HYDRATE 5% (W/V)*AQU EOUS SOLUTI
• TrinitrobenzoylsulfonicAcid
• PICRYLSULFONICACID,10%AQUEOUSSOLUTION
• PICRYLSULFONICACID,5%(W/V)SOLUTIONINMETHANOL
• PICRYLSULPHONICACID
• 2,4,6-TRINITROBENZENE SULFONIC ACID 98+%
• 2,4,6-TRINITROBENZENE SULFONIC ACID 5% W V IN METHANOL
• 2,4,6-TRINITROBENZENESULFONIC ACID, 1M SOLUTION IN WATER
• Picrylsulfonic Acid (ca. 1% in N,N-Dimethylformamide) [for Detection of Primary Amines]
• trinitrobenzenesulfonicacid
• 2,4,6-Trinitrobenzenesulfonic acid solution, TNBS
• Picrylsulfonic Acid (ca. 1mol/L in Water)
• Picrylsulfonic acid solution,2,4,6-Trinitrobenzenesulfonic acid solution, TNBS
• 2,4,6-Trinitrobenzenesulfonic
• ピクリルスルホン酸
• ピクリルスルホン酸 (約1% N,N-ジメチルホルムアミド溶液)
• ピクリルスルホン酸 (約1mol/L水溶液)
• ピクリルスルホン酸水和物
• 2,4,6-トリニトロベンゼンスルホン酸
• トリニトロベンゼンスルホン酸
• 2,4,6-トリニトロベンゼンスルホン酸 (約1% N,N-ジメチルホルムアミド溶液)
• 2,4,6-トリニトロベンゼンスルホン酸 (約1mol/L水溶液)
• 2,4,6-トリニトロベンゼンスルホン酸水和物
• ピクリルスルホン酸 溶液
• 有機合成化学
• アミン検出用試薬 / 第1級アミン用 (樹脂上の遊離アミン検出用)
• コンビナトリアルケミストリー