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(11BS)-N,N-ジメチル-8,9,10,11,12,13,14,15-オクタヒドロジナフト[2,1-D:1′,2′-F][1,3,2]ジオキサホスフェピン-4-アミン

(11BS)-N,N-ジメチル-8,9,10,11,12,13,14,15-オクタヒドロジナフト[2,1-D:1′,2′-F][1,3,2]ジオキサホスフェピン-4-アミン 化学構造式
389130-06-7
CAS番号.
389130-06-7
化学名:
(11BS)-N,N-ジメチル-8,9,10,11,12,13,14,15-オクタヒドロジナフト[2,1-D:1′,2′-F][1,3,2]ジオキサホスフェピン-4-アミン
别名:
(11BS)-N,N-ジメチル-8,9,10,11,12,13,14,15-オクタヒドロジナフト[2,1-D:1′,2′-F][1,3,2]ジオキサホスフェピン-4-アミン;(S)-(+)-(8,9,10,11,12,13,14,15-オクタヒドロ-3,5-ジオキサ-4-ホスファ-シクロヘプタ[2,1-a;3,4-a']ジナフタレン-4-イル)ジメチルアミン, 99%
英語名:
(S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
英語别名:
MonoPhos Ligand;3,4-a']dinaphthalen-4-;3,4-a']dinaphthalen-4-yl)dimethylamine,99%;3,4-a']dinaphthalen-4-yl)dimethylamine,97%;(S)-(+)-(8,9,10,11,12,13,14,15-Octahydro-3,5-dioxa-4-phospha-cyclohepta[2,1-a;(S)-(+)-N,N-Dimethyl(8,9,10,11,12,13,14,15-Octahydro-3,5-Dioxa-4-Phospha-Cyclohe;(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepi;(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4;(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho-[2,1-d:1,2-f][1,3,2]dioxaphosphepin-4-amin;(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho-[2,1-d:1,2-f][1,3,2]dioxaphosphepin-4-amine
CBNumber:
CB4450993
化学式:
C22H26NO2P
分子量:
367.42
MOL File:
389130-06-7.mol
MSDS File:
SDS

(11BS)-N,N-ジメチル-8,9,10,11,12,13,14,15-オクタヒドロジナフト[2,1-D:1′,2′-F][1,3,2]ジオキサホスフェピン-4-アミン 物理性質

融点 :
112-113°C
比旋光度 :
+318° (c 0.63, THF)
沸点 :
523.3±60.0 °C(Predicted)
貯蔵温度 :
under inert gas (nitrogen or Argon) at 2-8°C
酸解離定数(Pka):
2.15±0.20(Predicted)
外見 :
粉
色:
白い
光学活性 (optical activity):
[α]22/D 282.0°, c = 1 in chloroform
Sensitive :
moisture sensitive, store cold
CAS データベース:
389130-06-7

安全性情報

Rフレーズ  36/37/38
Sフレーズ  26-36/37/39
WGK Germany  3

(11BS)-N,N-ジメチル-8,9,10,11,12,13,14,15-オクタヒドロジナフト[2,1-D:1′,2′-F][1,3,2]ジオキサホスフェピン-4-アミン 価格 もっと(6)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01SRM15-3495 (S)-(+)-(8,9,10,11,12,13,14,15-オクタヒドロ-3,5-ジオキサ-4-ホスファ-シクロヘプタ[2,1-a;3,4-a']ジナフタレン-4-イル)ジメチルアミン, 99%
(S)-(+)-(8,9,10,11,12,13,14,15-Octahydro-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine, 99% 		389130-06-7 500mg ￥190500 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01MAS093082
(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 		389130-06-7 250mg ￥201900 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01MAS093082
(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 		389130-06-7 1g ￥448500 2024-03-01 購入
Sigma-Aldrich Japan 685569 (11bS)-N,N-ジメチル-8,9,10,11,12,13,14,15-オクタヒドロジナフト[2,1-d:1′,2′-f][1,3,2]ジオキサホスフェピン-4-アミン
(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine 		389130-06-7 100mg ￥17200 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01SRM15-3495 (S)-(+)-(8,9,10,11,12,13,14,15-オクタヒドロ-3,5-ジオキサ-4-ホスファ-シクロヘプタ[2,1-a;3,4-a']ジナフタレン-4-イル)ジメチルアミン, 99%
(S)-(+)-(8,9,10,11,12,13,14,15-Octahydro-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine, 99% 		389130-06-7 100mg ￥51600 2024-03-01 購入

(11BS)-N,N-ジメチル-8,9,10,11,12,13,14,15-オクタヒドロジナフト[2,1-D:1′,2′-F][1,3,2]ジオキサホスフェピン-4-アミン 化学特性,用途語,生産方法

使用

(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine is a monodentate phosphoramidite (MonoPhos) chiral ligand that can be used:
  • In the Cu-catalyzed synthesis of chiral 3-(arylbut-1-yn-1-yl)silane derivatives by reacting N-tosylhydrazones with silyl-substituted alkynes via asymmetric insertion.
  • In the Rh-catalyzed asymmetric hydrogenation of R-isopropylcinnamic acid derivative, a key intermediate of renin inhibitor aliskiren.
  • In the Rh-catalyzed conjugate addition of arylboronic acids to lactones, enones, and nitroalkenes.

(11BS)-N,N-ジメチル-8,9,10,11,12,13,14,15-オクタヒドロジナフト[2,1-D:1′,2′-F][1,3,2]ジオキサホスフェピン-4-アミン 上流と下流の製品情報

原材料

準備製品

(11BS)-N,N-ジメチル-8,9,10,11,12,13,14,15-オクタヒドロジナフト[2,1-D:1′,2′-F][1,3,2]ジオキサホスフェピン-4-アミン 生産企業

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389130-06-7((11BS)-N,N-ジメチル-8,9,10,11,12,13,14,15-オクタヒドロジナフト[2,1-D:1′,2′-F][1,3,2]ジオキサホスフェピン-4-アミン)キーワード:

(11BS)-N,N-ジメチル-8,9,10,11,12,13,14,15-オクタヒドロジナフト[2,1-D:1′,2′-F][1,3,2]ジオキサホスフェピン-4-アミン
  • 389130-06-7
  • (S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
  • (S)-(+)-(8,9,10,11,12,13,14,15-Octahydro-3,5-dioxa-4-phosphacyclohepta[2.1-a.3.4-a']dinaphthalen-4-yl)dimethylamine
  • (S)-(+)-(8,9,10,11,12,13,14,15-Octahydro-3,5-dioxa-4-phospha-cyclohepta[2,1-a
  • 3,4-a']dinaphthalen-4-yl)dimethylamine,99%
  • (11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-amine
  • (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4
  • (11bS)-8,9,10,11,12,13,14,15-octahydro-N,N-diMethyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine
  • MonoPhos Ligand
  • (S)-(+)-N,N-Dimethyl(8,9,10,11,12,13,14,15-Octahydro-3,5-Dioxa-4-Phospha-Cyclohe
  • (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepi
  • (11bS)-8,9,10,11,12,13,14,15-Octahydro-N,N-dimethyl-di naphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine,99%e.e.
  • 3,4-a']dinaphthalen-4-yl)dimethylamine,97%
  • (S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A;3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE,99%
  • 3,4-a']dinaphthalen-4-
  • (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho-[2,1-d:1,2-f][1,3,2]dioxaphosphepin-4-amine
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine,8,9,10,11,12,13,14,15-octahydro-N,N-dimethyl-, (11bS)-
  • (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho-[2,1-d:1,2-f][1,3,2]dioxaphosphepin-4-amin
  • (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (11BS)-N,N-ジメチル-8,9,10,11,12,13,14,15-オクタヒドロジナフト[2,1-D:1′,2′-F][1,3,2]ジオキサホスフェピン-4-アミン
  • (S)-(+)-(8,9,10,11,12,13,14,15-オクタヒドロ-3,5-ジオキサ-4-ホスファ-シクロヘプタ[2,1-a;3,4-a']ジナフタレン-4-イル)ジメチルアミン, 99%
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