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DIACETATO[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) RU(OAC)2[(S)-SEGPHOS®]

DIACETATO[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) RU(OAC)2[(S)-SEGPHOS®] 化学構造式
373650-12-5
CAS番号.
373650-12-5
化学名:
DIACETATO[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) RU(OAC)2[(S)-SEGPHOS®]
别名:
DIACETATO[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) RU(OAC)2[(S)-SEGPHOS®];ジアセタト[(S)-(-)-5,5'-ビス(ジフェニルホスフィノ)-4,4'-ビ-1,3-ベンゾジオキソール]ルテニウム(II) Ru(OAc)2[(S)-segphos®]
英語名:
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
英語别名:
RU(OAC)2[(S)-SEGPHOS];(S)-Ru(OAc)2(SEGPHOS);(S)-Ru(OAc)2(SEGPHOS(R));Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-be...;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II);Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II);Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II),Ru(OAc)2[(S)-segphos;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos];Diacetoxyruthenium, [4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl )-1,3-benzodioxol-5-yl]-diphenyl-phosphane;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)]
CBNumber:
CB71181064
化学式:
C38H28O4P2.C4H6O4Ru
分子量:
829.741
MOL File:
373650-12-5.mol

DIACETATO[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) RU(OAC)2[(S)-SEGPHOS®] 物理性質

融点 :
>100°C
貯蔵温度 :
2-8°C
外見 :
個体
色:
黄色から黒
Sensitive :
air sensitive

安全性情報

WGK Germany  3

DIACETATO[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) RU(OAC)2[(S)-SEGPHOS®] 価格 もっと(5)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01SRM44-0169 Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos®]
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos?] 		373650-12-5 250mg ￥22800 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01SRM44-0169 Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos®]
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos?] 		373650-12-5 1g ￥67900 2024-03-01 購入
Sigma-Aldrich Japan 693243
(S)-Ru(OAc)2(SEGPHOS?) 		373650-12-5 100mg ￥6310 2023-06-01 購入
Sigma-Aldrich Japan 693243
(S)-Ru(OAc)2(SEGPHOS?) 		373650-12-5 50mg ￥4410 2021-03-23 購入
富士フイルム和光純薬株式会社(wako) W01SRM44-0169 Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos®]
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos?] 		373650-12-5 5g ￥187500 2024-03-01 購入

DIACETATO[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) RU(OAC)2[(S)-SEGPHOS®] 化学特性,用途語,生産方法

使用

(S)-Ru(OAc)2(SEGPHOS?) can be used as a catalyst:
  • To prepare highly chemo, enantio, and diastereoselective primary β-amino lactams by asymmetric reductive amination of racemic β-keto lactams.
  • To synthesize chiral primary diarylmethylamines and sterically bulky benzylamines from diaryl and sterically hindered ketones via asymmetric reductive amination reaction.
  • For the conversion of levulinic acid to optically active γ-valerolactone via asymmetric hydrogenation reaction.

DIACETATO[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) RU(OAC)2[(S)-SEGPHOS®] 上流と下流の製品情報

原材料

準備製品

DIACETATO[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) RU(OAC)2[(S)-SEGPHOS®] 生産企業

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373650-12-5(DIACETATO[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) RU(OAC)2[(S)-SEGPHOS®])キーワード:

DIACETATO[(R)-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) RU(OAC)2[(R)-SEGPHOS®] ジアセタト[(S)-(-)-2,2'-ビス(ジフェニルホスフィノ)-1,1'-ビナフチル]ルテニウム(II) [1,2-ビス(ジフェニルホスフィノ)エタン]パラジウム(ＩＩ)ジクロリド ジクロロ(シクロオクタ-1,5-ジエン)ルテニウム(II) ジアセタト[(R)-(+)-2,2'-ビス(ジフェニルホスフィノ)-1,1'-ビナフチル]ルテニウム(II) [1,3-ビス(ジフェニルホスフィノ)プロパン]パラジウム(II)ジクロリド ジクロロ(2-ピリジンカルボキシラト)金 (S)-(-)-SEGPHOS(regR) DIACETATO[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) RU(OAC)2[(S)-SEGPHOS®]
  • 373650-12-5
  • Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
  • (S)-Ru(OAc)2(SEGPHOS(R))
  • Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos]
  • Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)]
  • Diacetoxyruthenium, [4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl )-1,3-benzodioxol-5-yl]-diphenyl-phosphane
  • Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-be...
  • (S)-Ru(OAc)2(SEGPHOS)
  • RU(OAC)2[(S)-SEGPHOS]
  • Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
  • Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II),Ru(OAc)2[(S)-segphos
  • DIACETATO[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM(II) RU(OAC)2[(S)-SEGPHOS®]
  • ジアセタト[(S)-(-)-5,5'-ビス(ジフェニルホスフィノ)-4,4'-ビ-1,3-ベンゾジオキソール]ルテニウム(II) Ru(OAc)2[(S)-segphos®]
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