クロム酸銅

クロム酸銅 化学構造式
12053-18-8
CAS番号.
12053-18-8
化学名:
クロム酸銅
别名:
クロム酸銅;クロム酸銅(Cr2Cu2O5);亜クロム酸銅, (バリウム促進化)
英語名:
Copper chromite
英語别名:
Oxocopper;COPPER CHROMITE;COOPER CHROMITE;Einecs 235-000-1;COPPER(II) CHROMITE;COPPERCHROMIUM OXIDE;COPPER CHROMITE CATALYST;oxo-(oxochromiooxy)chromium;CopperChromite(Ba/MnPromoted);copper(ii) chromium(iii) oxide
CBNumber:
CB7172861
化学式:
CrCuH2O
分子量:
133.56
MOL File:
12053-18-8.mol

クロム酸銅 物理性質

外見 :
InChI:
InChI=1S/Cr.Cu.H2O/h;;1H2
InChIKey:
ZKEGZFIDFXEQLM-UHFFFAOYSA-N
SMILES:
[Cr].[Cu].O
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  O,Xi,T,N
Rフレーズ  8-37-22-49-50
Sフレーズ  17-45-53-61
RIDADR  UN 1479 5.1/PG 2
WGK Germany  3
TSCA  Yes
国連危険物分類  5.1
絵表示(GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
注意喚起語 危険
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H272 火災助長のおそれ;酸化性物質 酸化性液体; 酸化性固体 2
3
危険
警告
GHS hazard pictograms P210, P220, P221P280, P370+P378,P501
H335 呼吸器への刺激のおそれ 特定標的臓器毒性、単回暴露; 気道刺激性 3 警告 GHS hazard pictograms
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 GHS hazard pictograms P273, P391, P501
注意書き
P210 熱/火花/裸火/高温のもののような着火源から遠ざ けること。-禁煙。
P220 衣類/.../可燃物から遠ざけること。
P261 粉じん/煙/ガス/ミスト/蒸気/スプレーの吸入を避ける こと。
P271 屋外または換気の良い場所でのみ使用すること。
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

クロム酸銅 価格 もっと(3)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01AFAA15502 亜クロム酸銅, (バリウム促進化)
Copper Chromite, Barium Promoted
12053-18-8 50g ¥5340 2021-03-23 購入
Sigma-Aldrich Japan 209317 亜クロム酸銅
Copper chromite
12053-18-8 100g ¥12200 2024-03-01 購入
Sigma-Aldrich Japan 209317 亜クロム酸銅
Copper chromite
12053-18-8 500g ¥34100 2024-03-01 購入

クロム酸銅 化学特性,用途語,生産方法

説明

Copper chromite is a black powder and inorganic pigment thatadopts a spinel crystal structure. It can be made by the high-temperaturecalcination of copper(II) oxide and chromium(III) oxide or the thermaldecomposition of copper chromate, which evolves oxygen at higher temperaturesand decomposes to copper chromite.
説明図
The copper chromite (CuCr2O4) is one of the most efficient materials, has wide commercial application as catalysts being used in the unit processes of organic synthesis such as hydrogenation, dehydrogenation, hydrogenolysis, oxidation, alkylation, cyclization, etc. It can be used in the pollution abatement as the catalyst to remove aqueous organic wastes, volatile organic compound (VOC) and vehicular primary emissions such as CO, unburned hydrocarbon, NOx and soot.

化学的特性

black powder

使用

Copper chromite is primarily used as a catalyst forhydrogenation reactions because of its ability to hydrogenate functional groupsin aliphatic and aromatic compounds selectively. Industrially, copper chromiteis used to reduce furfural to furfuryl alcohol and butyraldehyde to 1-butanol,partially reduce conjugated dienes to monoenes, and selectively reduce carbonylgroups in vegetable oils. This CuCr catalyst is studied for a variety ofcatalytic applications including converting the hydrogenolysis of cellulose.It is also used as a catalyst for combustion to help control burn rate and as alight-absorbing pigment.

製造方法

Copper chromite is produced by thermal decomposition of one of three substances. The traditional method is by the ignition of copper chromate:
2CuCrO4 → 2CuCrO3 + O2
Copper barium ammonium chromate is the most commonly used substance for production of copper chromite. The resulting copper chromite mixture produced by this method can only be used in procedures that contain materials inert to barium, as barium is a product of the decomposition of copper barium ammonium chromate, and is thus present in the resulting mixture. The by-product copper oxide is removed using an acetic acid extraction, consisting of washing with the acid, decantation and then heat drying of the remaining solid to yield isolated copper chromite. Copper chromite is produced by the exposure of copper barium ammonium chromate to temperatures of 350-450 °C, generally by a muffle furnace:
Ba2Cu2(NH4)2(CrO4)5 → CrCuO3 + CuO + 2Ba + 4H2O + 4Cr + N2 + 6O2

クロム酸銅 上流と下流の製品情報

原材料

準備製品


クロム酸銅 生産企業

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12053-18-8(クロム酸銅)キーワード:


  • 12053-18-8
  • CopperChromite(Ba/MnPromoted)
  • copper(ii) chromium(iii) oxide
  • COOPER CHROMITE
  • oxo-(oxochromiooxy)chromium
  • Oxocopper
  • COPPER(II) CHROMITE
  • COPPERCHROMIUM OXIDE
  • COPPER CHROMITE CATALYST
  • Einecs 235-000-1
  • oxocopper:oxo(oxochromiooxy)chromium
  • COPPER CHROMITE
  • A Speccial Chemical LDS Additive
  • Chromium copper oxide (Cr2Cu2O5)
  • クロム酸銅
  • クロム酸銅(Cr2Cu2O5)
  • 亜クロム酸銅, (バリウム促進化)
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