Ｏ-(ジフェニルホスフィニル)ヒドロキシルアミン
Ｏ-(ジフェニルホスフィニル)ヒドロキシルアミン 物理性質
- 融点 :
- >140℃ (decomposition)
- 沸点 :
- 368.0±25.0 °C(Predicted)
- 比重(密度) :
- 1.25±0.1 g/cm3(Predicted)
- 貯蔵温度 :
- 2-8°C
- 溶解性:
- DMSO (わずかに)、メタノール (ごくわずか、超音波処理済み)
- 酸解離定数(Pka):
- -1.65±0.70(Predicted)
- 外見 :
- 個体
- 色:
- 白い
- InChI:
- InChI=1S/C12H12NO2P/c13-15-16(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H,13H2
- InChIKey:
- SJECIYLGISUNRO-UHFFFAOYSA-N
- SMILES:
- P(C1=CC=CC=C1)(C1=CC=CC=C1)(ON)=O
Ｏ-(ジフェニルホスフィニル)ヒドロキシルアミン 価格
もっと(3)
| メーカー |
製品番号 |
製品説明 |
CAS番号 |
包装 |
価格 |
更新時間 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
46185-1A |
-(Diphenylphosphinyl)hydroxylamine |
72804-96-7 |
1g |
￥50050 |
2024-07-01 |
購入 |
|
Sigma-Aldrich Japan
|
712019 |
≥90% (HPLC)
O-(Diphenylphosphinyl)hydroxylamine ≥90% (HPLC) |
72804-96-7 |
1g |
￥39700 |
2021-03-23 |
購入 |
|
Sigma-Aldrich Japan
|
712019 |
≥90% (HPLC)
O-(Diphenylphosphinyl)hydroxylamine ≥90% (HPLC) |
72804-96-7 |
5g |
￥87000 |
2021-03-23 |
購入 |
Ｏ-(ジフェニルホスフィニル)ヒドロキシルアミン 化学特性,用途語,生産方法
化学的特性
Light yellow or white powder solid
使用
O-Diphenylphosphinylhydroxylamine is a versatile reactant used in the synthetic preparation of various products such as trans-acylaziridines and aldohydrazones.
説明
O-Diphenylphosphinylhydroxylamine (DPPH) is a versatile electrophilic amination reagent that has been used widely for the amination of stable carbanions, Grignard reagents, and π-electron-rich nitrogen heterocycles. Researchers have used DPPH for the aziridination of enones. Compared to other hydroxylamine derivatives typically stored as hydrochloride salts, this activated phosphinyl reagent exhibits good stability and can be stored indefinitely at 0 ℃. This compound in a single step from hydroxylamine hydrochloride and diphenylphosphinic chloride[1].
一般的な説明
O-(Diphenylphosphinyl)hydroxylamine is a general reagent for electrophilic C-amination, which aminates a variety of stable carbanions and Grignard reagents.
Ｏ-(ジフェニルホスフィニル)ヒドロキシルアミン 上流と下流の製品情報
原材料
準備製品
Ｏ-(ジフェニルホスフィニル)ヒドロキシルアミン 生産企業
Global( 206)Suppliers
Ｏ-(ジフェニルホスフィニル)ヒドロキシルアミン スペクトルデータ(1HNMR)
72804-96-7(Ｏ-(ジフェニルホスフィニル)ヒドロキシルアミン)キーワード:
- 72804-96-7
- O-DIPHENYLPHOSPHINYLHYDROXYLAMINE
- TwoPhenylphosphonichydroxylaMine
- O-(Diphenylphosphinyl)hydroxylamine
- HydroxylaMine, O-(diphenylphosphinyl)-
- (AMinooxy)diphenylphosphineoxid
- Diphenylphosphonoyl hydroxylamine
- O-DiphenyL
- Phosphinic acid, P,P-diphenyl-, azanyl ester
- O-(diphenylphosphoryl)hydroxylaMine
- diphenylphosphinate
- aMino diphenylphosphinate
- (AMinooxy)diphenylphosphine oxide
- phosphinyL
- Azanyl P,P-diphenylphosphinate
- O-DIPHENYLPHOSPHINYLHYDROXYLAMIN
- Ｏ-(ジフェニルホスフィニル)ヒドロキシルアミン