2'-ヨードアセトフェノン
2'-ヨードアセトフェノン 物理性質
- 沸点 :
- 139-140°C 12mm
- 比重(密度) :
- 1.72 g/mL at 25 °C(lit.)
- 屈折率 :
- n20/D 1.618(lit.)
- 闪点 :
- 218 °F
- 貯蔵温度 :
- Keep in dark place,Sealed in dry,Room Temperature
- 外見 :
- 液体
- 比重:
- 1.720
- 色:
- クリアイエロー
- Sensitive :
- Light Sensitive
- BRN :
- 2325078
- CAS データベース:
- 2142-70-3(CAS DataBase Reference)
2'-ヨードアセトフェノン 価格
もっと(18)
| メーカー |
製品番号 |
製品説明 |
CAS番号 |
包装 |
価格 |
更新時間 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01APOOR4681 |
2'-ヨードアセトフェノン
2'-Iodoacetophenone |
2142-70-3 |
5g |
￥6700 |
2024-03-01 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01APOOR4681 |
2'-ヨードアセトフェノン
2'-Iodoacetophenone |
2142-70-3 |
25g |
￥24000 |
2024-03-01 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01APOOR4681 |
2'-ヨードアセトフェノン
2'-Iodoacetophenone |
2142-70-3 |
100g |
￥74400 |
2024-03-01 |
購入 |
|
東京化成工業
|
I0689 |
2'-ヨードアセトフェノン >98.0%(GC)
2'-Iodoacetophenone
>98.0%(GC) |
2142-70-3 |
1g |
￥3700 |
2024-03-01 |
購入 |
|
東京化成工業
|
I0689 |
2'-ヨードアセトフェノン >98.0%(GC)
2'-Iodoacetophenone
>98.0%(GC) |
2142-70-3 |
5g |
￥10700 |
2024-03-01 |
購入 |
2'-ヨードアセトフェノン 化学特性,用途語,生産方法
外観
わずかにうすい黄色～黄色、液体
用途
有機合成原料。
化学的特性
Clear yellow liquid
使用
2′-Iodoacetophenone (2-Iodoacetophenone) may be used in the synthesis of:
indene derivatives
di-(o-acetylphenyl)acetylene
indenol derivative
製造方法
2'-Iodoacetophenone can be synthesized by diazotization of 2-acetylaniline.
To a solution of p-TsOH (22.80 g, 120 mmol) in CH3CN (160 mL) was added an aromatic amine (40 mmol). The resulting amine salt suspension was cooled to 0-5°C. A solution of NaNO2 (5.52 g, 80 mmol) in H2O (12 mL) and KI (16.6 g, 100 mmol) in H2O (12 mL) were added sequentially. The reaction mixture was stirred for 10 minutes, then allowed to warm to ambient temperature and stirred until all the amine was consumed. To the reaction mixture were then added H2O (700 mL), NaHCO3 (1M; until pH=9-10) and Na2S2O3 (2M, 80 mL). The reaction mixture was extracted with EtOAc and purified by column chromatography (hexanes:EtOAc, 9:1 v/v) to give 2'-iodoacetophenone:yellow oil in 94% yield.
反応性
2'-Iodoacetophenone is a bioactive molecule that reacts with boronic acids to form aryl boronic acid derivatives. This reaction can be carried out in chlorobenzene or dihedral solvents, and it is scalable and applicable to a variety of boronic acids. The product of this reaction is an organocatalyst for the synthesis of bioactive molecules. 2'-Iodoacetophenone also reacts with dipole-containing additives to form dichlorodiphenyldichloroethane, which has been used as a fungicide, insecticide, and herbicide.
一般的な説明
2′-Iodoacetophenone is a halogenated aromatic ketone.
2'-ヨードアセトフェノン 上流と下流の製品情報
原材料
準備製品
2'-ヨードアセトフェノン 生産企業
Global( 177)Suppliers
2'-ヨードアセトフェノン スペクトルデータ(IR)
2142-70-3(2'-ヨードアセトフェノン)キーワード:
- 2142-70-3
- 2'-IODOACETOPHENONE
- O-IODOACETOPHENONE
- 2''-IODOACETOPHENONE 97%
- 2'-Iodoacetophenone, 98+%
- 2'-IODOACETOPHENONE, 99+%
- Ethanone, 1-(2-iodophenyl)-
- 1-(2-nitrophenyl)-N-[4-[(E)-(2-nitrophenyl)methylideneamino]-1-piperazinyl]methanimine
- 2'-Iodoacetophenone>
- 1-(2-iodophenyl)ethanone
- 2-IODOACETOPHENONE
- 1-(2-Iodophenyl)ethan-1-one
- 2-iodophenone
- 2'-Iodoacetophenone
- 2'-ヨードアセトフェノン
- O-ヨードアセトフェノン
- 2′-ヨードアセトフェノン