Bis(adamant-1-yl) (부 틸) phosphine
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Bis(adamant-1-yl) (부 틸) phosphine 속성
- 녹는점
- 100°C
- 끓는 점
- 449.6±12.0 °C(Predicted)
- 저장 조건
- Inert atmosphere,Room Temperature
- 물리적 상태
- 가루
- 색상
- 흰색에서 노란색으로
- 감도
- air sensitive
- BRN
- 8726448
- InChI
- InChI=1S/C24H39P/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24/h17-22H,2-16H2,1H3
- InChIKey
- HTJWUNNIRKDDIV-UHFFFAOYSA-N
- SMILES
- P(CCCC)(C12CC3CC(CC(C3)C1)C2)C12CC3CC(CC(C3)C1)C2
- CAS 데이터베이스
- 321921-71-5
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 안전지침서 | 24/25 | ||
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| WGK 독일 | 3 | ||
| HS 번호 | 29310095 |
| 그림문자(GHS): |
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| 신호 어: | Warning | ||||||||||||||||||||||||||||
| 유해·위험 문구: |
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| 예방조치문구: |
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Bis(adamant-1-yl) (부 틸) phosphine C화학적 특성, 용도, 생산
물리적 성질
Butyldi-1-adamantylphosphine is a white to yellow solid with a melting point of 100°C and an estimated boiling point of 449.6±12.0°C. Store at room temperature, it is air sensitive.용도
suzuki reaction일반 설명
Sold in collaboration with Solvias AGSynthesis
Phosphonium salt (2.2 mmol) was added to a cooled solution (- 78 ??C) of Et3N (4.44 g, 44 mmol) in di-n-butyl ether (20 mL). The reaction mixture was stirred at -78 ??C for 5 h and then allowed to warm gradually to r.t. The solvent was removed under vacuum and the residue was dissolved in degassed EtOH (5 mL). After stirring for 15 min, the solid was filtered off and dried to yield the desired phosphine, which can be further purified by crystallization from EtOH. Butyldi-1-adamantylphosphine, yield 90%.31P NMR (C6D6)|?: 24.9. Mp 108-110??C. IR (KBr): 3425 (m, br), 2952 (s), 2847 (s), 2847 (s), 2675 (w), 1446 cm-1 (m). 1H NMR (250 MHz, C6D6): |? = 0.96 (3 H, t, 3JH, H = 7.3 Hz, CH3), 1.35-2.03 (36 H, m, adamantyl-30H, butyl-6H). 13C NMR (62 MHz, C6D6): |? = 41.3 (d, 2JC,P = 11.3 Hz, C-2), 37.4 (C-4), 36.1 (d, 1JC,P = 23.5 Hz, C-1), 33.9 (d, 1JC,P = 26.2 Hz, butyl-|á -CH2), 29.1 (d, 3JC,P = 7.6 Hz, C-3), 24.9 (d, 2JC,P = 13.1 Hz, butyl-|? -CH2), 17.1 (d, 3JC,P = 21.6 Hz, butyl-|? -CH2), 14.3 (butyl-CH3). MS (EI, 70 eV): m/z (%) = 358 (M+, 60), 135 (Ad+, 100).
Bis(adamant-1-yl) (부 틸) phosphine 준비 용품 및 원자재
원자재
질소
아다만탄
에틸알코올
이뷰틸 에테르
Clindamycin palmitate hydrochloride
황산 나트륨
요오드화부틸
트리에틸아민
클로로포름
염화알루미늄
삼염화 인
테트라하이드로푸란
초산에틸
수소화 리튬알미늄
염산
준비 용품
Bis(adamant-1-yl) (부 틸) phosphine 공급 업체
글로벌( 277)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 |
sales@runvmat.com | China | 439 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 |
factory@coreychem.com | China | 29811 | 58 |
| Shaoxin Catsyn Co., Ltd. | +undefined-0575-82040869 +86-0575-82040869; |
sales@catsyn.com | China | 6114 | 58 |
| Alfa Chemistry | |
Info@alfa-chemistry.com | United States | 24072 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 |
sales@hbmojin.com | China | 12840 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 |
sales@capot.com | China | 29791 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 18779 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21634 | 55 |
| Hangzhou FandaChem Co.,Ltd. | +8615858145714 |
FandaChem@Gmail.com | China | 9214 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 |
product@chemlin.com.cn | CHINA | 3009 | 60 |
Bis(adamant-1-yl) (부 틸) phosphine 관련 검색:
세륨(III) 클로라이드 요소 디-1-adamantylphosphine 포스핀(기체) Bis(adamant-1-yl) (부 틸) phosphine
Heptanoyl chloride
Butylamine
N-(n-Butyl)thiophosphoric triamide
n-Butyllithium
n-Butylboronic acid
DI-N-BUTYLMAGNESIUM
N-BUTYLMAGNESIUM BROMIDE
Butylmagnesium chloride
Adamantane
Oxalyl chloride
BENZYLDI-1-ADAMANTYLPHOSPHINE
DI-I-PROPYLPHOSPHINE
Diphenyl-2-pyridylphosphine