황화아연
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황화아연 속성
- 녹는점
- 1700°C
- 끓는 점
- 1185°C (estimate)
- 밀도
- 4.1 g/mL at 25 °C (lit.)
- 용해도
- insoluble in H2O, ethanol; soluble in dilute acid
- 물리적 상태
- 가루
- 색상
- 흰색에서 희미한 노란색까지
- Specific Gravity
- 4.1
- 수용성
- 산에 용해됩니다. 물에 불용성.
- Crystal Structure
- CuCl type
- crystal system
- Cube
- Merck
- 14,10160
- Solubility Product Constant (Ksp)
- pKsp: α-ZnS 23.80;β-ZnS 21.60
- Space group
- F43m
- Lattice constant
a/nm b/nm c/nm α/o β/o γ/o V/nm3 0.53829 0.53829 0.53829 90 90 90 0.156
- Dielectric constant
- 1.7(Ambient)
- 안정성
- 안정적인. 물과 반응하여 독성 황화수소를 생성할 수 있음. 산, 강한 산화제와 호환되지 않습니다. 공기와 습기에 민감합니다.
- InChI
- InChI=1S/S.Zn
- InChIKey
- WGPCGCOKHWGKJJ-UHFFFAOYSA-N
- SMILES
- S=[Zn]
- CAS 데이터베이스
- 1314-98-3(CAS DataBase Reference)
안전
- 위험 및 안전 성명
위험 카페고리 넘버 | 31 | ||
---|---|---|---|
안전지침서 | 50A | ||
WGK 독일 | 3 | ||
RTECS 번호 | ZH5400000 | ||
TSCA | Yes | ||
HS 번호 | 28309085 | ||
유해 물질 데이터 | 1314-98-3(Hazardous Substances Data) | ||
기존화학 물질 | KE-35583 |
황화아연 C화학적 특성, 용도, 생산
화학적 성질
Yellowish-white powder. ZnS exists in two crystalline forms, α (wurtzite) and β (sphalerite). Stable if kept dry. α: d 3.98. β: d 4.102, changes to α form at 1020C. Sublimes at 1180C. Soluble in acids; insoluble in water.용도
Pigment for paints, oilcloths, linoleum, leather, dental rubber, etc., especially in the form of lithopone; mixed with ZnO as "mineral white." Anhydrous zinc sulfide is used in x-ray screens and with a trace of a radium or mesothorium salt in luminous dials of watches; also television screens.생산 방법
Production is similar to that of lithopone. A Na2S solution is mixed with a zinc salt solution under precisely controlled conditions. The resulting zinc sulfide precipitate is calcined and processed to give the finished product. Na2S + ZnSO4 →ZnS + Na2SO4.정의
zinc sulphide: A yellow-whitewater-soluble solid, ZnS. It occursnaturally as sphalerite (see also zincblende) and wurtzite. The compoundsublimes at 1180°C. It is used as apigment and phosphor.일반 설명
A yellowish-white powder in a liquid. Insoluble in water and denser than water. Primary hazard is to the environment. Immediate steps should be taken to limit spread to the environment. Easily penetrates the soil to contaminate groundwater and nearby waterways.공기와 물의 반응
Insoluble in water.반응 프로필
These sulfides are rather inert, dissolve into acid, insoluble in water and alkalis.건강위험
Inhalation of material may be harmful. Contact may cause burns to skin and eyes. Inhalation of Asbestos dust may have a damaging effect on the lungs. Fire may produce irritating, corrosive and/or toxic gases. Some liquids produce vapors that may cause dizziness or suffocation. Runoff from fire control may cause pollution.화재위험
Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot.공업 용도
Zinc sulfide(Sachtolith) is mainly used in plastics. Functional properties such as lightening and hiding power are criteria for the use of Sachtolith. It has proved to be very useful for coloring many thermoplasts. During the dispersion process it does not cause abrasion of metallic production machinery or adversely effect the polymer, even at high operating temperatures or during multistage processing. Even ultrahigh molecular mass thermoplasts can be colored without problems. In glass-fiber-reinforced plastics, the soft texture of Sachtolith prevents mechanical fiber damage during extrusion. Sachtolith is also used as a dry lubricant during the fabrication of these materials.The low abrasiveness of Sachtolith prolongs the operating life of stamping tools used in the manufacture of industrial rubber articles. The lightfastness and ageing resistance of many elastomers are improved by using Sachtolith. It is also used as a dry lubricant for roller and plain bearings, and as a white pigment for greases and oils.
Toxicology
The use of zinc sulfide and barium sulfate in contact with foods is permitted by the FDA (United States) and in most European countries. Some restrictions apply in France, Italy, the United Kingdom, and Czechoslovakia.Soluble zinc is toxic in large amounts, but the human body requires small quantities (10–15 mg d−1) for metabolism. Zinc sulfide is harmless in the human due to its low solubility. The acid concentration in the stomach and the rate of dissolution following ingestion are not sufficient to produce physiologically significant quantities of soluble zinc. LD50 values in the rat exceed 15 g kg−1. No cases of poisoning or chronic damage to health have been observed in the manufacture of zinc sulfide pigments.
황화아연 준비 용품 및 원자재
원자재
준비 용품
황화아연 공급 업체
글로벌( 354)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Suzhou Actchem Co., Ltd. | +8618762124502 |
actchem@qq.com | China | 27 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8615531157085 |
abby@weibangbio.com | China | 8806 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-29-81148696 +86-15536356810 |
1022@dideu.com | China | 3882 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 |
sales@hbmojin.com | China | 12834 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531190177 |
peter@yan-xi.com | China | 5857 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 |
sales1@chuanghaibio.com | China | 5889 | 58 |
Hebei Fengjia New Material Co., Ltd | +86-0311-87836622 +86-17333973358 |
sales06@hbduling.cn | China | 8051 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 20283 | 58 |
Hebei Saisier Technology Co., LTD | +86-18400010335 +86-18034520335 |
admin@hbsaisier.cn | China | 1016 | 58 |
Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 |
admin@zlchemi.com | China | 3002 | 58 |
황화아연 관련 검색:
산화아연 황화아연 C.I. 색소 흰색 5 황화 아연(ZNS), 염화 구리-DOPED Cadmium sulfide, solid soln. with zinc sulfide, aluminum and copper-doped Cadmium sulfide solid soln. with zinc sulfide, copper chloride-doped
Zinc sulphate
Zinc sulfate monohydrate
Zinc carbonate hydroxide
Zinc fluoride
Zinc benzenesulfinate dihydrate
Zinc Phytate
Zinc borate
ZINC OXALATE
Zinc disodium EDTA
Zinc dibenzyldithiocarbamate
Zinc chloride
zinc bis[p-toluenesulphinate]