SCANDIUM SULFIDE

SCANDIUM SULFIDE 구조식 이미지
카스 번호:
12166-29-9
상품명:
SCANDIUM SULFIDE
동의어(영문):
SCANDIUM SULFIDE;scandium(III) sulfide;discandium trisulphide;SCANDIUM(III) SULFIDE, 99.99%;Scandium (III) sulfide, 99.9% (metals basis)
CBNumber:
CB0755230
분자식:
H2SSc
포뮬러 무게:
79.03
MOL 파일:
12166-29-9.mol

SCANDIUM SULFIDE 속성

녹는점
1775°C
밀도
2.910
물리적 상태
노란색 사방정계 결정
색상
yellow orthorhombic crystals, crystalline
crystal system
Nogata
Space group
Fddd
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
1.0410.7382.2059090901.694
EPA
Scandium sulfide (Sc2S3) (12166-29-9)

안전

기존화학 물질 KE-12265

SCANDIUM SULFIDE C화학적 특성, 용도, 생산

제조 방법

Scandium(III) sulfide, Sc2S3, is a yellow solid. Metal sulfides are typically prepared by heating mixtures of the two elements, but in the case of scandium, this method results in the formation of scandium monosulfide, ScS. Sc2S3 can be produced by heating scandium(III) oxide under flowing hydrogen sulfide in a graphite crucible to 1550℃ or higher for 2-3 hours. The crude product is subsequently purified by chemical vapor transport at 950℃  utilizing iodine as the transport agent.
Sc2O3+3H2S→Sc2S3 +3H2O

Structure and conformation

The crystal structure of Sc2S3 is similar to that of sodium chloride, in that it is based on a cubic close-packed array of anions. While NaCl has all the octahedral interstices in the anion lattice occupied by cations, Sc2S3 has one-third of them vacant. The vacancies are ordered, but in a very complicated pattern, resulting in a large, orthorhombic unit cell belonging to the space group Fddd. Above 1100℃, Sc2S3 loses sulfur, resulting in nonstoichiometric compounds such as Sc1.37S2.

SCANDIUM SULFIDE 준비 용품 및 원자재

원자재

준비 용품


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