싸이오사이안산동(I)

싸이오사이안산동(I)
싸이오사이안산동(I) 구조식 이미지
카스 번호:
1111-67-7
한글명:
싸이오사이안산동(I)
동의어(한글):
구리모노티오시아네이트;구리티오시아네이트(쿠(NCS));구리(1+)티오시아네이트;구리의티오시아네이트;구리의티오시아네이트(CUCNS);구리티오시아네이트;싸이오사이안산동(I);티오시안산,구리(1+)염;티오시안산동(I);구리티오시아네이트(COPPERTHIOCYANATE)
상품명:
Cuprous thiocyanate
동의어(영문):
COPPER(I) THIOCYANATE;cuprous;COPPER THIOCYANATE;CUPRIC THIOCYANATE;COPPER SULFOCYANIDE;CUPROUS THIOCYANATE;cuproussulfocyanate;cuprous thiocvalaate;Copper(Ⅰ) Thiocyanate;copper(1+)thiocyanate
CBNumber:
CB1152353
분자식:
CHCuNS
포뮬러 무게:
122.63
MOL 파일:
1111-67-7.mol
MSDS 파일:
SDS

싸이오사이안산동(I) 속성

녹는점
1084°C
밀도
2.84
증기압
0Pa at 20-50℃
저장 조건
Sealed in dry,Room Temperature
용해도
insoluble in H2O, dilute acid solutions,ethanol, acetone; soluble in ethyl ether
물리적 상태
가루
색상
회백색
Specific Gravity
2.843
수용성
물, 알코올에 거의 녹지 않습니다. NH{4}OH, 에테르에 용해됨
Merck
14,2669
Solubility Product Constant (Ksp)
pKsp: 12.75
노출 한도
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
안정성
안정적인.
InChIKey
PDZKZMQQDCHTNF-UHFFFAOYSA-M
CAS 데이터베이스
1111-67-7(CAS DataBase Reference)
EPA
Cuprous thiocyanate (1111-67-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,N
위험 카페고리 넘버 20/21/22-32-50/53-52/53
안전지침서 13-60-61-46-36/37
유엔번호(UN No.) UN 3077 9/PG 3
WGK 독일 3
RTECS 번호 GL8955000
TSCA Yes
위험 등급 9
HS 번호 2842908080
기존화학 물질 KE-08961
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P273 환경으로 배출하지 마시오.
P391 누출물을 모으시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
NFPA 704
0
4 0

싸이오사이안산동(I) C화학적 특성, 용도, 생산

화학적 성질

Copper(I) thiocyanate, CuSCN, [1111-67-7], MW 121.62, is a white powder when pure, but often the material of commerce is yellow. It is soluble in ammonia solution, alkali thiocyanate solutions, and diethyl ether, but it is only slightly soluble in water and dilute mineral acids. It is stable in air in the absence of moisture, but it slowly decomposes in the presence of moisture in air. It is used as an antifouling pigment.

용도

In marine antifouling paints; in primer compositions for explosives industry.

제조 방법

Copper(I) thiocyanate is prepared by the reaction of alkali metal thiocyanates with copper(I) chloride at 8090°C or by the reaction of copper(II) sulfate solutions with alkali metal thiocyanate in the presence of sulfite. It can also be prepared by precipitation from copper(II) salt solutions with hydrogen thiocyanate.

일반 설명

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잠재적 노출

Used as a microbiocide and algaecide in antifouling paints. Used as a laboratory chemical and for making other chemicals. Some formulations may be designated Restricted Use Pesticide (RUP).

운송 방법

UN3439 Nitriles, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required

Structure and conformation

At least two polymorphs of cuprous thiocyanate have been characterized by X-ray crystallography. They both feature copper(I) in a characteristic tetrahedral coordination geometry. The sulfur end of the SCN- ligand is triply bridging so that the coordination sphere for copper is CuS3N.

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides

폐기물 처리

Copper-containing soluble wastes can be concentrated through the use of ion exchange, reverse osmosis, or evaporators to the point where copper can be electrolytically removed and sent to a reclaiming firm. If recovery is not feasible, the copper can be precipitated through the use of caustics and the sludge deposited in a chemical waste landfill. Copper-containing wastes can be concentrated to the point where copper can be electrolytically removed and reclaimed. If recovery is not feasible, the copper can be precipitated by alkali; the cyanide destroyed by alkaline oxidation yielding a sludge which can be sent to a chemical waste landfill. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office

싸이오사이안산동(I) 준비 용품 및 원자재

원자재

준비 용품


싸이오사이안산동(I) 공급 업체

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