3-에틸-3-옥세탄메탄올

3-에틸-3-옥세탄메탄올
3-에틸-3-옥세탄메탄올 구조식 이미지
카스 번호:
3047-32-3
한글명:
3-에틸-3-옥세탄메탄올
동의어(한글):
3-에틸-3-옥세탄메탄올
상품명:
3-Ethyl-3-oxetanemethanol
동의어(영문):
(3-Ethyloxetan-3-yl)Methanol;3-ethyl;3-ETHYL-3-HYDROXYMETHYLOXETANE;EOX;EOXA;EHMO;OXA (oxet;YF-FM EHMO;Monomer-EHMO;Eternacoll EHO
CBNumber:
CB2354190
분자식:
C6H12O2
포뮬러 무게:
116.16
MOL 파일:
3047-32-3.mol
MSDS 파일:
SDS

3-에틸-3-옥세탄메탄올 속성

끓는 점
96 °C/4 mmHg (lit.)
밀도
1.019 g/mL at 25 °C (lit.)
증기압
3.1Pa at 25℃
굴절률
n20/D 1.453(lit.)
인화점
227 °F
저장 조건
under inert gas (nitrogen or Argon) at 2-8°C
물리적 상태
액체
산도 계수 (pKa)
14.58±0.10(Predicted)
색상
무색의
수용성
물에 섞임.
InChI
InChI=1S/C6H12O2/c1-2-6(3-7)4-8-5-6/h7H,2-5H2,1H3
InChIKey
UNMJLQGKEDTEKJ-UHFFFAOYSA-N
SMILES
O1CC(CC)(CO)C1
LogP
0.6 at 25℃
CAS 데이터베이스
3047-32-3(CAS DataBase Reference)
EPA
3-Oxetanemethanol, 3-ethyl- (3047-32-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn
위험 카페고리 넘버 36/37/38-22
안전지침서 37/39-26-24/25
WGK 독일 3
TSCA Yes
HS 번호 29329990
기존화학 물질 2009-3-4089
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P271 옥외 또는 환기가 잘 되는 곳에서만 취급하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
NFPA 704
1
2 0

3-에틸-3-옥세탄메탄올 C화학적 특성, 용도, 생산

화학적 성질

clear colorless liquid

용도

3-Ethyl-3-oxetanemethanol is used as pharmaceutical intermediate.

주요 응용

Poly(3-ethyl-3-oxetanemethanol) could be used as a core to synthesize amphiphilic hyperbranched polyethers (AHPs), which have multiple linear poly-(ethylene glycol) arms. The AHPs owned good dispersion performance for coating pigment particles. Among AHP's products, AHP47 with 0.47 DB had good potential in coating applications. can also be used to synthesize azobenzene-focused hyperbranched poly(3- ethyl-3-oxetanemethanol)[1-2].

Synthesis Reference(s)

Journal of the American Chemical Society, 79, p. 3455, 1957 DOI: 10.1021/ja01570a038

Synthesis

3-Ethyl-3-oxetanemethanol was prepared by a modified procedure described in the literature. A mixture of trimethylopropane (1, 26.8 g, 0.2 mol), diethyl carbonate (23.6 g, 0.2 mol) and potassium hydroxide (0.1 g, 1.8 mmol) in 2 ml absolute ethyl alcohol was refluxed in oil bath at 110?C for 1 h. Then, the mixture was distilled at 110?C for 1 h. Distillation was continued until the temperature of oil bath reached 140?C. After the distillation, the vacuum was supplied for 1 h to remove the excess solvent. On heating above 185?C, the distilled materials were collected in a cold trap under vacuum and obtained >85% of the theoretical yield. 1H-NMR (CDCl3, δ, ppm): 0.80–0.83 (t, 3H, –CH2CH3), 1.61–1.66 (q, 2H, –CH2CH3), 3.62 (s, 2H, –CH2OH), 3.66 (s, 1H, –CH2OH), 4.31–4.32 and 4.38–4.39 (d, 4H, –CH2O).

3-에틸-3-옥세탄메탄올 준비 용품 및 원자재

원자재

준비 용품


3-에틸-3-옥세탄메탄올 공급 업체

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